TY - GEN A1 - Spröte, Roland A1 - Fischer, Thomas A1 - Veste, Maik A1 - Raab, Thomas A1 - Wiehe, Wolfgang A1 - Lange, Philipp A1 - Bens, Oliver A1 - Hüttl, Reinhard F. T1 - Biological topsoil crusts at early successional stages on recultivated post-mining sites in Brandenburg, NE Germany Y1 - 2010 ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Repmann, Frank A1 - Fischer, Thomas A1 - Raab, Thomas T1 - Retardation of iron-cyanide complexes in soils of a former Manufactured Gas Plant site T2 - Book of abstracts, XII International Congress of Young Chemists, YoungChem2014, Szczecin, Poland 8th-12th October 2014 Y1 - 2014 SN - 978-83-61037-28-6 SP - S. 44 CY - Warsaw ER - TY - GEN A1 - Bonhage, Alexander A1 - Mykhailova, Larysa A1 - Hirsch, Florian A1 - Schneider, Anna A1 - Raab, Thomas A1 - Fischer, Thomas A1 - Raab, Alexandra A1 - Donovan, Sally A1 - Ouimet, William T1 - Effects of historical charcoal burning on soil landscapes in West Connecticut - Quantifying pyrogenic and organic soil carbon content of Technosols by FTIR analysis T2 - European Geosciences Union, General Assembly 2019, Vienna, Austria, 7–12 April 2019 Y1 - 2019 UR - https://meetingorganizer.copernicus.org/EGU2019/EGU2019-3115.pdf CY - Katlenburg-Lindau ER - TY - GEN A1 - Preußer, Daniel A1 - Bröring, Udo A1 - Fischer, Thomas A1 - Juretzek, Thomas T1 - Effects of antibiotics ceftriaxone and levofloxacin on the growth of Calliphora vomitoria L. (Diptera: Calliphoridae) and effects on the determination of the post-mortem interval T2 - Journal of Forensic and Legal Medicine N2 - The determination of the post-mortem interval (PMI) is one of the main tasks of forensic entomology, where growth and stages of development of arthropods are used for PMI determination. It is well acknowledged that maggot development is significantly influenced by temperature. Attention has also been paid to the microbial populations of the cadaver, because toxic substances contained in the substrate can influence the microorganisms and affect arthropods growth and development. However, little is known about the influence of antibiotics taken during lifetime of a person on insect development after that persons death. The aim of this study was to test the hypothesis that the antibiotics ceftriaxone and levofloxacin cause inhibition of growth and delay of pupation of the blow fly Calliphora vomitoria, which would then lead to an incorrect determination of the post-mortem interval in forensic cases. It was found that maggot development was delayed by levofloxacin mixed in minced pork, where a mixture of both antibiotics increased this effect. The maggot growth in the samples with ceftriaxone was not delayed. Pupation was delayed in treatments with a mixture of both antibiotics. The mortality was reduced by separate or combined application of ceftriaxone and levofloxacin, which we attribute to a bactericidal effect of the antibiotics on maggot pathogens. Depending on the concentration of the antibiotics, an underestimation of the post-mortem interval between 24 and 48 h could be suspected. We conclude that antibiotics need to be considered if instar stages are to be used to determine the PMI and that some antibiotics may improve the breeding conditions of maggots. KW - Antibiotics KW - Blowflies KW - Entomotoxicology KW - Post-mortem interval Y1 - 2021 U6 - https://doi.org/10.1016/j.jflm.2021.102207 SN - 1878-7487 SN - 1752-928X VL - 81 IS - 5 ER - TY - GEN A1 - Bonhage, Alexander A1 - Raab, Thomas A1 - Schneider, Anna A1 - Fischer, Thomas A1 - Ramezany, Shaghayegh A1 - Ouimet, William A1 - Raab, Alexandra A1 - Hirsch, Florian T1 - Vertical SOC distribution and aromatic carbon in centuries old charcoal-rich Technosols T2 - European Journal of Soil Science N2 - Charcoal-rich Technosols on century-old relict charcoal hearths (RCHs) are the subject of ongoing research regarding potential legacy effects that result from historic charcoal production and subsequent charcoal amendments on forest soil properties and forest ecosystems today. RCHs consist mostly of Auh horizons that are substantially enriched in soil organic carbon (SOC), of which the largest part seems to be of pyrogenic origin (PyC). However, the reported range of SOC and PyC contents in RCH soil also suggests that they are enriched in nonpyrogenic SOC. RCH soils are discussed as potential benchmarks for the long-term influence of biochar amendment and the post-wildfire influences on soil properties. In this study, we utilised a large soil sample dataset (n = 1245) from 52 RCH sites in north-western Connecticut, USA, to quantify SOC contents by total element analysis. The contents of condensed highly aromatic carbon as a proxy for black carbon (BC) were predicted by using a modified benzene polycarboxylated acid (BPCA) marker method in combination with diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy-based partial least square regression (r2 = 0.89). A high vertical spatial sampling resolution allowed the identification of soil organic matter (SOM) enrichment and translocation processes. The results show an average 75% and 1862% increase in TOC and BPCA-derived carbon, respectively, for technogenic Auh horizons compared to reference soils. In addition to an increase in aromatic properties, increased carboxylic properties of the RCH SOC suggest self-humification effects of degrading charcoal and thereby the continuing formation of leachable aromatic carbon compounds, which could have effects on pedogenic processes in buried soils. Indeed, we show BPCA-derived carbon concentrations in intermediate technogenic Cu horizons and buried top/subsoils that suggest vertical translocation of highly aromatic carbon originating in RCH Auh horizons. Topmost Auh horizons showed a gradual decrease in total organic carbon (TOC) contents with increasing depth, suggesting accumulation of recent, non-pyrogenic SOM. Lower aliphatic absorptions in RCH soil spectra suggest different SOM turnover dynamics compared to reference soils. Furthermore, studied RCH soils featured additional TOC enrichment, which cannot be fully explained now. Y1 - 2022 UR - https://bsssjournals.onlinelibrary.wiley.com/doi/10.1111/ejss.13293 U6 - https://doi.org/10.1111/ejss.13293 VL - 73 IS - 4 SP - 1 EP - 16 ER - TY - GEN A1 - Preußer, Daniel A1 - Fischer, Thomas A1 - Juretzek, Thomas T1 - Effects of antibiotics ceftriaxone and levofloxacin on the growth of Protophormia terraenovae (Diptera: Calliphoridae) T2 - Forensic Science, Medicine and Pathology N2 - AbstractProtophormia terraenovae is a colonizer of decomposing bodies and is known to cause pre-mortem myiasis as the female flies lay eggs in uncleaned wounds. In this study the effects of different concentrations of antibiotics levofloxacin and ceftriaxone on maggot development, weight, length, and mortality were examined. The maggot length and weight were significantly increased by therapeutical doses of levofloxacin and ceftriaxone. The maggot development time was significantly decreased in every levofloxacin treatment compared to the control. The time to start pupation was significantly increased in the control compared to the antibiotic treatments. Levofloxacin significantly increased the survivability of the maggots. Every levofloxacin treatment significantly improved the rearing conditions for the maggots. Reaching the third instar was delayed by 24 h in the control compared to the Levo 3.57 treatment. The Pupation in the control was delayed by an average of 48 h compared to the Levo 3.57 treatment. The significantly reduced development time of the maggots in the antibiotic treatments might lead to an overestimation of the post-mortem interval and therefore an incorrect time of death determination. The improved rearing conditions may be an indication of the potential of a combined application of antibiotics and maggot therapy. KW - General Medicine KW - Pathology and Forensic Medicine Y1 - 2024 U6 - https://doi.org/10.1007/s12024-024-00804-9 SN - 1556-2891 SP - 1 EP - 13 ER - TY - GEN A1 - Preußer, Daniel A1 - Fischer, Thomas A1 - Juretzek, Thomas T1 - Effects of antibiotics ceftriaxone and levofloxacin on the growth of Lucilia sericata (Diptera: Calliphoridae) T2 - Medical and Veterinary Entomology N2 - Lucilia sericata is one of the most studied species in forensic entomology due to its widespread distribution, forensic importance as well as medical use. The growth and development stage of maggots is often used to determine the post-mortem interval in forensic cases. L. sericata can cause myiasis in humans who are not able to maintain personal hygiene due to age or medical condition and can therefore be used to determine the time period of neglect. The influence of the temperature on the maggot development has been examined in various studies. Different examinations on the effects of toxic substances on the maggot development and survival have been conducted in order to test the influence and resulting deviations. In this study, the effects of different therapeutical doses of the antibiotics ceftriaxone and levofloxacin were examined on L. sericata in order to determine and compare deviations in maggot development and survival. The used antibiotics did not significantly influence the maggot weight and length. A significant delay in the time of pupation has been determined in the treatments with high concentrations of levofloxacin. The mortality was significantly increased in all treatments with antibiotics compared to the control, whereby the survivability of all treatments remained over 80%. Because of the high doses needed to produce an effect, we concluded that an overestimation of the post-mortem interval is unlikely but higher antibiotic concentrations or possible interactions with other medications could increase the maggot development time. KW - antibiotics KW - blow flies KW - entomotoxicology KW - myiasis KW - post‐mortem interval Y1 - 2023 U6 - https://doi.org/10.1111/mve.12685 SN - 0269-283X SN - 1365-2915 VL - 37 IS - 4 SP - 805 EP - 815 ER - TY - GEN A1 - Spröte, Roland A1 - Fischer, Thomas A1 - Veste, Maik A1 - Raab, Thomas A1 - Wiehe, Wolfgang A1 - Lange, Philipp A1 - Bens, Oliver A1 - Hüttl, Reinhard F. T1 - Biological topsoil crusts at early successional stages on Quaternary substrates dumped by mining in Brandenburg, NE Germany T2 - Geomorphologie: relief, processus, environnement N2 - The influence of biological soil crusts in natural ecosystems on structures and processes is well investigated. However, in South-Brandenburg (Germany), it is possible to study the development of biological soil crusts (BSC) during initial ecosystem genesis on two artificial water catchments with well-known ages and under differing starting conditions. The two experimental sites are located in the recultivation area of the lignite open-cast mining district of southern Brandenburg with a distance of approximately 1 km between them. Two different topographies were constructed at the experimental sites: the experimental plot at the catchment Neuer Lugteich was shaped like a dune, whereas the artificial water catchment Hühnerwasser was modelled as an inclined slope. The catchment Neuer Lugteich is four years older than Hühnerwasser. The original substrate at Neuer Lugteich is more sandy and carbonate-free compared to the original substrate dumped at Hühnerwasser. At both sites geomorphological differentiation and crust development were compared and the importance of substrate-dependent water availability and crust type clarified. Once settled, the crusts influenced the water regime of the soils by delaying infiltration through enhanced water repellency, and by limiting water infiltration. Chlorophyll analysis revealed that all crusts were at early stages of development. At Neuer Lugteich, the establishment of the biological soil crusts was closely associated with the vegetation succession, whereas no clear succession of the crusts could be observed at Hühnerwasser. The mosaic-like pattern of the biological soils crusts is associated with the distribution of fine-grained material here.zeige weniger Y1 - 2010 UR - http://geomorphologie.revues.org/8083 U6 - https://doi.org/10.4000/geomorphologie.8083 SN - 1957-777X VL - 16 IS - 4 SP - 359 EP - 370 ER - TY - GEN A1 - Hirsch, Florian A1 - Spröte, Roland A1 - Fischer, Thomas A1 - Forman, Steven L. A1 - Raab, Thomas A1 - Bens, Oliver A1 - Hüttl, Reinhard F. T1 - Late Quaternary aeloian dynamics, pedostratigraphy and soil formation in the North European Lowlands - new findings from the Baruther ice-marginal valley T2 - Die Erde N2 - The formation of dunes in central Europe reflects ample sediment supply during the last deglacial hemicycle. A Quaternary inland dune complex in southern Brandenburg, Germany, was studied to frame the duration of pedogenesis in two outcrops containing buried paleosols. An integrative approach, which combined geomorphological, sedimentological, pedological and chronological methods was used to identify aeolian deposition events, ensuing pedogenesis and anthropogenic remobilization. At the outcrops, which were situated approximately 2 km apart from each other, a total of twelve samples of the aeolian sands were dated using optically stimulated luminescence (OSL) and a further six samples using 14C dating. Although the dunes have similar morphological features, these forms have a different history of aeolian sand deposition and pedogenesis. At the older dune (Gl 1) the surface soil is a well developed Podzol, whereas soil development of the younger dune (Gl 2) is clearly in an initial state. The studied sites of the dune complex also differ in grain size distribution and in the presence of buried soils, thereby indicating a climatic impact on aeolian remobilization. Y1 - 2017 U6 - https://doi.org/10.12854/erde-148-30 SN - 0013-9998 VL - 148 IS - 1 SP - 58 EP - 73 ER - TY - CHAP A1 - Spröte, Roland A1 - Fischer, Thomas A1 - Veste, Maik A1 - Lange, Philipp A1 - Bens, Oliver A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Hydrophobicity in sandy soils triggered by the development of Scots Pine stands in southern Brandenburg, Germany T2 - EGU General Assembly 2010, held in Vienna, Austria, 02 – 07 May 2010 Y1 - 2010 UR - http://meetingorganizer.copernicus.org/EGU2010/EGU2010-4154.pdf N1 - EGU2010-4154 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Spröte, Roland A1 - Fischer, Thomas A1 - Veste, Maik A1 - Yair, Aaron A1 - Wiehe, Wolfgang A1 - Lange, Philipp A1 - Bens, Oliver A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Structures and processes of biological soil crusts during initial ecosystem genesis of an artificial watershed in Lusatia, NE Germany T2 - EGU General Assembly 2010, held Vienna, Austria, 02 – 07 May 2010 Y1 - 2010 N1 - EGU2010-4129 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Spröte, Roland A1 - Veste, Maik A1 - Fischer, Thomas A1 - Raab, Thomas A1 - Bens, Oliver A1 - Hüttl, Reinhard F. T1 - Development of biological soil crusts and their influence on soil hydrology in the recultivation area of lignite open-cast mining district in Lower Lusatia (Germany) T2 - EGU General Assembly 2012, held 22-27 April, 2012 in Vienna Y1 - 2012 N1 - EGU2012-6372 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Fischer, Thomas A1 - Spröte, Roland A1 - Veste, Maik A1 - Wiehe, Wolfgang A1 - Lange, Philipp A1 - Bens, Oliver A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Functions of biological soil crusts on central European inland dunes:Water repellency and pore clogging influence water infiltration T2 - EGU General Assembly 2010, held in Vienna, Austria, 02 – 07 May 2010 Y1 - 2010 UR - http://meetingorganizer.copernicus.org/EGU2010/EGU2010-4449.pdf N1 - EGU2010-4449 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Spröte, Roland A1 - Bens, Oliver A1 - Fischer, Thomas A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Soil water repellency as a phenomenon of initial soil formation – approaches and first results from the Transregional Collaborative Reserch Centre (SFB/TRR) 38 T2 - EGU General Assembly 2009, held in Vienna, Austria, 19 – 24 April 2009 Y1 - 2009 UR - http://adsabs.harvard.edu/abs/2009EGUGA..11.9008S N1 - EGU2009-9008 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Spröte, Roland A1 - Veste, Maik A1 - Fischer, Thomas A1 - Lange, Philipp A1 - Bens, Oliver A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Wie beeinflussen Kiefern (Pinus sylvestris L.) die Entwicklung der Benetzungshemmung auf Sandböden? T2 - Böden verstehen - Böden nutzen - Böden fit machen, Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, 3. - 9. September 2011 Y1 - 2011 UR - http://eprints.dbges.de/768/ ER - TY - CHAP A1 - Spröte, Roland A1 - Veste, Maik A1 - Fischer, Thomas A1 - Lange, Philipp A1 - Bens, Oliver A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Development of biologicalsoil crusts in initial ecosystems in Lusatia, Germany T2 - DBG Jahrestagung 2009 Bonn "Böden - eine endliche Ressource", 05.-13.09.2009, Bonn Y1 - 2009 UR - http://eprints.dbges.de/178/ ER - TY - GEN A1 - Elmer, Michael A1 - Bachmann, Ute A1 - Gutsch, Martin A1 - Schröder, Jens A1 - Bäucker, Ernst A1 - Lange, Mike A1 - Clauder, Lothar A1 - Bens, Oliver A1 - Suckow, Felicitas A1 - Kätzel, Ralf A1 - Bues, Claus-Thomas A1 - Frommhold, Heinz A1 - Sonntag, Herbert A1 - Fischer, Thomas A1 - Hüttl, Reinhard F. T1 - OakChain: Eichen-Kiefern-Mischbestände im Spannungsfeld von Klimawandel, Waldumbau und internationalem Holzmarkt T2 - Forst und Holz Y1 - 2009 SN - 0932-9315 VL - 64 IS - 7/8 SP - 26 EP - 29 ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Fischer, Thomas A1 - Repmann, Frank A1 - Raab, Thomas A1 - Dimitrova, Tsvetelina T1 - Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil T2 - Water, Air and Soil Pollution N2 - Vicinities of manufactured gas plants were often contaminated with solid iron–cyanide complexes as a result of the coal gasification process. During the remediation of affected soils, knowledge about contaminant concentrations is crucial, but laboratory methods are often expensive and time consuming. Rapid and non-destructive field methods for contaminant determination permit an analysis of large sample numbers and hence, facilitate identification of ‘hot spots’ of contamination. Diffuse near infrared reflectance spectroscopy has proven to be a reliable analytical tool in soil investigation. In order to determine the feasibility of a Polychromix Handheld Field Portable Near-Infrared Analyzer (FP NIR), various sample preparation methods were examined, including homogenizing, sieving, drying, and grinding. Partial least squares calibration models were developed to determine near infrared (NIR) spectral responses to the cyanide concentration in the soil samples. As a control, the contaminant concentration was determined using conventional flow injection analysis. The experiments revealed that portable near-infrared spectrometers could be a reliable device for detecting cyanide concentrations >2,400 mgkg−1 in the field and >1,750 mgkg−1 after sample preparation in the laboratory.We found that portable NIR spectrometry cannot replace traditional laboratory analyses due to high limits of detection, but that it could be used for identification of contamination ‘hot spots’. Y1 - 2012 U6 - https://doi.org/10.1007/s11270-012-1298-y SN - 1573-2932 VL - 223 IS - 8 SP - 5495 EP - 5504 ER - TY - CHAP A1 - Mykhailova, Larysa A1 - Raab, Thomas A1 - Gypser, Stella A1 - Fischer, Thomas T1 - Development and hydrology of biological soil crusts -- first results from a surface inoculation experiment T2 - European Geosciences Union, General Assembly 2016, Vienna, Austria, 17 April – 22 May 2016 Y1 - 2016 N1 - EGU2016-6129 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Fischer, Thomas A1 - Repmann, Frank A1 - Raab, Thomas T1 - Long-Term Release of Iron-Cyanide Complexes from the Soil of a Manufactured Gas Plant Site T2 - Journal of Environmental Protection N2 - Iron-cyanide (Fe-CN) complexes have been detected at Manufactured Gas Plant sites (MGP) worldwide. The risk of groundwater contamination depends mainly on the dissolution of ferric ferrocyanide. In order to design effective reme- diation strategies, it is relevant to understand the contaminant’s fate and transport in soil, and to quantify and mathe- matically model a release rate. The release of iron-cyanide complexes from four contaminated soils, originating from the former MGP in Cottbus, has been studied by using a column experiment. Results indicated that long-term cyanide (CN) release is governed by two phases: one readily dissolved and one strongly fixed. Different isotherm and kinetic equations were used to investigate the driving mechanisms for the ferric ferrocyanide release. Applying the isotherm equations assumed an approach by which two phases were separate in time, whereas the multiple first order equation considered simultaneous occurrence of both cyanide pools. Results indicated varying CN release rates according to the phase and soil. According to isotherm and kinetic models, the long-term iron cyanide release from the MGP soils is a complex phenomenon driven by various mechanisms parallely involving desorption, diffusion and transport processes. Phase I (rapid release) is presumably mainly constrained by the transport process of readily dissolved iron-cyanide complexes combined with desorption of CN bound to reactive heterogeneous surfaces that are in direct contact with the aqueous phase (outer-sphere complexation). Phase II (limited rate) is presumably driven by the diffusion controlled processes involving dissolution of precipitated ferric ferrocyanide from the mineral or inner-sphere complexation of fer- ricyanides. CN release rates in phase I and II were mainly influenced by the pH, organic matter (OM) and the total CN content. The cyanide release rates increased with increasing pH, decreased with low initial CN concentration and were retarded by the increase in OM content. Y1 - 2013 U6 - https://doi.org/10.4236/jep.2013.411A2002 SN - 2152-2219 VL - 4 IS - 11B SP - 8 EP - 19 ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Fischer, Thomas A1 - Repmann, Frank A1 - Raab, Thomas T1 - Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil T2 - European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 – 12 April 2013 N2 - In Germany, at more than 1000 sites, soil is polluted with an anthropogenic contaminant in form of iron-cyanide complexes. These contaminations are caused by former Manufactured Gas Plants (MGPs), where electricity for lighting was produced in the process of coal gasification. The production of manufactured gas was restrained in 1950, which caused cessation of MGPs. Our study describes the application of Polychromix Handheld Field Portable Near-Infrared (NIR) Analyzer to predict the cyanide concentrations in soil. In recent times, when the soil remediation is of major importance, there is a need to develop rapid and non-destructive methods for contaminant determination in the field. In situ analysis enables determination of ‘hot spots’, is cheap and time saving in comparison to laboratory methods. This paper presents a novel usage of NIR spectroscopy, where a calibration model was developed, using multivariate calibration algorithms, in order to determine NIR spectral response to the cyanide concentration in soil samples. As a control, the contaminant concentration was determined using conventional Flow Injection Analysis (FIA). The experiments revealed that portable near-infrared spectrometers could be a reliable device for identification of contamination ‘hot spots’, where cyanide concentration are higher than 2400 mg kg-1 in the field and >1750 mg kg-1 after sample preparation in the laboratory, but cannot replace traditional laboratory analyses due to high limits of detection. Y1 - 2013 UR - http://meetingorganizer.copernicus.org/EGU2013/EGU2013-1986.pdf N1 - EGU2013-1986 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Rodionov, Andrei A1 - Nii-Annang, Seth A1 - Fischer, Thomas A1 - Gattinger, Andreas A1 - Bens, Oliver A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Cross-linked polyacrylates in post-mining substrates: persistence and effects on plant growth T2 - Soil Use and Management N2 - Application of hydrophilic polymers composed of cross-linked polyacrylate can improve soil water-holding capacity and accelerate the restoration of post-mining substrates. In this work, we studied the persistence of a polyacrylate polymer incorporated into a soil and its impact on plant nutrients at a reclamation site of former lignite mining in Lusatia (Germany). In contrast to autumn application, the incorporation of the polymer enhanced the sequestration of plant-derived carbon in the soil, which was reflected by a significant increase in the concentration of a lignin marker. Attenuated total reflexion–Fourier transform infrared spectra (ATR-FTIR) and total elemental contents in the applied polymer suggested an intensive cation exchange between the polymer framework and the soil-forming substrate. In addition, there was an enrichment of carbonaceous material, which seems to reduce the swelling and thus the water-holding capacity of the cross-linked polyacrylate. Conversely, this process protected the polymer structure from rapid decomposition. Y1 - 2014 U6 - https://doi.org/10.1111/sum.12103 SN - 1475-2743 VL - 30 IS - 1 SP - 78 EP - 87 ER - TY - CHAP A1 - Bachmann, Ute A1 - Bens, Oliver A1 - Elmer, Michael A1 - Fischer, Thomas A1 - Raab, Thomas A1 - Hüttl, Reinhard F. ED - Elmer, Michael ED - Kätzel, Ralf ED - Bens, Oliver ED - Bues, Claus-Thomas ED - Sonntag, Herbert ED - Hüttl, Reinhard F. T1 - Boden und Standortqualität T2 - Nachhaltige Bewirtschaftung von Eichen-Kiefern-Mischbeständen : im Spannungsfeld von Klimawandel, Waldumbau und internationalem Holzmarkt Y1 - 2009 SN - 978-3-86581-196-7 SP - 31 EP - 44 PB - oekom CY - München ER - TY - GEN A1 - Fischer, Thomas A1 - Bergmann, Charlotte A1 - Hüttl, Reinhard F. T1 - Soil carbon and nitrogen budget in Scots pine (Pinus sylvestris L) stands along an air pollution gradient in Eastern Germany Y1 - 1995 ER - TY - GEN A1 - Bergmann, Charlotte A1 - Fischer, Thomas A1 - Hüttl, Reinhard F. T1 - Significance of litter- and humus-layer quality for rates and forms of N cycling in moder- to rawhumus-moder profiles under Scots pine (Pinus sylvestris L.) Y1 - 1999 ER - TY - GEN A1 - Fischer, Thomas T1 - Substantial rewetting phenomena on soil respiration can be observed at low water availability Y1 - 2009 ER - TY - GEN A1 - Fischer, Thomas A1 - Veste, Maik A1 - Wiehe, Wolfgang A1 - Lange, Philipp T1 - Water repellency and pore clogging at early successional stages of microbiotic crusts on inland dunes, Brandenburg, NE Germany Y1 - 2010 ER - TY - CHAP A1 - Fischer, Thomas T1 - Following chemical changes of Scots pine (Pinus sylvestris L.) root litter during decomposition using FTIR T2 - Woody root processes – Impact of different tree species, University of Tartu, Estonia, 05-09 June 2005 Y1 - 2005 SN - 9949-11-079-3 SP - 21 PB - Tartu University Press CY - Tartu ER - TY - GEN A1 - Fischer, Thomas T1 - Einfluß ausgewählter Fruchtfolgen und Fruchtarten auf die Kohlenstoffdynamik des Bodens auf einem grundwasserfernen Sandstandort T2 - Mitteilungen der Gesellschaft für Pflanzenbauwissenschaften Y1 - 1991 SN - 0934-5116 VL - 4 SP - 339 EP - 342 ER - TY - GEN A1 - Fischer, Thomas T1 - Einfluß von Winterweizen und Winterroggen in Fruchtfolgen mit unterschiedlichem Getreideanteil auf die mikrobielle Biomasse und die jahreszeitliche Kohlenstoffdynamik des Bodens T2 - Archiv für Acker- und Pflanzenbau und Bodenkunde Y1 - 1993 SN - 0365-0340 VL - 37 SP - 181 EP - 189 ER - TY - CHAP A1 - Fischer, Thomas ED - Merbach, Wolfgang T1 - Auswirkungen einer Wiederbefeuchtung auf die C- und N-Mineralisierung in der Humusauflage von Kiefernökosystemen T2 - Pflanzliche Stoffaufnahme und mikrobielle Wechselwirkungen in der Rhizosphere Y1 - 1996 SN - 3-8154-3528-5 SP - 13 EP - 20 PB - Teubner CY - Stuttgart [u.a.] ER - TY - GEN A1 - Fischer, Thomas A1 - Yair, Aaron A1 - Veste, Maik T1 - Microstructure and hydraulic properties of biological soil crusts on sand dunes: a comparison between arid and temperate climates T2 - Biogeosciences Discuss N2 - We studied the relationships between crust microstructure, infiltration and water holding capacity under arid and temperate conditions (Factor A: Climate) on biological soil crusts (BSCs) sampled along a catena on mobile sand dunes (Factor B: Catena). The arid study site was located near Nizzana, Israel (precipitation: 86mm a−1, PET: ca. 2500mm a−1) and the temperate site near Lieberose, Germany (precipitation: 569mm a−1, PET: ca. 780mm a−1). BSCs were sampled near the dune crest, at the centre of the dune slope and at the dune base at each site. Scanning electron microscopy (SEM) was used to characterize BSC morphology and microstructure. Infiltration was determined using microinfiltrometry under controlled moisture conditions in the lab. Water holding capacities were determined after water saturation of the dry BSCs. Wettability of the crusts was characterized using a “repellency index”, which was calculated from water and ethanol sorptivities. Irrespective of the climate, an accumulation of fine particles in the BSCs was found, increasing along the catena from dune crest to dune base. Texture was finer and water holding capacities of the underlying substrate were higher at the arid site, whereas surface wettability was reduced at the temperate site. At both sites, BSCs caused extra water holding capacity compared to the substrate. Infiltration rates decreased along the catena and were generally lower at the dune slope and base of the arid site. A mechanism of crust stabilization is proposed where BSCs benefit from increased texture and biomass mediated water supply, and where the water supply to higher plants was limited due to alteration of physico-chemical surface properties under temperate conditions. Y1 - 2012 U6 - https://doi.org/10.5194/bgd-9-12711-2012 VL - 9 SP - 12711 EP - 12734 ER - TY - CHAP A1 - Fischer, Thomas A1 - Yair, Aaron A1 - Veste, Maik T1 - Infiltration, water holding capacity and growth patterns of biological soil crusts on sand dunes under arid and temperate climates T2 - EGU General Assembly 2012, held 22-27 April, 2012 in Vienna Y1 - 2012 N1 - EGU2012-5034 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Dolezych, Martina A1 - Fischer, Thomas A1 - Gröschke, Andreas T1 - Pinuxylon succiniferum (GOEPPERT) KRAEUSEL emend. DOLEZYCH - amberized wood from GOEPPERT T2 - Mauritiana Y1 - 2011 SN - 0233-173X VL - 22 SP - 43 EP - 60 ER - TY - CHAP A1 - Fischer, Thomas A1 - Veste, Maik T1 - Small scale spatial heterogeneity of biological soil crusts during initial ecosystem development T2 - Abstract Book of the 12th European Ecological Federation Congress, 25-29 September 2011, Avila, Spain Y1 - 2011 UR - http://www.desertconsult.de/abstracts/Veste_EEF2011_2.pdf SP - S. 250 ER - TY - CHAP A1 - Fischer, Thomas A1 - Veste, Maik T1 - Biological soil crusts on inland dunes in NE Germany: Can we link succession with hydrology? T2 - Book of Abstracts Workshop "Biological Soil Crusts in Ecosystems - their Diversity, Ecology, and Management", 22-25. August 2010, Zellingen-Retzbach, Germany Y1 - 2010 UR - http://www.desertconsult.de/abstracts/biocrusts3.pdf SP - S. 52 ER - TY - GEN A1 - Geppert, Helmut A1 - Fischer, Thomas T1 - CHROMATOGRAPHIE-Festphasenmikroextraktion von polaren Verbindungen T2 - Labor Praxis Y1 - 2009 SN - 0344-1733 VL - 33 IS - 1 SP - 46 EP - 47 ER - TY - CHAP A1 - Fischer, Thomas A1 - Veste, Maik A1 - Lange, Philipp A1 - Wiehe, Wolfgang T1 - How biological soil crusts are stabilizing the soil surface? The development of organo-mineral interactions in the initial phase T2 - EGU General Assembly 2009, held in Vienna, Austria, 19 – 24 April 2009 Y1 - 2009 UR - http://meetingorganizer.copernicus.org/EGU2009/EGU2009-8635.pdf N1 - EGU2009-8635 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Fischer, Thomas A1 - Veste, Maik A1 - Bens, Oliver A1 - Hüttl, Reinhard F. T1 - Dew formation on the surface of biological soil crusts in central European sand ecosystems T2 - Biogeosciences N2 - Dew formation was investigated in three developmental stages of biological soil crusts (BSC), which were collected along a catena of an inland dune and in the initial substrate. The Penman equation, which was developed for saturated surfaces, was modified for unsaturated surfaces and used for prediction of dewfall rates. The levels of surface saturation required for this approach were predicted using the water retention functions and the thicknesses of the BSCs. During a first field campaign (2–3 August 2011), dewfall increased from 0.042 kg m−2 for the initial sandy substrate to 0.058, 0.143 and 0.178 kg m−2 for crusts 1 to 3, respectively. During a second field campaign (17–18 August 2011), where dew formation was recorded in 1.5 to 2.75-h intervals after installation at 21:30 CEST, dewfall increased from 0.011 kg m−2 for the initial sandy substrate to 0.013, 0.028 and 0.055 kg m−2 for crusts 1 to 3, respectively. Dewfall rates remained on low levels for the substrate and for crust 1, and decreased overnight for crusts 2 and 3 (with crust 3 > crust 2 > crust 1 throughout the campaign). Dew formation was well reflected by the model response. The suggested mechanism of dew formation involves a delay in water saturation in near-surface soil pores and extracellular polymeric substances (EPS) where the crusts were thicker and where the water capacity was high, resulting in elevated vapor flux towards the surface. The results also indicate that the amount of dewfall was too low to saturate the BSCs and to observe water flow into deeper soil. Analysis of the soil water retention curves revealed that, despite the sandy mineral matrix, moist crusts clogged by swollen EPS pores exhibited a clay-like behavior. It is hypothesized that BSCs gain double benefit from suppressing their competitors by runoff generation and from improving their water supply by dew collection. Despite higher amounts of dew, the water availability to the crust community decreases with crust development, which may be compensated by ecophysiological adaptation of crust organisms, and which may further suppress higher vegetation or mosses. Y1 - 2012 U6 - https://doi.org/10.5194/bg-9-4621-2012 SN - 1726-4189 VL - 9 SP - 4621 EP - 4628 ER - TY - GEN A1 - Brankatschk, Robert A1 - Fischer, Thomas A1 - Veste, Maik A1 - Zeyer, Josef T1 - Succession of N Cycling Processes in Biological Soil Crusts on a Central European Inland Dune T2 - FEMS Microbiology Ecology N2 - Biological soil crusts (BSCs) are microbial assemblages that occur worldwide and facilitate ecosystem development by nitrogen (N) and carbon accumulation. N turnover within BSC ecosystems has been intensively studied in the past; however, shifts in the N cycle during BSC development have not been previously investigated. Our aim was to characterise N cycle development first by the abundance of the corresponding functional genes (in brackets) and second by potential enzyme activities; we focussed on the four processes: N fixation (nifH), mineralisation as proteolysis and chitinolysis (chiA), nitrification (amoA) and denitrification (nosZ). We sampled from four phases of BSC development and from a reference located in the rooting zone of Corynephorus canescens, on an inland dune in Germany. BSC development was associated with increasing amounts of chlorophyll, organic carbon and N. Potential activities increased and were highest in developed BSCs. Similarly, the abundance of functional genes increased. We propose and discuss three stages of N process succession. First, the heterotrophic stage (mobile sand without BSCs) is dominated by mineralisation activity. Second, during the transition stage (initial BSCs), N accumulates, and potential nitrification and denitrification activity increases. Third, the developed stage (established BSCs and reference) is characterised by the dominance of nitrification. Y1 - 2013 U6 - https://doi.org/10.1111/j.1574-6941.2012.01459.x SN - 1574-6941 VL - 83 IS - 1 SP - 149 EP - 160 ER - TY - GEN A1 - Xiao, Bo A1 - Wang, Huifang A1 - Fan, Jun A1 - Fischer, Thomas A1 - Veste, Maik T1 - Biological soil crusts decrease soil temperature in summer and increase soil temperature in winter in semiarid environment T2 - Ecological Engineering N2 - In hot and wet conditions in summer, the biological soil crusts (BSCs) decreased soil temperature by up to 11.8 °C, 7.5 °C, 5.4 °C, and 3.2 °C at surface, 5 cm, 15 cm, and 30 cm, respectively; while in cold and dry conditions in winter the BSCs increased soil temperature by up to 1.2 °C, 1.2 °C, and 1.1 °C at 5 cm, 15 cm, and 30 cm, respectively. The daily mean soil temperatures of the BSCs in a whole year were averagely increased by 0.57 ± 0.04 °C, 0.31 ± 0.04 °C, and 0.22 ± 0.04 °C at 5 cm, 15 cm, and 30 cm, respectively. The effects of the BSCs on soil temperature were positively correlated with air temperature and soil moisture, and decreased with soil depth from surface to deep soil. We concluded that BSCs relieved the extreme hot and cold soil micro-environments in desert ecosystem to some extent. Therefore their effects on soil temperature are positive for improving water and nutrient availability and biological community structure, thus decreasing susceptibility to desertification. These results would be helpful for understanding the ecological and hydrological functions of BSCs in semiarid environment. Y1 - 2013 U6 - https://doi.org/10.1016/j.ecoleng.2013.06.009 SN - 0925-8574 VL - 58 SP - 52 EP - 56 ER - TY - GEN A1 - Fischer, Thomas A1 - Yair, Aaron A1 - Veste, Maik A1 - Geppert, Helmut T1 - Hydraulic properties of biological soil crusts on sand dunes studied by 13C-CP/MAS-NMR: a comparison between an arid and a temperate site T2 - Catena N2 - Using principal component analysis (PCA), we studied the relationships between hydraulic properties and 13C-CP/MAS-NMR shift regions of biological soil crusts (BSCs) on sand dunes under arid and temperate conditions. The arid study site was located near Nizzana, in the northwestern Negev, Israel and the temperate site was near Lieberose, Brandenburg, Germany. BSCs were sampled at each site near the dune crest, at the center of the dune slope and at the dune base. The soil texture was finer and water holding capacities (WHCs) were higher in Nizzana, whereas surface wettability was reduced in Lieberose. At both sites, BSCs caused extra WHC compared to the mineral substrate. Infiltration after wetting along both catenas generally reached a maximum after 10 min and decreased after 30 min. Carbohydrates were the dominating components in all of the BSCs studied, where the relative peak areas of carbohydrate-derived structures (60–110 ppm) amounted to 28–46% and to 10–14% of total C-peak areas, respectively. PCA revealed that the WHC of the substrate was closely related to the amount of silt and clay, whereas the BSC induced extra WHC was closely related to carbohydrates. It was further found that water repellency was positively related to carbohydrate C, but negatively related to alkyl C. Infiltration kinetics was attributed to polysaccharide hydration and swelling. Our findings support the hypothesis that hydraulic properties of BSCs are determined by extracellular polymeric substances (EPS) and soil texture. Hydraulic properties in BSCs result from the combination of chemical properties related to C compounds mainly dominated by carbohydrates and physical surface properties related to texture, porosity and water holding capacity. Y1 - 2013 U6 - https://doi.org/10.1016/j.catena.2013.06.002 SN - 0341-8162 VL - 110 SP - 155 EP - 160 ER - TY - CHAP A1 - Iurchenko, Valentina A1 - Mykhailova, Larysa A1 - Fischer, Thomas T1 - Kinetic Characteristics of Petrochemicals Transposition and Accumulation in Soils of Roadside Area T2 - Transbaltica 2013 Conference Proceedings, 09.-10. May 2013, Vilnius, Lithuania Y1 - 2013 U6 - https://doi.org/10.3846/transbaltica2013.016 ER - TY - GEN A1 - Mykhailova, Larysa A1 - Fischer, Thomas A1 - Iurchenko, Valentina T1 - Distribution and fractional composition of petroleum hydrocarbons in roadside soils T2 - Applied and Environmental Soil Science Y1 - 2013 U6 - https://doi.org/10.1155/2013/938703 VL - 2013 IS - ID 938703 SP - 1 EP - 6 ER - TY - GEN A1 - Wang, Haijing A1 - Geppert, Helmut A1 - Fischer, Thomas A1 - Wieprecht, Wolfgang A1 - Möller, Detlev T1 - Determination of volatile organic and polycyclic aromatic hydrocarbons in crude oil with efficient gas-chromatographic methods T2 - Journal of Chromatographic Science N2 - Determination of volatile organic compounds (VOCs) in crude oil, such as super volatile organic compounds (super VOCs) and simple polycyclic aromatic hydrocarbons (PAHs), is vital for targeting crude oil spill spots. In this study, a static headspace gas chromatography flame ionization detection method was established for determination of super VOCs in crude oil with both external and internal standard determination, which can be used in the field when using portable gas chromatography. Identification was done by comparing the retention time with the corresponding standards and quantitation was done with a new one-drop method. Another simplified and efficient method was performed to analyze volatile PAHs in crude oil, which can also be used in field analysis. Toluene was used as the extraction solvent for PAHs in crude oil. Method validation for both analyses was satisfactory. The result showed that n-butane and n-pentane were maximum super VOCs and naphthalene, phenanthrene and fluorene were the main PAHs in the crude oil studied. The super VOCs quantity ranged from 3 to 6% and the main PAHs consisted of 0.02–0.06% of studied crude oil. Y1 - 2014 U6 - https://doi.org/10.1093/chromsci/bmu113 SN - 1945-239X VL - 53 IS - 5 SP - 647 EP - 654 ER - TY - GEN A1 - Mykhailova, Larysa A1 - Fischer, Thomas A1 - Iurchenko, Valentina T1 - Deposition of petroleum hydrocarbons with sediment trapped in snow in roadside areas T2 - Journal of Environmental Engineering and Landscape Management N2 - Total petroleum hydrocarbon (TPH) deposition rates were determined along various roads using the natural snow cover as deposition trap. Daily deposition rates decreased with distance from the roads, which coincided with long-term TPH accumulation in roadside soils. Scanning electron microscopy (SEM-EDX) of the snow meltwater sediment revealed occurrence of carbon-rich plaques, which were identified as hydrocarbons using FTIR-microscopy. GC-MS revealed that the compounds extracted from the sediment consisted of an unresolved complex hydrocarbon mixture (UCM). Individual n-alkanes could not be resolved in the sediment extract, whereas TPHs extracted from soils contained a series of n-alkanes peaking at C25-C27. The proportion of UCM compounds from TPHs decreased with distance from road. We conclude that high-boiling hydrocarbons bind to coarse mineral dust and/or to splash water and vehicle spray, which preferentially deposit within a 10 m roadside strip. Y1 - 2014 U6 - https://doi.org/10.3846/16486897.2014.889698 SN - 1822-4199 VL - 22 IS - 3 SP - 237 EP - 244 ER - TY - CHAP A1 - Fischer, Thomas A1 - Veste, Maik A1 - Mykhailova, Larysa T1 - Ecological Maturity and Drought Stress of Biological Soil Crusts along a Central European Inland Dune Catena T2 - European Geosciences Union, General Assembly 2014, Vienna, Austria, 27 April – 02 May 2014 Y1 - 2014 N1 - EGU2014-11377 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Fischer, Thomas A1 - Yair, Aaron A1 - Geppert, Helmut A1 - Veste, Maik T1 - Water repellency and infiltration of biological soil crusts on an arid and a temperate dunes T2 - European Geosciences Union, General Assembly 2014, Vienna, Austria, 27 April – 02 May 2014 Y1 - 2014 N1 - EGU2014-12175 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Fischer, Thomas T1 - Initial pedogenesis in biological soil crusts T2 - Nasledie I. V. Tjurina v sovremennych issledovanijach v počvovedenii: materialy Meždunarodnoj naučnoj konferencii, Kazan', 15 - 17, oktjabrja 2013 Y1 - 2013 UR - http://kpfu.ru/docs/F928601744/Materialy.konferencii.Tjurina._1_.pdf SN - 978-5-9222-0726-3 SP - 19 EP - 21 PB - Izdat. Otečestvo CY - Kazan', Russian Federation ER - TY - GEN A1 - Wang, Haijing A1 - Fischer, Thomas A1 - Wieprecht, Wolfgang A1 - Möller, Detlev T1 - A predictive method for crude oil volatile organic compounds emission from soil: Evaporation and diffusion behavior investigation of binary gas mixtures T2 - Environmental Science and Pollution Research N2 - Due to their mobility and toxicity, crude oil volatile organic compounds (VOCs) are representative components for oil pipeline contaminated sites detection. Therefore, contaminated location risk assessment, with airborne light detection and ranging (LIDAR) survey, in particular, requires ground-based determinative methods for oil VOCs, the interaction between oil VOCs and soil, and information on how they diffuse from underground into atmosphere. First, we developed a method for determination of crude oil VOC binary mixtures (take n-pentane and n-hexane as examples), taking synergistic effects of VOC mixtures on polydimethylsiloxane (PDMS) solid-phase microextraction (SPME) fibers into consideration. Using this method, we further aim to extract VOCs from small volumes, for example, from soil pores, using a custom-made sampling device for nondestructive SPME fiber intrusion, and to study VOC transport through heterogeneous porous media. Second, specific surface Brunauer–Emmett–Teller (BET) analysis was conducted and used for estimation of VOC isotherm parameters in soil. Finally, two models were fitted for VOC emission prediction, and the results were compared to the experimental emission results. It was found that free diffusion mode worked well, and an empirical correction factor seems to be needed for the other model to adapt to our condition for single and binary systems. Y1 - 2015 U6 - https://doi.org/10.1007/s11356-014-4049-3 SN - 0944-1344 SN - 1614-7499 ER -