TY - GEN A1 - Recupido, Federica A1 - Lama, Giuseppe Cesare A1 - Steffen, Sebastian A1 - Dreyer, Christian A1 - Seidlitz, Holger A1 - Russo, Vincenzo A1 - Lavorgna, Marino A1 - De Luca Bossa, Ferdinando A1 - Silvano, Selena A1 - Boggioni, Laura A1 - Verdolotti, Letizia T1 - Efficient recycling pathway of bio-based composite polyurethane foams via sustainable diamine T2 - Ecotoxicology and Environmental Safety N2 - Aminolysis is widely recognized as a valuable chemical route for depolymerizing polymeric materials containing ester, amide, or urethane functional groups, including polyurethane foams. Bio-based polyurethane foams, pristine and reinforced with 40 wt% of sustainable fillers, were depolymerized in the presence of bio-derived butane-1,4-diamine, BDA. A process comparison was made using fossil-derived ethane-1,2-diamine, EDA, by varying amine/polyurethane ratio (F/A, 1:1 and 1:0.6). The obtained depolymerized systems were analyzed by FTIR and NMR characterizations to understand the effect of both diamines on the degradation pathway. The use of bio-based BDA seemed to be more effective with respect to conventional EDA, owing to its stronger basicity (and thus higher nucleophilicity), corresponding to faster depolymerization rates. BDA-based depolymerized systems were then employed to prepare second-generation bio-based composite polyurethane foams by partial replacement of isocyanate components (20 wt%). The morphological, mechanical, and thermal conductivity properties of the second-generation polyurethane foams were evaluated. The best performances (σ10 %=71 ± 9 kPa, λ = 0.042 ± 0.015 W∙ m-1 ∙K-1) were attained by employing the lowest F/A ratio (1:0.6); this demonstrates their potential application in different sectors such as packaging or construction, fulfilling the paradigm of the circular economy. KW - Health, Toxicology and Mutagenesis KW - Public Health, Environmental and Occupational Health KW - Pollution KW - General Medicine Y1 - 2024 U6 - https://doi.org/10.1016/j.ecoenv.2023.115758 SN - 0147-6513 VL - 269 ER -