TY - GEN A1 - Sebastia-Saez, Daniel A1 - Ramirez Reina, Tomas A1 - Silva, Ravi A1 - Arellano-García, Harvey T1 - Synthesis and characterisation of n‐octacosane@silica nanocapsules for thermal storage applications T2 - International Journal of Energy Research N2 - This work reports the synthesis and characterisation of a core‐shell n‐octacosane@silica nanoencapsulated phase‐change material obtained via interfacial hydrolysis and polycondensation of tetraethyl orthosilicate in miniemulsion. Silica has been used as the encapsulating material because of its thermal advantages relative to synthesised polymers. The material presents excellent heat storage potential, with a measured melting latent heat varying between 57.1 and 89.0 kJ kg−1 (melting point between 58.2°C and 59.9°C) and a small particle size (between 565 and 227 nm). Degradation of the n‐octacosane core starts between 150°C and 180°C. Also, the use of silica as shell material gives way to a heat conductivity of 0.796 W m−1 K−1 (greater than that of nanoencapsulated materials with polymeric shell). Charge/discharge cycles have been successfully simulated at low pressure to prove the suitability of the nanopowder as phase‐change material. Further research will be carried out in the future regarding the use of the synthesised material in thermal applications involving nanofluids. Y1 - 2019 UR - https://onlinelibrary.wiley.com/doi/10.1002/er.5039 U6 - https://doi.org/10.1002/er.5039 SN - 1099-114X SN - 0363-907X VL - 44 IS - 3 SP - 2306 EP - 2315 ER -