TY - GEN A1 - Pfister, Christian A1 - Wetter, Oliver A1 - Brázdil, Rudolf A1 - Dobrovolný, Petr A1 - Glaser, Rüdiger A1 - Luterbacher, Jürg A1 - Seneviratne, Sonia I. A1 - Zorita, Eduardo A1 - Alcoforado, Maria João A1 - Barriendos, Mariano A1 - Bieber, Ursula A1 - Burmeister, Karl H. A1 - Camenisch, Chantal A1 - Contino, Antonio A1 - Grünewald, Uwe A1 - Herget, Jürgen A1 - Himmelsbach, Iso A1 - Labbé, Thomas A1 - Limanówka, Danuta A1 - Litzenburger, Laurent A1 - Kiss, Andrea A1 - Kotyza, Oldřich A1 - Nordl, Øyvind A1 - Pribyl, Kathleen A1 - Retsö, Dag A1 - Riemann, Dirk A1 - Rohr, Christian A1 - Siegfried, Werner A1 - Spring, Jean-Laurent A1 - Söderberg, Johan A1 - Wagner, Sebastian A1 - Werner, Johannes P. T1 - Tree-rings and people – different views on the 1540 Megadrought. Reply to Büntgen et al. 2015 T2 - Climatic change Y1 - 2015 U6 - https://doi.org/10.1007/s10584-015-1429-8 SN - 0165-0009 SN - 1573-1480 VL - 131 IS - 2 SP - 191 EP - 198 ER - TY - GEN A1 - Ehrling, Sebastian A1 - Senkovska, Irena A1 - Efimova, Anastasia A1 - Bon, Volodymyr A1 - Abylgazina, Leila A1 - Petkov, Petko A1 - Evans, Jack D. A1 - Attallah, Ahmed Gamal A1 - Wharmby, Michael Thomas A1 - Roslova, Maria A1 - Huang, Zhehao A1 - Tanaka, Hideki A1 - Wagner, Andreas A1 - Schmidt, Peer A1 - Kaskel, Stefan T1 - Temperature Driven Transformation of the Flexible Metal-Organic Framework DUT-8(Ni) T2 - Chemistry - a European journal N2 - DUT-8(Ni) metal-organic framework belongs to the family of flexible pillared layer materials. The desolvated framework can be obtained in the open pore form (op) or in the closed pore form (cp), depending on the crystal size regime. In the present work, we report on the behaviour of desolvated DUT-8(Ni) at elevated temperatures. For both, op and cp variants, heating causes a structural transition, leading to an new, crystalline compound, containing two interpenetrated networks. The state of the framework before transition (op vs. cp) influences the transition temperature: the small particles of the op phase transform at significantly lower temperature in comparison to the macroparticles of the cp phase, transforming close to the decomposition temperature. The new compound, confined closed pore phase (ccp), was characterized by powder X-ray diffraction and spectroscopic techniques, such as IR, EXAFS, and positron annihilation lifetime spectroscopy (PALS). Thermal effects of structural cp to ccp transitions were studied using differential scanning calorimetry (DSC), showing an overall exothermic effect of the process, involving bond breaking and reformation. Theoretical calculations reveal the energetics, driving the observed temperature induced phase transition. KW - Metal organic framework (MOF) KW - Thermal analysis KW - Crystal structure KW - Phase transition Y1 - 2022 UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201281 U6 - https://doi.org/10.1002/chem.202201281 SN - 1521-3765 VL - 28 IS - 55 SP - 1 EP - 10 ER - TY - GEN A1 - Jahnke, Sonja A1 - Cruysen, Caren A1 - Prill, Robert A1 - Kittmann, Fabian A1 - Pflug, Nicola A1 - Albert, Justin Amadeus A1 - Camargo, Tibor de A1 - Arnrich, Bert A1 - Krolikowska, Aleksandra A1 - Kolcz, Anna A1 - Reichert, Pawel A1 - Oleksy, Lukasz A1 - Michel, Sven A1 - Kopf, Sebastian A1 - Wagner, Michael A1 - Scheffler, Sven A1 - Becker, Roland T1 - Protocol for a Randomized Crossover Trial to Evaluate the Effect of Soft Brace and Rigid Orthosis on Performance and Readiness to Return to Sport Six Months Post‑ACL‑Reconstruction T2 - Healthcare N2 - A randomized crossover trial was designed to investigate the influence of muscle activation and strength on functional stability/control of the knee joint, to determine whether bilateral imbalances still occur six months after successful anterior cruciate ligament reconstruction (ACLR), and to analyze whether the use of orthotic devices changes the activity onset of these muscles. Furthermore, conclusions on the feedforward and feedback mechanisms are highlighted. Therefore, twenty‑eight patients will take part in a modified Back in Action (BIA) test battery at an average of six months after a primary unilateral ACLR, which used an autologous ipsilateral semitendinosus tendon graft. This includes double‑leg and single‑leg stability tests, double‑leg and single‑leg countermovement jumps, double‑leg and single‑leg drop jumps, a speedy jump test, and a quick feet test. During the tests, gluteus medius and semitendinosus muscle activity are analyzed using surface electromyography (sEMG). Motion analysis is conducted using Microsoft Azure DK and 3D force plates. The tests are performed while wearing knee rigid orthosis, soft brace, and with no aid, in random order. Additionally, the range of hip and knee motion and hip abductor muscle strength under isometric conditions are measured. Furthermore, patient‑rated outcomes will be assessed. Y1 - 2023 U6 - https://doi.org/10.3390/healthcare11040513 SN - 2227-9032 VL - 11 IS - 4 ER -