TY - GEN A1 - Horsfield, Brian A1 - Scheck-Wenderoth, Magdalena A1 - Krautz, Hans Joachim A1 - Mutti, Maria T1 - Geoenergy: From visions to solutions KW - CCS Y1 - 2010 U6 - https://doi.org/10.1016/j.chemer.2010.06.002 ER - TY - GEN A1 - Krautz, Hans Joachim A1 - Nimtz, Michael T1 - Flexible Operation of CCS Power Plants to Match Variable Renewable Energies T2 - Energy Procedia N2 - The German Energiewende is resulting in high grid load changes caused by renewable energies. Therefore flexibility of power plants is getting more and more important. Future CCS power plants are usually equipped with more components than conventional power plants, resulting in a more complex and inert reaction on changes in power output. Additionally, due to the change in price structures and higher fixed and operational costs for CCS power plants, it is harder for them to be economically efficient. This study will show different options to increase the flexibility of CCS power plants and evaluate their benefits. KW - CCS; Flexibility; Post combustion capture; Oxyfuel; Solvent storage; Pipeline Y1 - 2013 U6 - https://doi.org/10.1016/j.egypro.2013.08.034 SN - 1876-6102 VL - 2013 IS - 40 SP - 294 EP - 303 ER - TY - GEN A1 - Krautz, Hans Joachim A1 - Corrêa da Silva, Rodrigo A1 - Kangwanpongpan, Tanin T1 - Flame pattern, temperatures and stability limits of pulverized oxy-coal combustion T2 - Fuel : the science and technology of fuel and energy N2 - The challenges in maintaining a stable oxy-coal flame have been reported in the open literature. In case of pulverized coal combustion, narrower flammable regimes arise not only of differences in the feed gas composition, but also due to changes in the flow dynamics because of reduced volume flow rate through the burners to match similar temperatures and radiative heat transfer within the furnace. The present work focuses on the study of flame structure and stability of pre-dried lignite fired by a staged feed-gas burner. Experimental runs were carried out in a 0.40 MWth laboratory facility, with the objective of investigating the effects of swirl strength and feed gas distribution in the burner registers. To assess the experimental data, a numerical study of the non-reacting flow in the near burner region is performed. Predicted flow pattern and flame images show that the primary fuel jet penetrates the internal recirculation zone, forming an annular doughnut reverse flow region for both firing conditions and resembling a type-1 flame pattern. Temperature measurements indicate that the feed gas distribution among the burner registers control the flame temperature in parallel with the swirl number in both air-fired and oxy-fired environments. The oxy-fuel cases exhibite markedly reduced temperatures on the flame axis. This difference in the core arises not just from the more pronounced penetration depth of the primary jet, but also due to reaction mechanisms including pyrolysis and gasification reactions at the higher concentrations of CO2 and water vapor. Flame stabilization is shown to be strongly dependent on an appropriate distribution of the feed gas and strength of swirling flow in the burner front. The results correlated in terms of swirl number, secondary/tertiary flow ratio and secondary/primary axial momentum point to similarities in the stability limits between air-firing and oxy-firing. KW - Oxy-fuel; Pulverized coal combustion; Flame pattern; Stability limits Y1 - 2014 U6 - https://doi.org/10.1016/j.fuel.2013.07.049 SN - 0016-2361 IS - Vol. 115 SP - 507 EP - 520 ER - TY - GEN A1 - Abang, Roger Atini A1 - Lisk, Alexander A1 - Krautz, Hans Joachim T1 - Fireside corrosion of superheater materials under oxy-coal firing conditions T2 - Energy Procedia N2 - The present study investigates the fireside corrosion behavior of selected superheater materials, namely: T24, P92, VM12-SHC, A800HT, and 7RE10 under oxy-coal combustion atmospheres. Data on mass change, scale thickness, metal loss, surface morphology and micro-structural characteristics of corrosion products were obtained. The alloy specimens were analyzed by SEM-EDX, light microscopy and X-Ray diffraction techniques. The results after 2000 hours of exposure at a metal surface temperature of 600 °C indicate that metal wastage increased with decreasing Cr-content under oxy-coal conditions. Y1 - 2013 U6 - https://doi.org/10.1016/j.egypro.2013.08.035 SN - 1876-6102 VL - 40 SP - 304 EP - 311 ER - TY - GEN A1 - Findeisen, Alexander A1 - Klatt, Matthias A1 - Krautz, Hans Joachim T1 - Examination of the corrosion behaviour of selected power plant materials under various operating conditions KW - Korrosion KW - CCS Y1 - 2010 U6 - https://doi.org/http://dx.doi.org/10.1016/j.chemer.2010.05.006 ER - TY - GEN A1 - Akay, Ömer A1 - Bashkatov, Aleksandr A1 - Coy, Emerson A1 - Eckert, Kerstin A1 - Einarsrud, Kristian Etienne A1 - Friedrich, Andreas A1 - Kimmel, Benjamin A1 - Loos, Stefan A1 - Mutschke, Gerd A1 - Röntzsch, Lars A1 - Symes, Mark D. A1 - Yang, Xuegeng A1 - Brinkert, Katharina T1 - Electrolysis in reduced gravitational environments: current research perspectives and future applications T2 - npj Microgravity N2 - Electrochemical energy conversion technologies play a crucial role in space missions, for example, in the Environmental Control and Life Support System (ECLSS) on the International Space Station (ISS). They are also vitally important for future long-term space travel for oxygen, fuel and chemical production, where a re-supply of resources from Earth is not possible. Here, we provide an overview of currently existing electrolytic energy conversion technologies for space applications such as proton exchange membrane (PEM) and alkaline electrolyzer systems. We discuss the governing interfacial processes in these devices influenced by reduced gravitation and provide an outlook on future applications of electrolysis systems in, e.g., in-situ resource utilization (ISRU) technologies. A perspective of computational modelling to predict the impact of the reduced gravitational environment on governing electrochemical processes is also discussed and experimental suggestions to better understand efficiency-impacting processes such as gas bubble formation and detachment in reduced gravitational environments are outlined. KW - Elektrolyse KW - electrolysis Y1 - 2022 UR - https://www.nature.com/articles/s41526-022-00239-y#citeas U6 - https://doi.org/10.1038/s41526-022-00239-y SN - 2373-8065 VL - 8 ER - TY - GEN A1 - Danila, Kevin A1 - Kunz, Philip A1 - Röntzsch, Lars T1 - Dynamic operation of low-temperature electrolyzer systems in modular large-scale chemical plants T2 - Chemie - Ingenieur - Technik : CIT N2 - As one of the main contributors to the greenhouse gas emissions worldwide, the reduction of emissions in chemical industry is indispensable. The production of hydrogen from renewable energy sources using water electrolysis can contribute to this goal. However, the dynamic character of renewable energy sources leads to major challenges regarding the dynamic operation of the production process. Here, a model of a modular low-temperature electrolyzer plant is presented. The effect of available time resolution of the source electricity as well as the impact of the integration time step is studied. With the presented model the positive effect of load-dependent operation of modular electrolyzer plants with fluctuating availability of source electricity on the total hydrogen output is demonstrated. KW - Dynamic simulation KW - Electrolyzer systems KW - Modularization KW - Renewable energy KW - Water electrolysis Y1 - 2025 U6 - https://doi.org/10.1002/cite.202400140 SN - 0009-286X VL - 2025 SP - 1 EP - 11 PB - Wiley-VCH GmbH ER - TY - GEN A1 - Höhne, Olaf A1 - Lechner, Stefan A1 - Schreiber, Matthias A1 - Krautz, Hans Joachim T1 - Drying of Lignite in a Pressurized Steam Fluidized Bed - Theory and Experiments Y1 - 2010 ER - TY - GEN A1 - Thummar, Krunalkumar A1 - Abang, Roger Atini A1 - Menzel, Katharina A1 - Groot, Matheus Theodorus de T1 - Coupling a Chlor-Alkali Membrane Electrolyzer Cell to a Wind Energy Source: Dynamic Modeling and Simulations T2 - Energies N2 - Renewable energy sources are becoming a greater component of the electrical mix, while being significantly more volatile than conventional energy sources. As a result, net stability and availability pose significant challenges. Energy-intensive processes, such as chlor-alkali electrolysis, can potentially adjust their consumption to the available power, which is known as demand side management or demand response. In this study, a dynamic model of a chlor-alkali membrane cell is developed to assess the flexible potential of the membrane cell. Several improvements to previously published models were made, making the model more representative of state-of-the-art CA plants. By coupling the model with a wind power profile, the current and potential level over the course of a day was simulated. The simulation results show that the required ramp rates are within the regular operating possibilities of the plant for most of the time and that the electrolyte concentrations in the cell can be kept at the right level by varying inlet flows and concentrations. This means that a CA plant can indeed be flexibly operated in the future energy system. Y1 - 2022 U6 - https://doi.org/10.3390/en15020606 SN - 1996-1073 VL - 15 IS - 2 SP - 1 EP - 26 ER - TY - GEN A1 - Sharma, Prerana A1 - Röntzsch, Lars A1 - Shahi, Vinod K. T1 - Advancements towards optimization of metal–organic framework-based polymer electrolyte membranes for aqueous redox flow batteries T2 - Journal of materials chemistry : A, materials for energy and sustainability N2 - Aqueous redox flow batteries (ARFBs) are considered a potential technology for large-scale energy storage owing to their eco-friendliness, high current density, and tuneable capacity. Polymer electrolyte membranes (PEMs) are vital components of ARFB, but they suffer from significant capacity/efficiency deterioration due to a lack of advancement in structural framing. To enhance the effectiveness of ARFBs, various membrane types have been optimized. However, the development of an efficient PEM remains a significant problem. Metal–organic frameworks (MOFs) made up of metal sites and organic linkers have gained significant scientific interest. As a result of their large surface area, adjustable pore diameters, and customized functionality, MOF-based PEMs are regarded as effective separators for ARFB. This review covers the state of the art MOF-based PEMs as ARFB separators. In recent years, significant efforts have been made to utilize the unique characteristics of MOFs as they not only improve the conductivity (attributed to their 3D channel structure) and gradient distribution in the polymer framework but also stabilize and mitigate active species cross-over by regulating the effective pore size. The aforementioned tactics can stimulate more research on energy storage technologies and provide future insight into the development and design of size-sieving separators for ARFB. Y1 - 2025 U6 - https://doi.org/10.1039/D4TA08720H SN - 2050-7488 VL - 13 IS - 17 SP - 11952 EP - 11988 PB - Royal Society of Chemistry (RSC) CY - London ER -