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Complete system for combinatorial synthesis and functional investigation of conductive polymers

  • Complete system for combinatorial electrochemical synthesis and functional characterization of combinatorial libraries formed by different polymers and polymeric structures will be presented. Control of electrical potential of single electrode groups consisting of four electrodes (designed for 4-point measurements ) on the array comprising 96 such electrode groups provides addressable electrochemical polymer synthesis on the defined electrodes. After polymerization, electrical characteristics of polymers or/and polymer/electrode contacts and influence of potential analytes on these characteristic are measured. Final data analysis provides complete analytically relevant information on the investigated thin polymer layers or multilayer polymer structures: absolute and relative sensitivity, response time, reversibility, reproducibility, regeneration kinetics, linearity or binding constant. Examples of applications for the development of gas-sensitive (co)polymers and optimization of their sensitive properties and polymer/metal contactsComplete system for combinatorial electrochemical synthesis and functional characterization of combinatorial libraries formed by different polymers and polymeric structures will be presented. Control of electrical potential of single electrode groups consisting of four electrodes (designed for 4-point measurements ) on the array comprising 96 such electrode groups provides addressable electrochemical polymer synthesis on the defined electrodes. After polymerization, electrical characteristics of polymers or/and polymer/electrode contacts and influence of potential analytes on these characteristic are measured. Final data analysis provides complete analytically relevant information on the investigated thin polymer layers or multilayer polymer structures: absolute and relative sensitivity, response time, reversibility, reproducibility, regeneration kinetics, linearity or binding constant. Examples of applications for the development of gas-sensitive (co)polymers and optimization of their sensitive properties and polymer/metal contacts will be presented.show moreshow less

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Metadaten
Author: Vladimir M. MirskyORCiDGND, Valentin Kulikov, Otto S. WolfbeisGND
Title of the source (English):American Chemical Society PMSE Preprints
Document Type:Scientific journal article peer-reviewed
Language:English
Year of publication:2005
Volume/Year:93
First Page:1053
Faculty/Chair:Fakultät 2 Umwelt und Naturwissenschaften / FG Nanobiotechnologie
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