Temperature Initiated P-Polymerization in Solid [Cd3Cu]CuP10
- [Cd3Cu]CuP10 is the first representative of a class of compounds featuring polyphosphidic adamantine-analogous [P10] units, which tend to be fragmented and polymerized to [P6] rings and tubular [P26] units in the solid state. A new polyphosphide with nominal composition Cd15Cu10P46 results, featuring isolated and polymerized polyanions. Thermoanalytic experiments and phase analytic measurements substantiated the consecutive loss of P4 and Cd of the starting material via different intermediate steps. After P4 loss, the new polyphosphide occurred followed by various binary copper phosphides to the final product Cu3P.
Author: | Melanie Bawohl, Tom Nilges, Peer SchmidtORCiD |
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URL: | http://pubs.acs.org/doi/abs/10.1021/ic401508n |
DOI: | https://doi.org/10.1021/ic401508n |
ISSN: | 1520-510X |
Title of the source (English): | Inorganic chemistry |
Document Type: | Scientific journal article peer-reviewed |
Language: | English |
Year of publication: | 2013 |
Tag: | Thermal Analysis, Solid State Synthesis, Crystal Structure, Polyphosphide |
Volume/Year: | 52 |
Issue number: | 20 |
First Page: | 11895 |
Last Page: | 11901 |
Faculty/Chair: | Fakultät 2 Umwelt und Naturwissenschaften / FG Anorganische Chemie |
Institution name at the time of publication: | Fakultät für Naturwissenschaften (eHL) / Prof. Anorganische Chemie |