TY - CHAP A1 - Schneider, Anna A1 - Hirsch, Florian A1 - Fritsch, Simone A1 - Raab, Alexandra A1 - Raab, Thomas T1 - Hydraulische Eigenschaften von Böden an historischen Holzkohlemeilerplätzen in Brandenburg T2 - Unsere Böden - unser Leben, Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, 2. - 10. September 2015, München Y1 - 2015 PB - Deutsche Bodenkundliche Gesellschaft CY - Göttingen ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Human impact on late Quaternary landscapes in the Central Spanish Pyrenees T2 - AGU Meeting Abstract, 2011 Fall Meeting San Francisco 2011 Y1 - 2011 N1 - EP31D-0842 ER - TY - CHAP A1 - Hirsch, Florian A1 - Nicolay, Alexander A1 - Schneider, Anna A1 - Blaszkiewicz, Miroslaw A1 - Kordowski, Jarosław A1 - Noryskiewicz, Agnieszka M. A1 - Tyszkowski, Sebastian A1 - Raab, Alexandra A1 - Raab, Thomas T1 - Late Quaternary geomorphodynamics and soil development in Wygonin (Poland) T2 - Tagungsband und Exkursionsführer, Arbeitskreis Geoarchäologie Jahrestagung 2013, 2. - 4.5.2013 BTU Cottbus Y1 - 2013 SP - S. 50 PB - Brandenburg Univ. of Technology CY - Cottbus ER - TY - CHAP A1 - Raab, Thomas A1 - Hirsch, Florian ED - Wunderlich, J. ED - Houben, P. T1 - Quartäre Sedimente und Bodenbildung in den Aragonesischen Pyrenäen T2 - AK Geomorphologie, Jahrestagung 2010 in Frankfurt am Main/Schmitten Y1 - 2010 SP - S. 38 PB - Goethe Universität, Institut für Physische Geographie CY - Frankfurt am Main ER - TY - GEN A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Stratigraphy and distribution of Late Quaternary sediments in the Aragon- and Gallego Valley (Aragonese Pyrenees, Spain) T2 - Quaternary International N2 - Within the scope of the research project post-LGM pedogenesis and geomorphodynamics in the Aragonese Pyrenees (Spain), funded by the DFG (Az RA 931/3-1), soils and sediments are used to reconstruct the Late Quaternary landscape formation. By employing multiple field and laboratory methods, several sediment facies (glacial, periglacial, fluvial and anthropogenic induced colluvial displacement) can be distinguished. Due to small scale horizontal and vertical distribution of the Quaternary sediments, the genetic differentiation is crucial for the dating of periglacial and glacial phases. The polygenetic sediment sequences indicate periods of post-glacial geomorphodynamic, probably induced by changing climatic or anthropogenic influences. The glacial sediments are preserved as lateral and terminal moraines. Due to the arrangement of the moraines, several Pleistocene glacial advances can be recognized. Cold climate conditions led to the formation of periglacial slope deposits which are classified as lower and upper heads in accordance to findings from Central Europe (Raab & Völkel 2003, Raab et al. 2010). Although lower heads are restricted to the Pleistocene extraglacial landscape, upper heads can be located in the Pleistocene extraglacial and glacial landscape. Upper heads are characterized by a high amount of silt, which is interpreted as the result of an aeolian admixture. The aeolian component is not limited to the upper head but can also be found as loess deposit on glaciofluvial and fluvial terraces. Due to the characteristically low inclination of the terraces the aeolian cover was only sparsely affected by erosion. On the other hand, on steeper slopes, intensive land use results in residual shallow sediment cover above the bedrock in the upper slopes and deep colluvial layers on the foot slopes and valley bottoms. Y1 - 2012 U6 - https://doi.org/10.1016/j.quaint.2012.08.370 N1 - XVIII INQUA Congress, 21st–27th July, 2011, Bern, Switzerland VL - 279-280 SP - S. 202 ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas ED - Wunderlich, J. ED - Houben, P. T1 - Sedimentologische Untersuchungen zur quartären Landschaftsgeschichte in den Aragonesischen Pyrenäen T2 - AK Geomorphologie, Jahrestagung 2010 in Frankfurt am Main/Schmitten Y1 - 2010 SP - S. 19 PB - Goethe Universität, Institut für Physische Geographie CY - Frankfurt am Main ER - TY - CHAP A1 - Turu, Valenti A1 - Hirsch, Florian A1 - Pena-Monne, J. L. A1 - Raab, Thomas A1 - Ros, X. A1 - Marti-Bono, Carlos A1 - Constante-Orrios, A. ED - Turu, Valenti ED - Constante, Ana T1 - Prospeccion geofisica y geomecanica de la ribera de Biescas (pirineos centrales): estructura del relleno sedimentario del fondo del valle y los sedimentos de vertiente T2 - Resums XIII Reunio Nacional de Quaternari, AEQUA, Andorra 2011 Y1 - 2011 SN - 978-99920-1-861-3 SN - 978-99920-1-860-6 SP - 81 EP - 83 PB - Imp. Envalira [u.a.] CY - Andorra la Vella ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas ED - Völkel, Jörg T1 - Post-LGM-zeitliche Pedogenese und Geomorphodynamik in den Spanischen Zentralpyrenäen T2 - Jahrestagung 2012, 10. - 13. Oktober 2012 in München/Campus Weihenstephan, Deutscher Arbeitskreis für Geomorphologie, Tagungsband zur Critical Zone-Forschung Y1 - 2012 SP - S. 26 PB - München CY - Technische Universität ER - TY - CHAP A1 - Hirsch, Florian A1 - Nicolay, Alexander A1 - Schneider, Anna A1 - Błaszkiewicz, Mirosław A1 - Kordowski, Jarosław A1 - Noryskiewicz, Agnieszka M. A1 - Tyszkowski, Sebastian A1 - Raab, Alexandra A1 - Raab, Thomas ED - Bork, Hans-Rudolf ED - Dreibrodt, Stefan ED - Duttmann, Rainer ED - Unkel, Ingmar T1 - Spätquartäre Landschaftsentwicklung seit der Pommerschen Phase in Wygonin (Nordpolen) T2 - Jahrestagung des AK Geomorphologie in Kiel 2014 Y1 - 2014 SP - S. 66 PB - Christian-Albrechts-Universität CY - Kiel ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Reliktische Bodenbildung in den Spanischen Zentralpyrenäen als Hinweis auf spätquartäre Klimawechsel T2 - Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, Berlin, Potsdam Y1 - 2011 PB - Deutsche Bodenkundliche Gesellschaft CY - Göttingen ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas ED - Sauer, Daniela ED - Jahn, Reinhold ED - Stahr, Karl T1 - Soil formation on Late Quaternary sediments in the Central Pyrenees (Spain) T2 - Landscapes and soils through time, proceedings, Hohenheim, July 28th – August 01th, 2011 Y1 - 2011 SP - 4 EP - 5 CY - Hohenheim ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Distribution, formation and chronology of Late Quaternary sediments in the Central Spanish Pyrenees T2 - 8th International Conference (IAG) on Geomorphology, IAG, Paris, 27 - 31 August 2013, abstract volume Y1 - 2013 SP - S. 342 PB - International Association of Geomorphologists CY - Paris ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Micromorphology and macrofabrics of Late Quaternary sediments in the Aragonese Pyrenees, Spain T2 - 8th International Conference (IAG) on Geomorphology, IAG, Paris, 27 - 31 August 2013, abstract volume N2 - Within the scope of the research project Post-LGM pedogenesis and geomorphodynamics in the Aragonese Pyrenees we used a combination of field and laboratory methods to differentiate and classify Late Quaternary sediments. Our analyses indicate no post sedimentary erosion of the LGM lateral moraines in the Aragon and Gallego valley. Precipitation of calcium carbonate led to the fixation of the diamictons and thus stabilized the glacial landforms. Clasts in the glacial sediments are orientated parallel to the Pleistocene glacial flow direction and therefore underpin the stability of the glacial deposits during paraglacial times. Grain size analyses and OSL ages indicate the covering of glacial sediments by an eolian deposit before the onset of the Holocene. Y1 - 2013 SP - S. 1018 PB - International Association of Geomorphologists CY - Paris ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas A1 - Schneider, Anna A1 - Wechler, Klaus-Peter T1 - Late Holocene eolian fossilization of Podzols in Northeastern Germany T2 - European Geosciences Union, General Assembly 2016, Vienna, Austria N2 - The North European lowland has been formed by glacial and periglacial processes in the Late Pleistocene. Multiple reshaping since the Late Glacial considerably changed the landscape up to and including especially historic times. Sediment sequences and (fossilized) soils can improve our understanding of Late Quaternary landscape development, but mapping of buried soils and surfaces is often limited to single outcrops. Ongoing archaeological rescue excavations in the pre-field of the open-cast mine Cottbus-Nord (northeastern Germany) with dense excavation trenches in an about 10 ha dune and drift sand area reveal multilayered sediment sequences with fossilized soils and sediments from the Late Pleistocene to the Late Holocene. Archaeological findings ranging from Mesolithic flint stones to an about 200 year old ceramics in eolian sediments covering plow horizons and wheel tracks suggest that eolian relocation of sandy material was intensive about 200 years ago. Still unpublished OSL dating underline the intense eolian activity. Recent studies showed that between the 15Th to the 19Th century an iron smelter 5 km to the west of our study site was supplied with charcoal, which was produced in a forest 5 km east to our study site. Our current findings about Late Holocene eolian activity raise the question if this eolian reshaping of the landscape is connected with the operation of the iron smelter either directly by transport or bog iron ore winning or indirectly by population pressure caused by the prospering iron smelter. Our ongoing research indicates, that already for historic land-use off-site effects causing further landscape changes have to be considered. Y1 - 2016 N1 - EGU2016-5754-1 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Raab, Thomas A1 - Hirsch, Florian A1 - Ouimet, William A1 - Dethier, David T1 - Soil stratigraphy of charcoal kiln remains (CKR) in the Litchfield Hills, CT, USA T2 - European Geosciences Union, General Assembly 2016, Vienna, Austria N2 - Charcoal kiln relicts (CKRs) are small anthropogenic landforms that are often found in historic mining areas. CKRs have not been a big research topic yet but mainly were studied as by-products of archaeological excavations. In the last years newly available and very accurate Digital Elevation Models (DEMs) based on high-resolution Airborne Laser Scanning (ALS) data have been used to identify these archaeological remains. In addition, findings of several thousands CKRs in the North German Lowland have increased the awareness that historical charcoal production may significantly contribute to Late Holocene landscape change. Besides the archaeological aspect of CKRs, potential impacts of charcoal burning on the ecology of modern soil landscapes and ecosystem processes must be considered. A relatively high density of CKRs is found in the Litchfield Hills nearby the town of West Cornwall, Litchfield County, CT, USA. The CKRs are especially well preserved on slopes of the tributary valleys of the Housatonic River and form little, circular ramparts with diameters normally less than ten meters. First, rough field surveys in Litchfield County in spring 2015 have suggested differences between soils inside and outside the CKR. Soils on the CKR seem to have relatively deep humus-rich and charcoal containing topsoils whereas the topsoils outside the CKR appear typically thinner and less rich in humus. More thorough investigations have been started in autumn 2015 to prove the hypothesis that properties, distribution and development of soils are controlled by archaeological remains of historical charcoal burning. We present preliminary results from our field studies conducted in October 2015. The stratigraphy and the extent of the 26 CKRs were studied using a sedimentological-pedological approach by coring and trenching. Our results indicate that in Litchfield County the CKRs were used twice and in quick succession. Before the second reuse, the rim of the platform was stabilized with boulders. The black topsoils on the CKRs contain residual charcoal and the topsoils are thicker compared to the soil sequences outside of the CKRs. Y1 - 2016 N1 - EGU2016-3477 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Missing evidence for the LGM-asynchronity in the Central Spanish Pyrenees in geomorphological, sedimentological and pedological archives T2 - European Geosciences Union, General Assembly 2016, Vienna, Austria N2 - According to the state of knowledge, the glacial advances in the Eastern Pyrenees were synchronous with the global LGM during the Late Pleistocene (MIS 2), but the glacial advances in the Central Spanish Pyrenees at MIS 3 were asynchron with the global LGM. Whereas in the Eastern Pyrenees the glacial advances are dated in several well agreeing studies by surface exposure dating of boulders from lateral or terminal moraines, the asynchronity of the Central Spanish Pyrenees was postulated mainly by OSL dating on glacial and fluvial sediments and on radiocarbon dating of pollen from lacustrine deposits. The time difference of about 15 ka raises the question if this is a result of (local) climate factors or owed to failures caused by using several dating techniques on different archives. Anyway, if this time lag is correct, post-LGM formation of soils and sediments from the Late Pleistocene should be different between the Eastern Pyrenees and the Central Spanish Pyrenees. We therefore applied a combined approach of geomorphological, sedimentological and pedological investigations to reconstruct the Late Quaternary landscape development in the Aragon- and Gallego Valley of the Central Spanish Pyrenees. Our study reveals that in both valleys the Pre-Holocene geomorphodynamics on the lateglacial deposits show clear analogies with findings from Pleistocene periglacial landscapes in Central Europe. For MIS 4 and early MIS 3 periglacial processes are proven by loess deposition and formation of solifluction sediments. The glacial sediments, which were dated in earlier studies into mid MIS 3 and counted so far as prove for the asynchronous LGM of the Central Spanish Pyrenees, are covered by periglacial deposits of lateglacial age (14 ka to 11 ka). Surprisingly neither the glacial sediments have pedogenic features that indicate lateglacial soil development, nor do the periglacial deposits show indications for lateglacial soil erosion. Therefore we conclude that soil formation began after the sedimentation of the periglacial deposits, either implying a striking timeframe of more than 15 ka with a stable landscape without any pedogenesis, or the untenability of the MIS 3 age of the glacial sediments. Because we can clearly differentiate further phases of geomorphodynamics during the Holocene with truncated soil profiles and the correlate sediments of soil erosion next to undisturbed soils in periglacial sediments with a lateglacial age, we challenge the thesis of an asynchronous LGM in the Central Spanish Pyrenees and advocate a synchronous LGM in the Gallego- and Aragon valley analog to the Eastern Pyrenees. Y1 - 2016 N1 - EGU2016-5788 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Hirsch, Florian A1 - Raab, Thomas T1 - Chronology of Late Quaternary sediments in the Aragonese Pyrenees T2 - Quaternary International N2 - The Spanish Pyrenees are a type region for Quaternary glaciations. Although the history of glacial research dates back until the first fieldtrips of Charpentier in 1841 and Penck in 1883, the maximum extent of Pleistocene glaciers and the exact chronology is still discussed. Whereas some authors suggest a last glacial maximum (LGM) synchronous to the European Alps, there are also several authors preferring a much earlier Pyrenean LGM. The differing ages for the LGM research using absolute chronological methods reveal the need for a clear stratigraphical and sedimentological approach prior to chronological sampling on Quaternary sediments. Within the scope of the research project post-LGM pedogenesis and geomorphodynamics in the Aragonese Pyrenees (Spain) funded by the DFG (Az RA 931/3-1) Quaternary sediments are differentiated by a combination of multiple field and laboratory methods. This identification of the sediments, combined with the stratigraphic approach forms the basis for the dating of the sediment facies and therefore the prevailing climate conditions at the time of the sedimentation. The studies are mainly conducted in the Aragon- and Gallego Valley, which are both situated in the Aragonese Pyrenees (Spain). We use optically stimulated luminescence (OSL) to date the uppermost unit of the periglacial slope deposits which typically cover glacial sediments in most parts of the study area. There is clear evidence that the glacial and periglacial sediments are partly eroded due to human impact. First OSL and 14C dating reveal relatively young ages for this phase of soil erosion and redepostion on the slopes (approximately 300 a BP). Y1 - 2012 U6 - https://doi.org/10.1016/j.quaint.2012.08.371 N1 - XVIII INQUA Congress, 21st–27th July, 2011, Bern, Switzerland VL - 279-280 SP - S. 202 ER - TY - CHAP A1 - Hirsch, Florian A1 - Nicolay, Alexander A1 - Schneider, Anna A1 - Błaszkiewicz, Mirosław A1 - Kordowski, Jarosław A1 - Noryskiewicz, Agnieszka M. A1 - Tyszkowski, Sebastian A1 - Raab, Alexandra A1 - Raab, Thomas T1 - Late Quaternary soil genesis and geomorphodynamics in Northern Poland T2 - 2nd Annual ICLEA Workshop 2013, Dynamics of climate and landscape evolution of cultural landscapes in the Northern Central European Lowlands since the last ice age, Abstract volume & Excursion guide Y1 - 2013 U6 - https://doi.org/10.2312/GFZ.b103-13047 SP - S. 43 PB - Deutsches GeoForschungsZentrum GFZ CY - Potsdam ER - TY - CHAP A1 - Błaszkiewicz, Mirosław A1 - Brademann, Brian A1 - Brauer, Achim A1 - Brykała, Dariusz A1 - Degórski, Marek A1 - Froehlich, Wojciech A1 - Gierszewski, Piotr A1 - Hirsch, Florian A1 - Kaczmarek, Halina A1 - Kordowski, Jarosław A1 - Kramkowski, Mateusz A1 - Krzymińska, Jarmila A1 - Lamparski, Piotr A1 - Lutyńska, Monika A1 - Mirosław-Grabowska, Joanna A1 - Nicolay, Alexander A1 - Noryśkiewicz, Agnieszka M. A1 - Noryśkiewicz, Bożena A1 - Obremska, Milena A1 - Ott, Florian A1 - Raab, Alexandra A1 - Raab, Thomas A1 - Schneider, Anna A1 - Schwab, Markus T1 - Introduction to ICLEA fieldtrips – Stara Kiszewa 2013 T2 - 2nd Annual ICLEA Workshop 2013, Dynamics of climate and landscape evolution of cultural landscapes in the Northern Central European Lowlands since the last ice age, Abstract volume & Excursion guide Y1 - 2013 U6 - https://doi.org/10.2312/GFZ.b103-13047 N1 - 4 weitere Verfasser SP - 53 EP - 67 PB - Deutsches GeoForschungsZentrum GFZ CY - Potsdam ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas A1 - Schuhart, Stefan T1 - Quaternary deposits and soil formation in the Aragón Pyrenees (Spain) - First results from sedimentological studies T2 - EGU General Assembly 2010, held in Vienna, Austria, 02 – 07 May 2010 Y1 - 2010 N1 - EGU2010-3935 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Lange, Ulrich A1 - Hirsch, Thomas A1 - Mirsky, Vladimir M. A1 - Wolfbeis, Otto S. T1 - Hydrogen sensor based on graphene - palladium nanocomposite T2 - Electrochimica Acta N2 - A composite material was prepared from graphene and palladium nanoparticles (PdNP) by layer-by-layer deposition on gold electrodes. The material was characterized by absorption spectroscopy, scanning electron microscopy, Raman spectroscopy and surface plasmon resonance. Cyclic voltammetry demonstrated the presence of electrocatalytic centers in the palladium decorated graphene. This material can serve as a sensor material for hydrogen at levels from 0.5 to 1% in synthetic air. Pure graphene is poorly sensitive to hydrogen, but incorporation of PdNPs increases its sensitivity by more than an order of magnitude. The effects of hydrogen, nitrogen dioxide and humidity were studied. Sensor regeneration is accelerated in humid air. The sensitivity of the nanocomposite depends on the number of bilayers of graphene–PdNPs. KW - Graphene KW - Palladium KW - Nanoparticle KW - Sensor KW - Layer-by-layer Y1 - 2011 U6 - https://doi.org/10.1016/j.electacta.2010.10.078 SN - 0013-4686 VL - 56 IS - 10 SP - 3707 EP - 3712 ER - TY - GEN A1 - Fassold, Alexander A1 - Falk, Werner A1 - Anders, Sven A1 - Hirsch, Thomas A1 - Mirsky, Vladimir M. A1 - Straub, Rainer H. T1 - Soluble neuropilin-2, a nerve repellent receptor, is increased in rheumatoid arthritis synovium and aggravates sympathetic fiber repulsion and arthritis T2 - Arthritis and Rheumatology N2 - In inflammatory lesions, sympathetic nerve fibers disappear soon after the start of inflammation. We identified sympathetic nerve repellents as possible causal agents in rheumatoid arthritis (RA). On nerve terminals, repellent factors bind to neuropilin-2 and its coreceptor. The aim of this study was to investigate the role of neuropilin-2 in the synovial tissue of patients with RA and patients with osteoarthritis (OA) and in experimental arthritis. The density of neuropilin-2–positive fibers and cells positive for semaphorin 3F (a sympathetic repellent) was investigated using immunofluorescence staining. Enzyme-linked immunosorbent assay was used to detect soluble neuropilin-2 in body fluids from patients with RA and patients with OA. An axon outgrowth assay and a neuropilin-2 Fc fusion construct (neuropilin-2Fc) were used to investigate semaphorin 3F–induced sympathetic nerve repulsion. In an animal model of type II collagen–induced arthritis, soluble neuropilin-2Fc was studied in vivo. The synovial density of neuropilin-2–positive sympathetic nerve fibers was lower in RA than in OA, but the density of cells positive for semaphorin 3F was similar. In synovial fluid, the level of soluble neuropilin-2 was markedly higher in RA compared with OA. Mouse sympathetic ganglia served as an excellent model with which to study semaphorin 3F–induced nerve fiber repulsion. Neuropilin-2 and its coreceptor were present on sympathetic neurons, and semaphorin 3F bound to neuropilin-2Fc (binding constant 96 nmoles/liter). Semaphorin 3F dose-dependently increased sympathetic nerve fiber repulsion (at a 50% maximum response concentration of 160–210 nmoles/liter). In contrast to our expectations, soluble neuropilin-2Fc did not inhibit repulsion but increased the repellent effect of semaphorin 3F. In experimental arthritis, therapy with neuropilin-2Fc aggravated arthritis. Soluble neuropilin-2 has no antirepellent activity but aggravates sympathetic nerve fiber repulsion and arthritis. Increased shedding of neuropilin-2 is probably an unfavorable sign in RA. Y1 - 2009 U6 - https://doi.org/10.1002/art.24860 SN - 2326-5205 VL - 60 IS - 10 SP - 2892 EP - 2901 ER - TY - GEN A1 - Hirsch, Thomas A1 - Shaporenko, Andrey A1 - Mirsky, Vladimir M. A1 - Zharnikov, Michael T1 - Monomolecular films of phthalocyanines: formation, characterisation and expelling by alkanethiols T2 - Langmuir N2 - Adsorption of aluminum-2,3-naphthalocyanine (Al-PC) onto gold (111) substrate from the pure and mixed (with alkanethiols) solutions of the target molecules in ethanol was studied. The resulting films were characterized by X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure spectroscopy. The adsorption from the pure solution resulted in formation of an Al-PC monolayer composed of the strongly inclined molecules. However, a presence of only one molar percent of a thiolated compound (alkanethiol) in the primary solution led to the complete expelling of the Al-PC molecules from the substrate and formation of a one-component alkylthiolate monolayer. The results indicate that an equilibrium formation of mixed monolayers of rodlike thiolated molecules and relatively large planar-geometry molecules, whose interaction with the metal surface is mainly provided by the π-electron system, is difficult to achieve or is in most cases even impossible under equilibrium conditions and requires an introduction of additional anchor moieties (e.g., thiols) into these molecules, as has been demonstrated by successful coadsorption of hexadecanethiol and thiolated tetraphenylporphyrin. Y1 - 2007 U6 - https://doi.org/10.1021/la0634239 SN - 0743-7463 SN - 1520-5827 VL - 23 IS - 8 SP - 4373 EP - 4377 ER - TY - CHAP A1 - Raab, Thomas A1 - Raab, Alexandra A1 - Schneider, Anna A1 - Hirsch, Florian A1 - Takla, Melanie A1 - Nicolay, Alexander A1 - Bonhage, Alexander A1 - Bauriegel, Albrecht A1 - Rösler, Horst T1 - Landnutzungsgeschichte und historische Landschaftsentwicklung in der Niederlausitz – Neue Befunde und aktuelle Forschung T2 - Jahrestagung Arbeitskreis Geoarchäologie, Tübingen, 4. Mai bis 7. Mai 2016 N2 - Seit 2010 untersucht eine interdisziplinäre Forschergruppe der BTU, des BLDAM und des LBGR die Landnutzungsgeschichte sowie die natürliche und anthropogen induzierte Landschaftsentwicklung in der Niederlausitz, Brandenburg. Systematische archäologische Grabungen des BLDAM im Vorfeld der laufenden Tagebaue sind eine wichtige Grundlage für geopedologische Untersuchungen. Die Arbeiten hatten zunächst ihren räumlichen Schwerpunkt in den Braunkohletagebauen nordöstlich von Cottbus (Tgb. Cottbus Nord, Tgb. Jänschwalde) und wurden dann ausgedehnt auf weitere Forstflächen nördlich von Peitz. Wir geben einen Überblick über die wichtigsten Erkenntnisse der letzten Jahre, präsentieren aktuelle Ergebnisse und zeigen zukünftige Forschungsfelder auf. Im Tagebau Jänschwalde sind zwischenzeitlich mehr als 1000 Relikte von Holzkohlmeilern (HKM) als Zeugen einer intensiven historischen Holznutzung archäologisch dokumentiert. Mit Stand Januar 2016 liegen Dendroalter von 64 HKM vor. Die Alter schwanken zwischen dem ausgehenden 16. Jahrhundert und der Mitte des 19. Jahrhunderts, was in etwa dem Betriebszeitraum des Hüttenwerks in Peitz entspricht. Die Mehrzahl der Meiler datiert auf den Beginn des 18. Jahrhunderts. Weitere Hinterlassenschaften der historischen Landnutzung sind u.a. Wölbäcker und begrabene Ackerböden. Fossile Böden und ehemalige Landoberflächen sind stellenweise mit äolischen Sedimenten überdeckt. 14C- und OSL-Datierungen an diesen Böden und Sedimenten lassen auf eine Intensivierung der äolischen Aktivität zur slawischen Zeit und im Deutschen Mittelalter schließen. Einige Relikte von HKM sind mit Sand überweht worden, und an einer Stelle konnte das Alter dieser äolischen Sedimentation mittels Dendrodatierung des begrabenen Meilers auf1850 oder jünger bestimmt werden. Allerdings stellt dies die Ausnahme dar. Der weitaus größere Teil der HKM-Relikte liegt direkt an der Oberfläche und ist nicht begraben, was auf eine sehr geringe Winderosion in der Neuzeit schließen lässt. Seit 2015 konnte im Rahmen des DFG-Projekts „Räumliche und zeitliche Dimension der historischen Köhlerei im Tauerschen Forst (Niederlausitz, Brandenburg). Ein Beitrag zur Kulturlandschaftsentwicklung des Norddeutschen Tieflands“ (Az RA 1129/3-1; RA 931/6-1) ein weiteres Gebiet mit hoher HKM-Dichte untersucht werden. Erste Auswertungen der LiDAR-Daten ergeben eine Anzahl von 4449 ehemaligen Meilerstandorten im Tauerschen Forst. 26 Meilerstellen sind beprobt, die Dendroalter hierzu sind in Bearbeitung. Ebenfalls in jüngerer Zeit fanden Untersuchungen zur Verbreitung von HKM-Relikten für das gesamte Land Brandenburg statt. Mit Hilfe eines binären Modells wurden Gebiete mit hoher Wahrscheinlichkeit von HKM-Standorten detektiert. Im Rahmen des im November 2016 beginnenden DFG-Projekts „Die historische Köhlerei in Brandenburg - Analyse der räumlichen Dimension und der Effekte auf bodenhydraulische Eigenschaften“ (SCHN 1349/1-1) sollen nun neben der Verbreitung der historischen Köhlerei auch bodenrelevante Auswirkungen beschrieben und bewertet werden. Y1 - 2016 UR - https://akgeoarchaeologie.de/de/180 ER - TY - CHAP A1 - Schneider, Anna A1 - Raab, Alexandra A1 - Rösler, Horst A1 - Takla, Melanie A1 - Hirsch, Florian A1 - Ritschl, Bosse A1 - Raab, Thomas ED - Schopper, Franz ED - Bönisch, Eberhard T1 - Geophysikalische Prospektion und Mikrodrohnenbefliegungen zur Dokumentation von Meilerplätzen in der Jänschwalder Heide T2 - Ausgrabungen im Niederlausitzer Braunkohlerevier 2013/2014 Y1 - 2016 SN - 978-3-910011-79-3 SP - 145 EP - 154 PB - Brandenburgisches LAndesamt für Denkmalpflege und Archäologisches Landesmuseum CY - Zossen OT Wünsdorf ER - TY - GEN A1 - Hirsch, Thomas A1 - Zharnikov, Michael A1 - Shaporenko, Andrey A1 - Stahl, Joachim A1 - Weiss, Dieter A1 - Wolfbeis, Otto S. A1 - Mirsky, Vladimir M. T1 - Size-controlled electrochemical synthesis of metallic nanoparticles on molecular templates T2 - Angewandte Chemie International Edition N2 - Reduction on the spot: Planarly adsorbed thiolated porphyrin molecules (purple) incorporated in an insulating alkanethiol monolayer (blue) function as nanoelectrodes for the local reduction of metals (gray). This approach was applied for the in situ synthesis of nanoparticles of a predetermined size. Y1 - 2005 U6 - https://doi.org/10.1002/anie.200500912 SN - 1521-3773 VL - 44 IS - 41 SP - 6775 EP - 6778 ER - TY - GEN A1 - Prodramidis, Mamas I. A1 - Hirsch, Thomas A1 - Wolfbeis, Otto S. A1 - Mirsky, Vladimir M. T1 - Enantioselective chemosensors based on spreader-bar structures T2 - Electroanalysis N2 - Chiroselective binding sites have been created on thin gold films by application of the spreader-bar approach. Impedometric techniques and surface plasmon resonance were applied to detect binding. (R)-(+)-1,1 '-Binaphthyl-2,2 '-diol (R-BNOH) and (S)-(-)-1,1 '-binaphthyl-2,2'-diol (S-BNOH) were used as model analytes. The artificial receptors were prepared by co-adsorption of 16-mercaptohexadecane (matrix) with a thiol-modified chiral selector (template). The conjugates of d, l-thioctic acid and (R)-(+)- or (S)-(-)-1,1'-binaphthyl-2,2'-diamine were used as templates. Different concentration ratios of the matrix and template were tested. No chiral selectivity of surfaces formed by either the matrix or the template alone was observed. The use of alkylthiols shorter than 16-mercaptohexadecane led to the formation of surfaces with no chiral selectivity. The gold electrodes coated by the spreader-bar technique displayed an enantioselectivity of up to 4.76 or up to 2.55 as measured by the capacitive and SPR methods, espectively. KW - Enantioselective artificial receptors KW - Spreader-bar technique KW - Capacitive chemosensor KW - Surface plasmon resonance Y1 - 2003 U6 - https://doi.org/10.1002/elan.200302756 SN - 1521-4109 VL - 15 IS - 22 SP - 1795 EP - 1798 ER - TY - GEN A1 - Mirsky, Vladimir M. A1 - Wrobel, Nadia A1 - Riepl, Michael A1 - Hirsch, Thomas A1 - Wolfbeis, Otto S. T1 - Intelligente Nanostrukturen für Biosensoren und Sensor-Arrays T2 - BioTec: Zeitschrift für Biotechnologie Y1 - 1999 SN - 0937-2725 VL - 10 SP - 28 EP - 32 ER - TY - GEN A1 - Hirsch, Thomas A1 - Kettenberger, Hubert A1 - Wolfbeis, Otto S. A1 - Mirsky, Vladimir M. T1 - A simple strategy for preparation of sensor arrays: Nanostructured monolayers as recognition elements T2 - Chemical Communications N2 - The spreader-bar approach is a simple method for producing a huge variety of receptors with different selectivities. A sensor-array consisting of five such receptors is presented. A pattern recognition provides selective detection of different purines and pyrimidines. Y1 - 2003 U6 - https://doi.org/10.1039/b210554c SN - 1359-7345 SN - 1364-548X IS - 3 SP - 432 EP - 433 ER - TY - GEN A1 - Mirsky, Vladimir M. A1 - Hirsch, Thomas A1 - Panasyuk, Tatiana L. A1 - Piletsky, Sergey A. A1 - Wolfbeis, Otto S. T1 - Two- and three-dimensional artificial chemoreceptors: molecular spreader-bar vs. molecular imprinting T2 - Medical and Biological Engineering and Computing Y1 - 1999 SN - 0140-0118 SN - 1741-0444 VL - 37 IS - suppl.2 SP - 344 EP - 345 ER - TY - GEN A1 - Mirsky, Vladimir M. A1 - Hirsch, Thomas A1 - Piletsky, Sergey A. A1 - Wolfbeis, Otto S. T1 - A spreader-bar approach to molecular architecture: formation of stable artificial chemoreceptors T2 - Angewandte Chemie International Edition N2 - The destructive influence of lateral diffusion on nanostructured monolayers can be prevented by using the spreader-bar technique. This approach allows the formation of stable artificial receptors for barbituric acid by lateral structuring of a dodecanethiol monolayer with molecular spreader-bars from thiobarbituric acid without chemical polymerization (see schematic representation). The new technique may have applications in chemosensors, affinity chromatography, stereoselective catalysis, and molecular electronics. KW - Molecular architecture KW - Molecular recognition KW - Monolayers KW - Nanostructures KW - Sensors Y1 - 1999 U6 - https://doi.org/10.1002/(SICI)1521-3773(19990419)38:8<1108::AID-ANIE1108>3.0.CO;2-C SN - 1521-3773 VL - 38 IS - 8 SP - 1108 EP - 1110 ER - TY - CHAP A1 - Raab, Thomas A1 - Raab, Alexandra A1 - Takla, Melanie A1 - Nicolay, Alexander A1 - Hirsch, Florian A1 - Schneider, Anna A1 - Rösler, Horst T1 - Integrative Application of Traditional and Cutting-Edge Techniques to Reconstruct Holocene Earth Surface Processes and Landscape Dynamics - A Case Study from the Northern German Lowland T2 - AGU Joint Assembly, Montreal, 2015, abstracts listing N2 - This study outlines the opportunities to reconstruct Holocene landscape dynamics in active opencast lignite mines in southern Brandenburg (Germany). Studies on extensive outcrops that address geomorphology, pedology and archaeology provide unique insights into human-induced environmental changes. Our approach uses a variety of traditional and cutting-edge techniques to characterize small-scale landforms (high-resolution DEMs by micro-drone and LiDAR), to analyze soils and substrate properties in the field (GPR, ERT, geomagnetics, Field Portable XRF and XRD) and to provide chronological information (OSL, 14C, tree-ring dating). This approach is combined with a GIS for data integration. We present the most recent results and review important findings from the last several years. Studies conducted in the opencast mines focus on soil development and Late Quaternary geomorphodynamics and as well as past land use and the legacy of agriculture and woodland use. Our results regarding the human-induced geomorphodynamics are similar to those in other regions in Central Europe, but we also observe regional differences caused by the local setting, e.g., intensification of soil erosion coinciding with the expansion of farming of cultivated lands in the Slavic Middle Ages. By analyzing LiDAR data the largest area of historical charcoal production in the Northern European Lowland (NEL) has been revealed. We are clearly only beginning to understand the massive dimensions of charcoal production in the region and the impact on late Holocene geomorphodynamics. The usage of new high-resolution imagery is essential to identify small-scale anthropogenic landforms hidden in the landscape. Future work will consist of developing and improving our integrative approach. However, comprehensive ground truth data provided by the archaeological prospections in the open-cast mines are an excellent basis for GIS-based analyses of high-resolution ALS data and geomorphological research. Y1 - 2015 UR - http://www.mineralogicalassociation.ca/doc/2015_Joint_Assembly_Abstract_Proceedings.pdf N1 - ES33A-01 SP - 135 EP - 136 ER - TY - CHAP A1 - Schneider, Anna A1 - Takla, Melanie A1 - Raab, Alexandra A1 - Raab, Thomas A1 - Hirsch, Florian A1 - Rösler, Horst T1 - Mapping historic charcoal production fields from excavation to landscape scale T2 - AGU Joint Assembly, Montreal, 2015, abstracts listing N2 - In the forefield of the open-cast mine Jänschwalde (north of Cottbus, Germany), archaeological excavations have revealed one of the largest charcoal production fields described so far. As remains of the historic charcoal kilns, small mounds of sediment rich in charcoal fragments and ash cover the soil surface. We applied a combination of methods for mapping such kiln relicts across a range of scales, in order to analyze the spatial distribution of kiln sites and to improve the understanding of historic forest use systems. In archaeological excavations in the mine forefield, the geometry of kiln relicts could be studied in high detail. We used a microdrone to record high-resolution photographs of excavation sites for the documentation of kiln site ground plans and other traces of historic land use. Based on airborne laser scanning elevation models, kiln site mapping was extended to areas beyond the mine forefield. Manual digitization from shaded relief maps was used for mapping kiln sites in further woodland areas surrounding an historic ironwork north of Cottbus. An automated mapping approach based on template matching was developed to detect charcoal production fields on a larger scale, and was applied for an area of about 1000 km2up to now. In archaeological excavations, about 900 kiln sites have been documented on an approximately 17 km2 large area. Excavation documentations and aerial photographs show variations in the kiln site ground plans. By manual digitization from Shaded Relief Maps, more than 5000 kiln sites with diameters up to 29 m were detected in the 32 km2 area of the royal forest Jänschwalder Heide north of Cottbus. First results of mapping for larger areas indicate similar densities, but smaller diameters of kiln sites in other charcoal production fields; and show that charcoal production is a so far underestimated component of the land use history in many areas in the Northern European Lowlands. Y1 - 2015 UR - http://www.mineralogicalassociation.ca/doc/2015_Joint_Assembly_Abstract_Proceedings.pdf N1 - GA44A-0124 SP - 168 ER - TY - CHAP A1 - Hirsch, Florian A1 - Bauriegel, Albrecht A1 - Bonhage, Alexander A1 - Schneider, Anna A1 - Raab, Thomas T1 - Occurrence, micromorphology, and soil chemistry of Fuchserden (Rhodic Arenosols) on sandy deposits in northeastern Germany T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - In the sandy deposits from the Late Pleistocene in the Northern European lowlands, the local appearance of red subsoils emerges the question of their formation and palaeoenvironmental significance. According to the WRB this soil is classified as Rhodic Arenosols, but in the German Guidelines for Soil Mapping this soil is still unconsidered because the age and genesis is unclear. Due to the intense red subsoil, the working title of this soil is ‘Fuchserde’. Whereas rubefication is a characteristic feature of soils in regions with warm and dry summers like in the Mediterranean, the occurrence of red subsoil horizons containing hematite in soils in northeastern Germany is not an indicator for tropic or Mediterranean climate conditions. Already the appearance of Fuchserden on sandy deposits from the last glaciation objects earlier theories that consider these soils as a relictic soil formation from the last interglacial or even the Palaeogene or Neogene. To characterize the genesis of the Fuchserden, we focused on four different study sites in northeastern Germany. We present our findings from soil micromorphology and the identification of the iron(hydr)oxides by FTIR. Our results give new insights on the development of the Fuchserden and the importance of lateral input of iron for their genesis. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-4000-1.pdf N1 - EGU2017-4000-1 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Hirsch, Florian A1 - Maaten-Theunissen, Marieke van der A1 - Maaten, Ernst van der A1 - Schneider, Anna A1 - Raab, Alexandra A1 - Raab, Thomas T1 - Soil physics and chemistry at a medieval ridge and furrow site in northeastern Germany T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - The usage of non-reversible ploughs, mainly during the Middle Ages and until historic times, led to the formation of ridge and furrow systems. Due to improvements of agricultural techniques, these historic agricultural sites were often abandoned and are now marginal land. The parallel ridges and furrows are usually, if not destroyed by later conventional ploughing, preserved in present-day forests. In northeastern Germany ridge and furrow systems are normally several decameters long and up to ten meters wide. The height difference between ridge top and furrow bottom is up to 50 centimeters and is expected to cause significant contrasts of soil properties and vegetation. Furthermore, due to the abandonment of sites with ridges and furrows, soils on these sites are unique archives for studies on fertilization, soil carbon dynamics and soil development. Therefore, we are characterizing soil physics (bulk density, saturated soil hydraulic conductivity, texture) and soil chemistry (soil acidity, carbon and nitrogen content) on a type location of historic ridges and furrows about 100 km northwest of Berlin. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-4003-1.pdf N1 - EGU2017-4003-1 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas A1 - Ouimet, William A1 - Dethier, David A1 - Schneider, Anna A1 - Raab, Alexandra T1 - Soils on historic charcoal hearths – chemical properties and terminology T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - Charcoal hearths are a unique archive for the long term interaction between biochar, soil development and plant growth. Charcoal as raw material was crucial for the production of iron in iron works and hence numerous charcoal hearths can be found in the forests near historic iron works in Europe as well as the Eastern United States. Charcoal hearths are round to elliptical forms often around 10 m in diameter, and consisting of a several decimeter thick layer containing charcoal fragments, ash, and burnt soil. We studied the soil chemistry of 24 charcoal hearths and compared them to the surrounding ‘natural’ soils in Litchfield County, Connecticut. The thickness of the organic rich horizons on the charcoal hearths and their carbon content is remarkably higher than in the surrounding topsoils. The wide distribution of charcoal hearths, their usually high quantity, and their occurrence in different ecosystems underlines their importance for further pedological research. Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?http://meetingorganizer.copernicus.org/EGU2017/EGU2017-4009-1.pdf N1 - EGU2017-4009-1 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Raab, Thomas A1 - Hirsch, Florian A1 - Vasserman, Oleksandr A1 - Raab, Alexandra A1 - Naeth, M. Anne T1 - Influence of relief and vegetation on soil properties in a disturbed chernozem soil landscape T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - In central and southeastern Alberta, chernozems dominate the soil landscape and are divided into several groups that follow the climate gradient from Northwest to Southeast: Dark Grey Chernozems, Black Chernozems, Dark Brown Chernozems; Brown Chernozems. Principles controlling development and distribution of these chernozem subtypes along the ecotone transect are quite well known. However, intensive land use over the last century has affected soils that originally have formed under natural conditions during the Holocene in more than 10,000 years. There is a lack of knowledge regarding soil development in these landscapes on the decadal to centennial time scale. Within this time frame the most important factor of soil formation may be relief, although this has not been properly studied. This study aims to compare soil properties in a typical chernozem landscape where soils have been highly disturbed and parent materials have been re-arranged by surface coal mining.We hypothesize that within 50 years, soils develop with significant differences based on vegetation type and slope aspect. Our study site is the former Diplomat Mine near Forestburg, Alberta where spoils form a small scale ridge and graben topography. The south facing slopes of the piles are covered by grassland, whereas on the north exposition has trees and shrubs. Samples were taken from six sites with differences in topography and vegetation type. Diplomate T1 is at the top of the ridge with grassland, Diplomate S1 is on the southern slope with grassland, Diplomate N1 is on the northern slope with trees, and Diplomate N2 is on the northern slope with shrubs. For comparison we took samples from two sites without slope aspect. One site was an undisturbed grassland (Diplomate Z1) and the other sites were reclaimed piles (Diplomate R1). At each site, five soil profiles were examined and volumetrically sampled (250 cm3 steel ring) in steps of five centimeters to a depth of 30 centimeters. We present first results of basic physical and chemical soil parameters (bulk density, water content, pH, Cstock, N-stock). Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-2332.pdf N1 - EGU2017-2332 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Schneider, Anna A1 - Hirsch, Florian A1 - Raab, Alexandra A1 - Bonhage, Alexander A1 - Raab, Thomas T1 - Assessing the legacy effects of historic charcoal production in Brandenburg, Germany T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - Charcoal produced in kilns or hearths was an important source of energy in many regions of Europe and Northern America until the 19th century, and charcoal production in hearths is still common in many other regions of the world. The remains of charcoal hearths are therefore a widespread legacy of historic land use in forest areas. Soils on charcoal hearth sites are characterized by a technogenic layer rich in charcoal and ash on top of the soil profile, and by a pyrogenic modification of substrates below the former hearth. The aims of our study are to examine how these alterations to the natural soil profiles affect the soil water regime and other soil physical properties, and to assess the relevance of these effects on the landscape scale. We present first results of a mapping of hearth site occurrence in forest areas in the state of Brandenburg, Germany, and of a characterization of the infiltration behaviour on hearth sites as compared with undisturbed forest soils. Results of mapping small-scale relief features from LIDAR-based digital elevation models show that charcoal hearths occur in a high density in many large forest areas throughout Brandenburg. In the areas studied so far, up to almost 3% of the soil surface were found to be affected by the remains of historic hearths. First analyses of soil physical properties indicate differences in the infiltration characteristics of hearth site soils and undisturbed forest soils: Hood infiltrometer measurements show a very high spatial variability of hydraulic conductivity for hearth site soils, and water-drop-penetration-time tests reflect extremely high hydrophobicity of the technogenic layer on the sites. Results of dye tracer experiment show considerably strong preferential flow and therefore a higher spatial variability of soil wetness below the hearth remains. Overall, our first results therefore indicate that the legacy effects of historic charcoal production might significantly affect overall site conditions in forest areas with a high density of charcoal hearth remains. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-6096-1.pdf N1 - EGU2017-6096-1 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Raab, Alexandra A1 - Schneider, Anna A1 - Bonhage, Alexander A1 - Raab, Thomas A1 - Hirsch, Florian T1 - Extensive historical charcoal production in Brandenburg (Germany) – identification of potential areas by GIS analysis T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - We used a GIS analysis of environmental and historical data to identify potential areas of extensive charcoal production in Brandenburg. The analysis was based on three assumptions (i to iii). Large charcoal kiln fields can be found in areas that i) are close to historical industrial sites, ii) are close to bog iron ore deposits, and iii) have been continuously covered by forest during the last centuries. Information on theses parameters was gathered in an archive and literature study and from historical and recent maps. Areas with a high probability of kiln site occurrence were then determined using a simple binary additive model. In the last step, shaded-relief maps (SRMs) were visually checked for clearly visible kiln sites and soil properties were analysed in the determined areas. In total, eight areas with a high probability of kiln site occurrence are identified for the state of Brandenburg. By visual interpretation of SRMs, high kiln site densities in these areas are confirmed. The analysis of soil maps shows that kiln fields are predominantly located on sandy soils with a low yield potential. Although further parameters and study areas need to be considered in the model in order to explain the spatial distribution patterns of charcoal production, the results indicate correlations between the location of bog iron ore deposits, historic ironworks and charcoal kiln fields. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-2976.pdf N1 - EGU2017-2976 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Schneider, Anna A1 - Hirsch, Florian A1 - Wechler, Klaus-Peter A1 - Raab, Alexandra A1 - Raab, Thomas T1 - Mapping a paleosurface and archaeological site location in an inland dune area in Brandenburg, Germany T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - Mapping and visualizing the position of archaeological remains in the surface relief provides important basic information for archaeological survey design and interpretation. Geomorphological processes in (pre)history can have resulted in a modification of the local relief around archaeological sites, especially in areas that are prone to sediment erosion and relocation, so that models of past surfaces are necessary for a correct interpretation of archaeological survey results. In this study, we combined terrestrial survey and remote sensing methods to reconstruct the palaeorelief around two archaeological excavation sites in an inland dune area in southern Brandenburg, Germany. Remains from two Mesolithic hunter-gatherer camps were documented in archaeological excavations and found to be associated with a buried soil horizon. To gather information on the relief of the buried soil surface, we used a combination of sedimentological and pedological profile description of archaeological survey trenches and geophysical prospection with Ground-Penetrating Radar; supplemented by microdrone photography and photogrammetry, GPS surveys and analysis of LIDAR-based elevation models. A digital elevation model of the buried surface was created by combining point data from these sources. The buried surface morphology and the position of the archeological remains within the reconstructed landscape were analyzed in GIS. The comparison of the generated paleosurface model with the recent surface elevation model shows that sand remobilization resulted in a considerable reshaping of the relief. Analysis of the buried surface model further shows that the relief position of the two archaeological sites in the study area was considerably more prominent in relation to the corresponding buried soil surface than in relation to the recent surface morphology. Results affirm the importance of considering Holocene relief modifications in archaeological surveys. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-6066-1.pdf N1 - EGU2017-6066-1 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Hirsch, Florian A1 - Dietrich, Nils A1 - Knoop, Christine A1 - Raab, Thomas T1 - Micromorphology of pelletized soil conditioners T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - Soil conditioners produced by anaerobic digestion and subsequent composting of organic household waste, bear the potential to improve unproductive farmland together with a reduced input risk of unwanted pollutants into the soils. Within the VeNGA project (http://www.biogas-network.de/venga), soil conditioners from anaerobically digested organic household waste are tested for their potential to increase plant growth in glasshouse and field experiments. Because the production techniques of these soil conditioners may influence their physical and chemical behaviour in the soil, two different techniques for pelletizing the soil conditioners where applied. We present findings from a pot experiment with cereal that has been sampled after two months for micromorphological analyses.We visualize the decomposition and the physical behaviour of the soil conditioners. Pellets produced in an agglomeration mixer result in dense balls, that are only slightly decomposed after the trial. But the soil conditioners created under pressure in a screw extruder are rich in voids and have the potential of retaining more soil water. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-3996.pdf N1 - EGU2017-3996 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Hirsch, Florian A1 - Raab, Thomas T1 - The Finow soil – a stratigraphic marker or just a pedologic horizon? T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - Palaeosoils indicate periods of landscape stability, and therefore warmer periods during the cold climate conditions of the Late Pleistocene, when pedogenic processes can shape the surface. Therefore, in Late Pleistocene glacial and periglacial deposits, palaeosoils are widely used as chronostratigraphic markers. However, in contrast to limnic archives the records in terrestrial sediments are often discontinuous or ambiguous. The so called Finow soil is commonly found as 5 to 15 cm thick and fossilized horizon, characterized by brunification and the illuviation of clay in the sandy deposits of Northern Central Europe. We present a micromorpological approach together with OSL ages, that contradicts the stratigraphic potential of the Finow soil and also questions the suitability of soil horizons formed by clay illuviation as stratigraphic markers. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-3997.pdf N1 - EGU2017-3997 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Raab, Thomas A1 - Raab, Alexandra A1 - Hirsch, Florian A1 - Schneider, Anna A1 - Bonhage, Alexander ED - Schwab, Markus ED - Błaszkiewicz, Mirek ED - Raab, Thomas ED - Wilmking, Martin ED - Brauer, Achim T1 - Late Quaternary landscape development and legacies of human‐induced land use changes in Lower Lusatia, South Brandenburg, Germany T2 - ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume & Excursion Guide Y1 - 2017 UR - http://gfzpublic.gfz-potsdam.de/pubman/item/escidoc:2215927 U6 - https://doi.org/10.2312/GFZ.b103-17037 SP - 182 EP - 198 PB - GFZ German Research Centre for Geosciences CY - Potsdam ER - TY - CHAP A1 - Hirsch, Florian A1 - Schneider, Anna A1 - Raab, Alexandra A1 - Raab, Thomas A1 - Ouimet, William A1 - Dethier, David ED - Schwab, Markus ED - Błaszkiewicz, Mirek ED - Raab, Thomas ED - Wilmking, Martin ED - Brauer, Achim T1 - Late Holocene biochar enrichment in soils ‐ implications of an anthropogenic legacy for ecosystems T2 - ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume & Excursion Guide Y1 - 2017 UR - http://gfzpublic.gfz-potsdam.de/pubman/item/escidoc:2215927 U6 - https://doi.org/10.2312/GFZ.b103-17037 SP - 79 EP - 81 PB - GFZ German Research Centre for Geosciences CY - Potsdam ER - TY - CHAP A1 - Schneider, Anna A1 - Hirsch, Florian A1 - Raab, Alexandra A1 - Raab, Thomas ED - Schwab, Markus ED - Błaszkiewicz, Mirek ED - Raab, Thomas ED - Wilmking, Martin ED - Brauer, Achim T1 - Dye tracer visualization of infiltration patterns in soils on historic charcoal hearth sites T2 - ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume & Excursion Guide Y1 - 2017 UR - http://gfzpublic.gfz-potsdam.de/pubman/item/escidoc:2215927 U6 - https://doi.org/10.2312/GFZ.b103-17037 SP - 150 EP - 151 PB - GFZ German Research Centre for Geosciences CY - Potsdam ER - TY - CHAP A1 - Schneider, Anna A1 - Hirsch, Florian A1 - Wechler, Klaus-Peter A1 - Raab, Alexandra A1 - Raab, Thomas ED - Schwab, Markus ED - Błaszkiewicz, Mirek ED - Raab, Thomas ED - Wilmking, Martin ED - Brauer, Achim T1 - Mapping a palaeosurface and archaeological site location in an anthropogenic drift sand area T2 - ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume & Excursion Guide Y1 - 2017 UR - http://gfzpublic.gfz-potsdam.de/pubman/item/escidoc:2215927 U6 - https://doi.org/10.2312/GFZ.b103-17037 SP - 152 EP - 154 ER - TY - CHAP A1 - Schneider, Anna A1 - Raab, Alexandra A1 - Hirsch, Florian A1 - Bonhage, Alexander A1 - Raab, Thomas ED - Schwab, Markus ED - Błaszkiewicz, Mirek ED - Raab, Thomas ED - Wilmking, Martin ED - Brauer, Achim T1 - Assessing the legacies of historical charcoal production in Brandenburg T2 - ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume & Excursion Guide Y1 - 2017 UR - http://gfzpublic.gfz-potsdam.de/pubman/item/escidoc:2215927 U6 - https://doi.org/10.2312/GFZ.b103-17037 SP - 155 EP - 156 PB - GFZ German Research Centre for Geosciences CY - Potsdam ER - TY - GEN A1 - Hirsch, Florian A1 - Raab, Thomas A1 - Heller, Sebastian A1 - Bauriegel, Albrecht T1 - Classification of pedogenic cementation in Podzols by pocket penetrometry T2 - Journal of Plant Nutrition and Soil Science N2 - According to the German Soil Taxonomy, the formation of cemented horizons in Podzols is restricted to the precipitation of iron oxides. However, in iron-poor sandy substrates, also illuviation of only organic compounds can form cemented horizons with penetration resistances of up to 14 kg cm−2. We present a reproducible field test for classifying pedogenic cementation in Podzols and suggest considering cemented horizons (Bmh and Bhm) in the upcoming edition of the Guidelines for Soil Mapping. KW - field techniques KW - micromorphology KW - soil classification KW - soil development KW - soil systematics Y1 - 2017 UR - http://onlinelibrary.wiley.com/doi/10.1002/jpln.201600395/abstract U6 - https://doi.org/10.1002/jpln.201600395 SN - 1522-2624 VL - 180 IS - 4 SP - 430 EP - 435 ER - TY - GEN A1 - Hirsch, Florian A1 - Raab, Thomas A1 - Ouimet, William A1 - Dethier, David A1 - Schneider, Anna A1 - Raab, Alexandra T1 - Soils on historic charcoal hearths - terminology and chemical properties T2 - Soil Science Society of America Journal : SSSAJ N2 - Historic charcoal hearth remains provide a unique archive of the long term interaction between biochar, soil development and plant growth. Charcoal as raw material was crucial for production of iron in iron works and hence numerous charcoal hearths can be found in the forests near historic iron works in Europe as well as the Eastern United States. Charcoal hearths are round to elliptical forms often around 10 m in diameter, and consist of several decimeter thick layers that contain charcoal fragments, ash, and burnt soil. We studied the soil chemistry of 24 charcoal hearths and compared them to the surrounding ‘natural’ soils in the northern Appalachians of northwestern Connecticut. The thickness of the topsoils on the charcoal hearths and their carbon content are remarkably higher than in the surrounding topsoils. The presence of residual products from charcoal production classifies the soils as Anthropic Udorthents (US Soil Taxonomy) or Spolic Technosols (Humic) according to the World Reference Base for Soil Resources. The widespread occurrence of charcoal hearth remains and their high spatial density in different ecosystems underlines their importance for further pedological research. KW - biochar KW - pedogenesis KW - land use KW - carbon sink Y1 - 2017 U6 - https://doi.org/10.2136/sssaj2017.02.0067 SN - 1435-0661 SN - 0361-5995 VL - 81 IS - 6 SP - 1427 EP - 1435 ER - TY - CHAP A1 - Raab, Thomas A1 - Schneider, Anna A1 - Raab, Alexandra A1 - Hirsch, Florian A1 - Bonhage, Alexander ED - Holzheu, Stefan ED - Thies, Birgit T1 - The geomorphic legacy of historic charcoal production in Brandenburg, Germany T2 - 4th Central European Geomorphology Conference, Bayreuth, October 9th-13th 2017 Y1 - 2017 SP - 117 EP - 118 CY - Bayreuth ER - TY - CHAP A1 - Hirsch, Florian A1 - Bauriegel, Albrecht A1 - Bonhage, Alexander A1 - Schneider, Anna A1 - Raab, Thomas T1 - Fuchserden in Brandenburg – Vorkommen, Mikromorphologie und Bodenchemie T2 - Abstracts der Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, Göttingen, 2017 Y1 - 2017 UR - http://dbg17.abstract-dialog.de/search/abstract_detail.php?aId=360 PB - DBG CY - Göttingen ER -