TY - THES A1 - Sut-Lohmann, Magdalena T1 - Detection and behavior of iron-cyanide complexes in soils of a former Manufactured Gas Plant site N2 - In Germany, soil and groundwater atmore than a thousand sites are contaminatedwith ironcyanide complexes. These contaminations originate from the gas purification p process that was conducted inManufactured Gas Plants (MGP).There is a risk of human threat depending on the stability dissolved iron-cyanide complexes due to the potential release of toxic free cyanide, CN(aq) and HCN(g), (aq). The aim of this thesis was to evaluate a new method for the cyanide detection and to investigate the stability and retardation of the iron-cyanide complexes in soils by batch and column experiments in order to improve the knowledge concerning the fate of cyanide compounds in soil and groundwater. This study seeks for enhancing the efficiency of phytoremediation as a proper approach to decontaminate ironcyanides complexes and thus tries to make a contribution to environmental protection. Y1 - 2014 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:co1-opus4-40631 PB - BTU Cottbus-Senftenberg CY - Cottbus ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Raab, Thomas T1 - Feasibility of diffuse reflectance infrared Fourier spectroscopy (DRIFTS) to quantify iron-cyanide (Fe-CN) complexes in soil T2 - European Geosciences Union, General Assembly 2017, Vienna, Austria N2 - Contaminated sites create a significant risk to human health, by poisoning drinking water, soil, air and as a consequence food. Continuous release of persistent iron-cyanide (Fe-CN) complexes from various industrial sources poses a high hazard to the environment and indicates the necessity to analyze considerable amount of samples. At the present time quantitative determination of Fe-CN concentration in soil usually requires a time consuming two step process: digestion of the sample (e.g., micro distillation system) and its analytical detection performed, e.g., by automated spectrophotometrical flow injection analysis (FIA). In order to determine the feasibility of diffuse reflectance infrared Fourier spectroscopy (DRIFTS) to quantify the Fe-CN complexes in soil matrix, 42 soil samples were collected (8 to 12.520 mg kg-1CN) indicating single symmetrical CN band in the range 2092 - 2084 cm-1. Partial least squares (PLS) calibration-validation model revealed IR response to CNtot exceeding 1268 mg kg-1 (limit of detection, LOD). Subsequently, leave-one-out cross-validation (LOO-CV) was performed on soil samples containing low CNtot (<900 mg kg-1), which improved the sensitivity of the model by reducing the LOD to 154 mg kg-1. Finally, the LOO-CV conducted on the samples with CNtot >900 mg kg-1 resulted in LOD equal to 3494 mg kg-1. Our results indicate that spectroscopic data in combination with PLS statistics can efficiently be used to predict Fe-CN concentrations in soil. We conclude that the protocol applied in this study can strongly reduce the time and costs essential for the spatial and vertical screening of the site affected by complexed Fe-CN. Y1 - 2017 UR - http://meetingorganizer.copernicus.org/EGU2017/EGU2017-6995.pdf N1 - EGU2017-6995 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Raab, Thomas T1 - Quick detection and quantification of iron-cyanide complexes using fourier transform infrared spectroscopy T2 - Environmental Pollution N2 - The continuous release of persistent iron-cyanide (Fe-CN) complexes from various industrial sources poses a high hazard to the environment and indicates the necessity to analyze a considerable amount of samples. Conventional flow injection analysis (FIA) is a time and cost consuming method for cyanide (CN) determination. Thus, a rapid and economic alternative needs to be developed to quantify the Fe-CN complexes. 52 soil samples were collected at a former Manufactured Gas Plant (MGP) site in order to determine the feasibility of diffuse reflectance infrared Fourier spectroscopy (DRIFTS). Soil analysis revealed CN concentrations in a range from 8 to 14.809 mg kg⁻¹, where 97% was in the solid form (Fe₄[Fe(CN)₆]₃), which is characterized by a single symmetrical CN band in the range 2092-2084 cm-1. The partial least squares (PLS) calibration-validation model revealed IR response to CNtot which exceeds 2306 mg kg⁻¹(limit of detection, LOD). Leave-one-out cross-validation (LOO-CV) was performed on soil samples, which contained low CNtot (<900 mg kg⁻¹). This improved the sensitivity of the model by reducing the LOD to 154 mg kg⁻¹. Finally, the LOO-CV conducted on the samples with CNtot > 900 mg kg⁻¹ resulted in LOD equal to 3751 mg kg⁻¹. It was found that FTIR spectroscopy provides the information concerning different CN species in the soil samples. Additionally, it is suitable for quantifying Fe-CN species in matrixes with CNtot > 154 mg kg⁻¹. Thus, FTIR spectroscopy, in combination with the statistical approach applied here seems to be a feasible and quick method for screening of contaminated sites. Y1 - 2017 U6 - https://doi.org/10.1016/j.envpol.2017.04.052 SN - 0269-7491 VL - 227 SP - 64 EP - 72 ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Boldt-Burisch, Katja A1 - Pohle, Ina A1 - Raab, Thomas T1 - Advancing performance of green technologies for remediation and reclamation of degraded urban soils Y1 - 2015 SN - 978-3-944863-18-4 SN - 978-3-944863-19-1 PB - United Nations University, Institute for Integrated Management of Material Fluxes and of Resources CY - Dresden ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Repmann, Frank A1 - Fischer, Thomas A1 - Raab, Thomas T1 - Retardation of iron-cyanide complexes in soils of a former Manufactured Gas Plant site T2 - Book of abstracts, XII International Congress of Young Chemists, YoungChem2014, Szczecin, Poland 8th-12th October 2014 Y1 - 2014 SN - 978-83-61037-28-6 SP - S. 44 CY - Warsaw ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Knoop, Christine A1 - Raab, Thomas T1 - Effect of the post treatments for biowaste‐based digestateson water solubility of nutrients and iron‐cyanide (Fe‐CN)complex mobility T2 - Land Degradation & Development N2 - With recent policy developments, an increase in organic waste utilization is expected. However, the use of organic amendments to reduce the mobility of iron‐cyanide (Fe‐CN) complexes and simultaneously promote vegetation growth has not been studied before. Therefore, we evaluated the effect of (a) drying, (b) composting, and (c) pelletizing on the ability of digestates (biowastes from an anaerobic treatment of municipal organic waste) to provide easily available nutrients and stabilize Fe‐CN complexes. Extraction with deionized water resulted in a considerably higher nutrient and carbon elution from air‐dried and oven‐dried digestates (50% dry matter [DM] of total K, 11% DM Mg, 7% DM Ca, and 6% DM C). Mixer‐pelletized digestates stand out among the composted samples (42% of total K, 3% DM C, 5% DM P, 1.5% DM Mg, and 1% DM Ca). The adsorption experiment showed the highest significant tot. CN conc. reduction using noncomposted, air‐dried (100%), and oven‐dried (82%) digestates. Significant correlations have been found for Mg, Ca, and dissolved organic carbon elution and slightly acidic pH as well as CN adsorption. The Fourier transform infrared analysis revealed Fe‐CN complexation on inorganic (K₂Mn[Feᴵᴵ(CN)₆] and NH₄Fe[Feᴵᴵ(CN)₆]) and organic constituents indicating formation of nitriles. Air‐ and oven‐dried digestates showed the most promising results in terms of nutrients' availability and ability to decrease Fe‐CN complex mobility. Y1 - 2019 UR - https://onlinelibrary.wiley.com/doi/10.1002/ldr.3336 U6 - https://doi.org/10.1002/ldr.3336 SN - 1099-145X VL - 30 IS - 13 SP - 1545 EP - 1553 ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Jonczak, Jerzy A1 - Raab, Thomas T1 - Phytofiltration of chosen metals by aquarium liverwort (Monosoleum tenerum) T2 - Ecotoxicology and Environmental Safety N2 - Aquatic bryophytes are widely used as indicators of water pollution with various substances, including metals. We present a first study concerning the feasibility of Monosoleum tenerum to remove potentially toxic metals Zn, Cu, Ni, Mn and Fe from water. The novel approach to study the bioaccumulation under controlled conditions and in vitro grown aquarium liverworts was applied. The plants were exposed to 1, 10 and 100 ppm multi-metal solution for 7 days and subsequently the metal content was determined in plant material and media to calculate the bioaccumulation factor (BAF). The study revealed various accumulation behavior (metal and dose dependent), which followed the order of Cu > Zn > Mn > Ni > Fe for 1 ppm; Zn > Cu > Mn > Fe > Ni for 10 ppm and Cu > Fe > Zn > Ni > Mn for 100 ppm solution. However, with increasing Cu, Mn and Ni concentration in the solution, BAF decreased. For Zn the highest BAF value (136) was obtained for the 10 ppm solution. Fe bioaccumulation increased with the increasing solution concentration. After 7 week exposure, the results indicated highest accumulation of Cu (3,25 mg) followed by Fe (1,8 mg) in the plant tissue for the 100 ppm solution. Overall, the bryophyte M. tenerum demonstrate high potential for the removal of toxic metals from the multi-metal solution via accumulation in plant tissue. The BAF values were proper to indicate the use of M. tenerum for phytofiltration of waste waters affected by Zn, Cu, Ni, Mn and Fe. Y1 - 2020 U6 - https://doi.org/10.1016/j.ecoenv.2019.109844 SN - 1090-2414 SN - 0147-6513 VL - Vol. 188 ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Jonczak, Jerzy A1 - Parzych, Agnieszka A1 - Šimanský, Vladimír A1 - Polláková, Nora A1 - Raab, Thomas T1 - Accumulation of airborne potentially toxic elements in Pinus sylvestris L. bark collected in three Central European medium-sized cities T2 - Ecotoxicology and Environmental Safety Y1 - 2020 U6 - https://doi.org/10.1016/j.ecoenv.2020.110758 SN - 0147-6513 VL - 200 ER - TY - GEN A1 - Jonczak, Jerzy A1 - Jankiewicz, Ursula A1 - Kondras, Marek A1 - Kruczkowska, Bogusława A1 - Oktaba, Lidia A1 - Oktaba, Jarosław A1 - Olejniczak, Izabella A1 - Pawłowicz, Edyta A1 - Polláková, Nora A1 - Raab, Thomas A1 - Regulska, Edyta A1 - Słowińska, Sandra A1 - Sut-Lohmann, Magdalena T1 - The influence of birch trees (Betula spp.) on soil environment – A review T2 - Forest Ecology and Management Y1 - 2020 U6 - https://doi.org/10.1016/j.foreco.2020.118486 SN - 0378-1127 VL - 477 ER - TY - GEN A1 - Klos, Friederike A1 - Sut-Lohmann, Magdalena A1 - Raab, Thomas A1 - Hirsch, Florian T1 - Innovative Drone-based Hyperspectral Detection of Heavy Metals (Ni, Zn, and Cu) in Plants cultivated for Phytomining T2 - EGU General Assembly 2020, Online | 4–8 May 2020 Y1 - 2020 U6 - https://doi.org/10.5194/egusphere-egu2020-9370 ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Knoop, Christine A1 - Raab, Thomas T1 - Effect of drying, composing and pelletizing of biowaste-based digestates on providing water soluble nutrients and stabilizing iron-cyanide (Fe-CN) complexes T2 - EGU General Assembly 2020, Online | 4–8 May 2020 Y1 - 2020 U6 - https://doi.org/10.5194/egusphere-egu2020-8013 ER -