TY - GEN A1 - Buchanan, Erin M. A1 - Lewis, Savannah C. A1 - Paris, Bastien A1 - Forscher, Patrick S. A1 - Pavlacic, Jeffrey M. A1 - Beshears, Julie E. A1 - Drexler, Shira Meir A1 - Gourdon-Kanhukamwe, Amélie A1 - Mallik, Peter R A1 - Silan, Miguel Alejandro A. A1 - Miller, Jeremy K. A1 - IJzerman, Hans A1 - Moshontz, Hannah A1 - Beaudry, Jennifer L. A1 - Suchow, Jordan W. A1 - Chartier, Christopher R. A1 - Coles, Nicholas A. A1 - Sharifian, MohammadHasan A1 - Todsen, Anna Louise A1 - Levitan, Carmel A. A1 - Azevedo, Flávio A1 - Legate, Nicole A1 - Heller, Blake A1 - Rothman, Alexander J. A1 - Dorison, Charles A. A1 - Gill, Brian P. A1 - Wang, Ke A1 - Rees, Vaughan W. A1 - Gibbs, Nancy A1 - Goldenberg, Amit A1 - Thi Nguyen, Thuy-vy A1 - Gross, James J. A1 - Kaminski, Gwenaêl A1 - von Bastian, Claudia C. A1 - Paruzel-Czachura, Mariola A1 - Mosannenzadeh, Farnaz A1 - Azouaghe, Soufian A1 - Bran, Alexandre A1 - Ruiz-Fernandez, Susana A1 - Santos, Anabela Caetano A1 - Reggev, Niv A1 - Zickfeld, Janis H. A1 - Akkas, Handan A1 - Pantazi, Myrto A1 - Ropovik, Ivan A1 - Korbmacher, Max A1 - Arriaga, Patrícia A1 - Gjoneska, Biljana A1 - Warmelink, Lara A1 - Alves, Sara G. A1 - de Holanda Coelho, Gabriel Lins A1 - Stieger, Stefan A1 - Schei, Vidar A1 - Hanel, Paul H. P. A1 - Szaszi, Barnabas A1 - Fedotov, Maksim A1 - Antfolk, Jan A1 - Marcu, Gabriela-Mariana A1 - Schrötter, Jana A1 - Kunst, Jonas R. A1 - Geiger, Sandra J. A1 - Adetula, Adeyemi A1 - Kocalar, Halil Emre A1 - Kielińska, Julita A1 - Kačmár, Pavol A1 - Bokkour, Ahmed A1 - Galindo-Caballero, Oscar J. A1 - Djamai, Ikhlas A1 - Pöntinen, Sara Johanna A1 - AGESIN, Bamikole Emmanuel A1 - Jernsäther, Teodor A1 - Urooj, Anum A1 - Rachev, Nikolay R. A1 - Koptjevskaja-Tamm, Maria A1 - Kurfalı, Murathan A1 - Pit, Ilse L. A1 - Li, Ranran A1 - Çoksan, Sami A1 - Dubrov, Dmitrii A1 - Paltrow, Tamar Elise A1 - Baník, Gabriel A1 - Korobova, Tatiana A1 - Studzinska, Anna A1 - Jiang, Xiaoming A1 - Aruta, John Jamir Benzon R. A1 - Vintr, Jáchym A1 - Chiu, Faith A1 - Kaliska, Lada A1 - Berkessel, Jana B. A1 - Tümer, Murat A1 - Morales-Izquierdo, Sara A1 - Chuan-Peng, Hu A1 - Vezirian, Kevin A1 - Rosa, Anna Dalla A1 - Bialobrzeska, Olga A1 - Vasilev, Martin R. A1 - Beitner, Julia A1 - Kácha, Ondřej A1 - Žuro, Barbara A1 - Westerlund, Minja A1 - Nedelcheva-Datsova, Mina A1 - Findor, Andrej A1 - Krupić, Dajana A1 - Kowal, Marta A1 - Askelund, Adrian Dahl A1 - Pourafshari, Razieh A1 - Đorđević, Jasna Milošević A1 - Schmidt, Nadya-Daniela A1 - Baklanova, Ekaterina A1 - Szala, Anna A1 - Zakharov, Ilya A1 - Vranka, Marek A. A1 - Ihaya, Keiko A1 - Grano, Caterina A1 - Cellini, Nicola A1 - Białek, Michał A1 - Anton-Boicuk, Lisa A1 - Dalgar, Ilker A1 - Adıgüzel, Arca A1 - Verharen, Jeroen P. H. A1 - Maturan, Princess Lovella G. A1 - Kassianos, Angelos P. A1 - Oliveira, Raquel A1 - Čadek, Martin A1 - Adoric, Vera Cubela A1 - Özdoğru, Asil Ali A1 - Sverdrup, Therese E. A1 - Aczel, Balazs A1 - Zambrano, Danilo A1 - Ahmed, Afroja A1 - Tamnes, Christian K. A1 - Yamada, Yuki A1 - Volz, Leonhard A1 - Sunami, Naoyuki A1 - Suter, Lilian A1 - Vieira, Luc A1 - Groyecka-Bernard, Agata A1 - Kamburidis, Julia Arhondis A1 - Reips, Ulf-Dietrich A1 - Harutyunyan, Mikayel A1 - Adetula, Gabriel Agboola A1 - Allred, Tara Bulut A1 - Barzykowski, Krystian A1 - Antazo, Benedict G A1 - Zsido, Andras N. A1 - Šakan, Dušana Dušan A1 - Cyrus-Lai, Wilson A1 - Ahlgren, Lina Pernilla A1 - Hruška, Matej A1 - Vega, Diego A1 - Manunta, Efisio A1 - Mokady, Aviv A1 - Capizzi, Mariagrazia A1 - Martončik, Marcel A1 - Say, Nicolas A1 - Filip, Katarzyna A1 - Vilar, Roosevelt A1 - Staniaszek, Karolina A1 - Vdovic, Milica A1 - Adamkovic, Matus A1 - Johannes, Niklas A1 - Hajdu, Nandor A1 - Cohen, Noga A1 - Overkott, Clara A1 - Krupić, Dino A1 - Hubena, Barbora A1 - Nilsonne, Gustav A1 - Mioni, Giovanna A1 - Solorzano, Claudio Singh A1 - Ishii, Tatsunori A1 - Chen, Zhang A1 - Kushnir, Elizaveta A1 - Karaarslan, Cemre A1 - Ribeiro, Rafael R. A1 - Khaoudi, Ahmed A1 - Kossowska, Małgorzata A1 - Bavolar, Jozef A1 - Hoyer, Karlijn A1 - Roczniewska, Marta A1 - Karababa, Alper A1 - Becker, Maja A1 - Monteiro, Renan P. A1 - Kunisato, Yoshihiko A1 - Metin-Orta, Irem A1 - Adamus, Sylwia A1 - Kozma, Luca A1 - Czarnek, Gabriela A1 - Domurat, Artur A1 - Štrukelj, Eva A1 - Alvarez, Daniela Serrato A1 - Parzuchowski, Michal A1 - Massoni, Sébastien A1 - Czamanski-Cohen, Johanna A1 - Pronizius, Ekaterina A1 - Muchembled, Fany A1 - van Schie, Kevin A1 - Saçaklı, Aslı A1 - Hristova, Evgeniya A1 - Kuzminska, Anna O. A1 - Charyate, Abdelilah A1 - Bijlstra, Gijsbert A1 - Afhami, Reza A1 - Majeed, Nadyanna M. A1 - Musser, Erica D. A1 - Sirota, Miroslav A1 - Ross, Robert M. A1 - Yeung, Siu Kit A1 - Papadatou-Pastou, Marietta A1 - Foroni, Francesco A1 - Almeida, Inês A. T. A1 - Grigoryev, Dmitry A1 - Lewis, David M. G. A1 - Holford, Dawn L. A1 - Janssen, Steve M. J. A1 - Tatachari, Srinivasan A1 - Batres, Carlota A1 - Olofsson, Jonas K. A1 - Daches, Shimrit A1 - Belaus, Anabel A1 - Pfuhl, Gerit A1 - Corral-Frias, Nadia Sarai A1 - Sousa, Daniela A1 - Röer, Jan Philipp A1 - Isager, Peder Mortvedt A1 - Godbersen, Hendrik A1 - Walczak, Radoslaw B. A1 - Van Doren, Natalia A1 - Ren, Dongning A1 - Gill, Tripat A1 - Voracek, Martin A1 - DeBruine, Lisa M. A1 - Anne, Michele A1 - Očovaj, Sanja Batić A1 - Thomas, Andrew G. A1 - Arvanitis, Alexios A1 - Ostermann, Thomas A1 - Wolfe, Kelly A1 - Arinze, Nwadiogo Chisom A1 - Bundt, Carsten A1 - Lamm, Claus A1 - Calin-Jageman, Robert J A1 - Davis, William E. A1 - Karekla, Maria A1 - Zorjan, Saša A1 - Jaremka, Lisa M. A1 - Uttley, Jim A1 - Hricova, Monika A1 - Koehn, Monica A A1 - Kiselnikova, Natalia A1 - Bai, Hui A1 - Krafnick, Anthony J. A1 - Balci, Busra Bahar A1 - Ballantyne, Tonia A1 - Lins, Samuel A1 - Vally, Zahir A1 - Esteban-Serna, Celia A1 - Schmidt, Kathleen A1 - Macapagal, Paulo Manuel L. A1 - Szwed, Paulina A1 - Zdybek, Przemysław Marcin A1 - Moreau, David A1 - Collins, W. Matthew A1 - Joy-Gaba, Jennifer A. A1 - Vilares, Iris A1 - Tran, Ulrich S. A1 - Boudesseul, Jordane A1 - Albayrak-Aydemir, Nihan A1 - Dixson, Barnaby James Wyld A1 - Perillo, Jennifer T A1 - Ferreira, Ana A1 - Westgate, Erin C. A1 - Aberson, Christopher L. A1 - Arinze, Azuka Ikechukwu A1 - Jaeger, Bastian A1 - Butt, Muhammad Mussaffa A1 - Silva, Jaime R. A1 - Storage, Daniel Shafik A1 - Janak, Allison P A1 - Jiménez-Leal, William A1 - Soto, Jose A. A1 - Sorokowska, Agnieszka A1 - McCarthy, Randy A1 - Tullett, Alexa M A1 - Frias-Armenta, Martha A1 - Ribeiro, Matheus Fernando Felix A1 - Hartanto, Andree A1 - Forbes, Paul A. G. A1 - Willis, Megan L. A1 - del Carmen Tejada R, María A1 - Torres, Adriana Julieth Olaya A1 - Stephen, Ian D A1 - Vaidis, David C. A1 - de la Rosa-Gómez, Anabel A1 - Yu, Karen A1 - Sutherland, Clare A. M. A1 - Manavalan, Mathi A1 - Behzadnia, Behzad A1 - Urban, Jan A1 - Baskin, Ernest A1 - McFall, Joseph P. A1 - Ogbonnaya, Chisom Esther A1 - Fu, Cynthia H. Y. A1 - Rahal, Rima-Maria A1 - Ndukaihe, Izuchukwu L. G. A1 - Hostler, Thomas J. A1 - Kappes, Heather Barry A1 - Sorokowski, Piotr A1 - Khosla, Meetu A1 - Lazarevic, Ljiljana B. A1 - Eudave, Luis A1 - Vilsmeier, Johannes K. A1 - Luis, Elkin O. A1 - Muda, Rafał A1 - Agadullina, Elena A1 - Cárcamo, Rodrigo A. A1 - Reeck, Crystal A1 - Anjum, Gulnaz A1 - Venegas, Mónica Camila Toro A1 - Misiak, Michal A1 - Ryan, Richard M. A1 - Nock, Nora L. A1 - Travaglino, Giovanni A. A1 - Mensink, Michael C. A1 - Feldman, Gilad A1 - Wichman, Aaron L. A1 - Chou, Weilun A1 - Ziano, Ignazio A1 - Seehuus, Martin A1 - Chopik, William J. A1 - Kung, Franki Y. H. A1 - Carpentier, Joelle A1 - Vaughn, Leigh Ann A1 - Du, Hongfei A1 - Xiao, Qinyu A1 - Lima, Tiago J. S. A1 - Noone, Chris A1 - Onie, Sandersan A1 - Verbruggen, Frederick A1 - Radtke, Theda A1 - Primbs, Maximilian A. T1 - The psychological science accelerator’s COVID-19 rapid-response dataset T2 - Scientific Data Y1 - 2023 U6 - https://doi.org/10.1038/s41597-022-01811-7 SN - 2052-4463 VL - 10 IS - 1 SP - 1 EP - 15 PB - Springer Science and Business Media LLC ER - TY - GEN A1 - Veldkamp, Edzo A1 - Schmidt, Marcus A1 - Markwitz, Christian A1 - Beule, Lukas A1 - Beuschel, René A1 - Biertümpfel, Andrea A1 - Bischel, Xenia A1 - Duan, Xiaohong A1 - Gerjets, Rowena A1 - Göbel, Leonie A1 - Graß, Rüdiger A1 - Guerra, Victor A1 - Heinlein, Florian A1 - Komainda, Martin A1 - Langhof, Maren A1 - Luo, Jie A1 - Potthoff, Martin A1 - Ramshorst, Justus G. V. van A1 - Rudolf, Carolin A1 - Seserman, Diana-Maria A1 - Shao, Guodong A1 - Siebicke, Lukas A1 - Svoboda, Nikolai A1 - Swieter, Anita A1 - Carminati, Andrea A1 - Freese, Dirk A1 - Graf, Torsten A1 - Greef, Jörg M. A1 - Isselstein, Johannes A1 - Jansen, Martin A1 - Karlovsky, Petr A1 - Knohl, Alexander A1 - Lamersdorf, Norbert A1 - Priesack, Eckart A1 - Wachendorf, Christine A1 - Wachendorf, Michael A1 - Corre, Marife D. T1 - Multifunctionality of temperate alley-cropping agroforestry outperforms open cropland and grassland T2 - Communications Earth & Environment N2 - AbstractIntensively managed open croplands are highly productive but often have deleterious environmental impacts. Temperate agroforestry potentially improves ecosystem functions, although comprehensive analysis is lacking. Here, we measured primary data on 47 indicators of seven ecosystem functions in croplands and 16 indicators of four ecosystem functions in grasslands to assess how alley-cropping agroforestry performs compared to open cropland and grassland. Carbon sequestration, habitat for soil biological activity, and wind erosion resistance improved for cropland agroforestry (P ≤ 0.03) whereas only carbon sequestration improved for grassland agroforestry (P < 0.01). In cropland agroforestry, soil nutrient cycling, soil greenhouse gas abatement, and water regulation did not improve, due to customary high fertilization rates. Alley-cropping agroforestry increased multifunctionality, compared to open croplands. To ameliorate the environmental benefits of agroforestry, more efficient use of nutrients is required. Financial incentives should focus on conversion of open croplands to alley-cropping agroforestry and incorporate fertilizer management. Y1 - 2023 U6 - https://doi.org/10.1038/s43247-023-00680-1 SN - 2662-4435 VL - 4 IS - 1 PB - Springer Science and Business Media LLC ER - TY - GEN A1 - Pfetsch, Marc E. A1 - Fügenschuh, Armin A1 - Geißler, Björn A1 - Geißler, Nina A1 - Gollmer, Ralf A1 - Hiller, Benjamin A1 - Humpola, Jesco A1 - Koch, Thorsten A1 - Lehmann, Thomas A1 - Martin, Alexander A1 - Morsi, Antonio A1 - Rövekamp, Jessica A1 - Schewe, Lars A1 - Schmidt, Martin A1 - Schultz, Rüdiger A1 - Schwarz, Robert A1 - Schweiger, Jonas A1 - Stangl, Claudia A1 - Steinbach, Marc C. A1 - Vigerske, Stefan A1 - Willert, Bernhard M. T1 - Validation of Nominations in Gas Network Optimization: Models, Methods, and Solutions T2 - Optimization Methods and Software Y1 - 2015 U6 - https://doi.org/10.1080/10556788.2014.888426 SN - 1055-6788 SN - 1029-4937 VL - 30 IS - 1 SP - 15 EP - 53 ER - TY - GEN A1 - Grönke, Martin A1 - Schmidt, Peer A1 - Valldor, Martin A1 - Oswald, Steffen A1 - Wolf, Daniel A1 - Lubk, Axel A1 - Büchner, Bernd A1 - Hampel, Silke T1 - Chemical vapor growth and delamination of α-RuCl3 nanosheets down to the monolayer limit T2 - Nanoscale N2 - 2D layered honeycomb magnet α-ruthenium(III) chloride (α-RuCl3) is a promising candidate to realize a Kitaev spin model. As alteration of physical properties on the nanoscale is additionally intended, new synthesis approaches to obtain phase pure α-RuCl3 nanocrystals have been audited. Thermodynamic simulations of occurring gas phase equilibria were performed and optimization of synthesis conditions was achieved based on calculation results. Crystal growth succeeded via chemical vapor transport (CVT) in a temperature gradient of 973 K to 773 K on YSZ substrates. Single crystal sheets of high crystallinity with heights ≤ 30 nm were obtained via pure CVT. The crystal properties were characterized by means of optical and electron microscopy, AFM, SAED, micro-Raman and XPS proving their composition, morphology, crystallinity and phase-purity. A highlight of our study is the successful individualization of nanocrystals and the delamination of nanosheets on YSZ substrates down to the monolayer limit (≤ 1 nm) which was realized by means of substrate exfoliation and ultrasonication in a very reproducible way. KW - Crystal growth KW - Thermodynamic modeling KW - Chemical vapor transport KW - 2D layered compounds KW - Nanocrystals Y1 - 2018 UR - https://pubs.rsc.org/en/content/articlelanding/2018/nr/c8nr04667k#!divAbstract U6 - https://doi.org/10.1039/C8NR04667K SN - 2040-3372 VL - 10 IS - 40 SP - 19014 EP - 19022 ER - TY - GEN A1 - Grönke, Martin A1 - Pohflepp, Danny A1 - Schmidt, Peer A1 - Valldor, Martin A1 - Oswald, Steffen A1 - Wolf, Daniel A1 - Hao, Qi A1 - Steiner, Udo A1 - Büchner, Bernd A1 - Hampel, Silke T1 - Simulation and synthesis of alpha-MoCl₃ nanosheets on substrates by short time chemical vapor transport T2 - Nano-Structures & Nano-Objects N2 - Alpha-molybdenum(III) chloride (MoCl₃) belongs to layered van-der-Waals materials, which are in focus to exhibit interesting properties due to their weak chemical and magnetic interactions. Especially the structure of alpha-MoCl₃ has been discussed in terms of symmetry breaking dimerization of Mo atoms at room temperature, which might led to exotic ground states. By exploiting the 2D materials characteristics, an investigation of physical properties on the nanoscale is intended. We herein demonstrate the probably first approach to synthesize phase pure, as-grown alpha-MoCl₃ few-layer nanosheets by means of a pure short time chemical vapor transport (CVT) process. Vapor growth benefits from a one-step deposition of high crystalline alpha-MoCl₃ nanosheets without stacking faults on a substrate. Thus, mostly applied subsequent delamination, associated with the introduction of structural defects, becomes redundant. According to the CVT process thermodynamic simulations of gas phase equilibria have been performed and the synthesis conditions could be optimized based on the calculation results. By CVT the as-grown nanolayers are deposited on sapphire (Al₂O₃) substrates by applying a temperature gradient of 70 K from 743 K to 673 K. Single crystalline sheets with thicknesses ≤75 nm down to five layer (3 nm) could be obtained by using a pure CVT process. According to the deposited nanostructures we approve the desired composition, morphology, phase purity and high crystallinity by using several microscopy and spectroscopy techniques. Furthermore, we show micro-RAMAN measurements which hint at a slight increase in phonon energies for nanosheets in comparison to the corresponding bulk phase. KW - Crystal growth KW - Chemical vapor transport KW - 2D layered compounds KW - Halides Y1 - 2019 UR - https://www.sciencedirect.com/science/article/pii/S2352507X18304888?via%3Dihub#! U6 - https://doi.org/10.1016/j.nanoso.2019.100324 SN - 2352-507X IS - 19 SP - 1 EP - 7 ER - TY - GEN A1 - Grönke, Martin A1 - Arrozi, Ubed S. F. A1 - Bronkalla, Nadine A1 - Schmidt, Peer A1 - Valldor, Martin A1 - Oswald, Steffen A1 - Woodcock, Thomas G. A1 - Eckert, Victoria A1 - Hao, Qi A1 - Plüschke, Laura A1 - Lederer, Albena A1 - Nielsch, Kornelius A1 - Büchner, Bernd A1 - Kaskel, Stefan A1 - Hampel, Silke T1 - Layered α-TiCl₃: Microsheets on YSZ Substrates for Ethylene Polymerization with Enhanced Activity T2 - Chemistry of Materials N2 - The transition metal halide α-titanium(III) chloride (α-TiCl₃) is a layered two-dimensional compound and a well-established Ziegler–Natta catalyst for the polymerization of ethylene. A new synthesis technique is used to obtain thin sheets of α-TiCl₃ that show exceptional physical properties in contrast to their bulk counterparts, due to an enlarged surface-to-volume ratio. Chemical vapor transport (CVT) of α-titanium(III) chloride directly on substrates results in microsheets that exhibit an improved catalytic effect. For rational planning of synthesis conditions, thermodynamic simulations of occurring gas-phase equilibria were performed. Based on these calculation results, crystal growth was achieved by adding GaCl₃via pure short term CVT in a temperature gradient of 700–600 K on yttrium-stabilized zirconia (YSZ) substrates. Phase pure, as-grown, single crystal sheets with high crystallinity and a thickness of around 4 μm were obtained. These thin sheets of α-TiCl₃ on YSZ substrates were implemented as catalysts for the ethylene polymerization reaction. A significant improvement of catalytic activity of 16% was achieved, probably due to an increased surface-to-volume ratio. As a highlight, the as-grown microsheets were exfoliated subsequently to a thickness lower than 200 nm and an even higher catalytic activity of up to 24% was confirmed experimentally due to delamination effects. This is the first time that an improved catalytic effect of α-TiCl₃ is observed as a result of downscaling from bulk to microsheets by CVT. KW - Crystal growth KW - Chemical vapor transport KW - Thermodynamic modeling KW - 2D layered compounds KW - Halides KW - Nanocrystals (1) Y1 - 2019 UR - https://pubs.acs.org/doi/10.1021/acs.chemmater.9b01818 U6 - https://doi.org/10.1021/acs.chemmater.9b01818 VL - 31 IS - 14 SP - 5305 EP - 5313 ER - TY - GEN A1 - Grönke, Martin A1 - Buschbeck, Benjamin A1 - Schmidt, Peer A1 - Valldor, Martin A1 - Oswald, Steffen A1 - Hao, Qi A1 - Lubk, Axel A1 - Wolf, Daniel A1 - Steiner, Udo A1 - Büchner, Bernd A1 - Hampel, Silke T1 - Chromium Trihalides CrX₃(X = Cl, Br, I): Direct Deposition of Micro‐ and Nanosheets on Substrates by Chemical Vapor Transport T2 - Advanced Materials Interfaces N2 - The experimental observation of intrinsic ferromagnetism in single layered chromium trihalides CrX₃ (X = Cl, Br, I) has gained outstanding attention recently due to their possible implementation in spintronic devices. However, the reproducible preparation of highly crystalline chromium(III) halide nanolayers without stacking faults is still an experimental challenge. As chromium trihalides consist of adjacent layers with weak interlayer coupling, the preparation of ultrathin CrX₃ nanosheets directly on substrates via vapor transport proves as an advantageous synthesis technique. It is demonstrated that vapor growth of ultrathin highly crystalline CrX₃ micro‐ and nanosheets succeeds directly on yttrium stabilized zirconia substrates in a one‐step process via chemical vapor transport (CVT) in temperature gradients of 100 K (600°C → 500°C for CrCl₃ and 650°C → 550°C for CrBr₃ or CrI₃) without a need for subsequent delamination. Due to simulation results, optimization of synthesis conditions is realized and phase pure CrX₃ nanosheets with thicknesses ≤25 nm are obtained via short term CVT. The nanosheets morphology, crystallinity, and phase purity are analyzed by several techniques, including microscopy, diffraction, and spectroscopy. Furthermore, a potential subsequent delamination technique is demonstrated to give fast access to CrX₃ monolayers using the example of CrCl₃ . KW - 2D layered compounds KW - Crystal growth KW - Chemical vapor transport KW - Halides KW - Nanocrystals KW - Thermodynamic modeling Y1 - 2019 UR - https://onlinelibrary.wiley.com/doi/epdf/10.1002/admi.201901410 U6 - https://doi.org/10.1002/admi.201901410 SN - 2196-7350 VL - 6 IS - 24 ER - TY - GEN A1 - Fügenschuh, Armin A1 - Geißler, Björn A1 - Gollmer, Ralf A1 - Hayn, Christine A1 - Henrion, René A1 - Hiller, Benjamin A1 - Humpola, Jesco A1 - Koch, Thorsten A1 - Lehmann, Thomas A1 - Martin, Alexander A1 - Mirkov, Radoslava A1 - Morsi, Antonio A1 - Rövekamp, Jessica A1 - Schewe, Lars A1 - Schmidt, Martin A1 - Schultz, Rüdiger A1 - Schwarz, Robert A1 - Schweiger, Jonas A1 - Stangl, Claudia A1 - Steinbach, Marc C. A1 - Willert, Bernhard M. T1 - Mathematical Optimization for Challenging Network Planning Problems in Un- bundled Liberalized Gas Markets T2 - Energy Systems Y1 - 2014 U6 - https://doi.org/10.1007/s12667-013-0099-8 SN - 1868-3975 SN - 1868-3967 VL - 5 IS - 3 SP - 449 EP - 473 ER - TY - GEN A1 - Froeschke, Samuel A1 - Wolf, Daniel A1 - Hantusch, Martin A1 - Giebeler, Lars A1 - Wels, Martin A1 - Gräßler, Nico A1 - Büchner, Bernd A1 - Schmidt, Peer A1 - Hampel, Silke T1 - Synthesis of micro- and nanosheets of CrCl3–RuCl3 solid solution by chemical vapour transport T2 - Nanoscale N2 - Solid solutions of 2D transition metal trihalides are rapidly growing in interest for the search for new 2D materials with novel properties at nanoscale dimensions. In this regard, we present a synthesis method for the Cr1−xRuxCl3 solid solution and describe the behaviour of the unit cell parameters over the whole composition range, which in general follows Vegard's law in the range of a = 5.958(6)CrCl3 … 5.9731(5)RuCl3 Å, b = 10.3328(20)CrCl3 … 10.34606(21)RuCl3 Å, c = 6.110(5)CrCl3 … 6.0385(5)RuCl3 Å and β = 108.522(15)CrCl3 … 108.8314(14)RuCl3 °. The synthesized solid solution powder was subsequently used to deposit micro- and nanosheets directly on a substrate by applying chemical vapour transport in a temperature gradient of 575 °C → 525 °C for 2 h and 650 °C → 600 °C for 0.5 h as a bottom-up approach without the need for an external transport agent. The observed chromium chloride enrichment of the deposited crystals is predicted by thermodynamic simulation. The results allow for a nanostructure synthesis of this solid solution with a predictable composition down to about 30 nm in height and lateral size of several μm. When applying a quick consecutive delamination step, it is possible to obtain few- and monolayer structures, which could be used for further studies of downscaling effects for the CrCl3–RuCl3 solid solution. X-ray photoelectron spectroscopy, transmission electron microscopy and Raman spectroscopy were used to confirm the purity and quality of the synthesized crystals. KW - Crystal growth KW - Chemical vapor transport KW - Thermal analysis KW - Thermodynamic modeling KW - 2D layered compounds Y1 - 2022 UR - https://pubs.rsc.org/en/content/articlelanding/2022/NR/D2NR01366E U6 - https://doi.org/10.1039/D2NR01366E SN - 2040-3372 VL - 29 IS - 14 SP - 10483 EP - 10492 ER - TY - GEN A1 - Hall, Braeden A1 - Schmidt, Kathleen A1 - Wagge, Jordan A1 - Lewis, Savannah C. A1 - Weissgerber, Sophia C. A1 - Kiunke, Felix A1 - Pfuhl, Gerit A1 - Stieger, Stefan A1 - Tran, Ulrich S. A1 - Barzykowski, Krystian A1 - Bogatyreva, Natalia A1 - Kowal, Marta A1 - Massar, KarlIJn A1 - Pernerstofer, Felizitas A1 - Sorokowski, Piotr A1 - Voracek, Martin A1 - Chartier, Christopher R. A1 - Brandt, Mark J. A1 - Grahe, Jon E. A1 - Özdoğru, Asil A. A1 - Andreychik, Michael R. A1 - Chen, Sau-Chin A1 - Evans, Thomas R. A1 - Hautekiet, Caro A1 - IJzerman, Hans A1 - Kačmár, Pavol A1 - Krafnick, Anthony J. A1 - Musser, Erica D. A1 - Vergauwe, Evie A1 - Werner, Kaitlyn M. A1 - Aczel, Balazs A1 - Arriaga, Patrícia A1 - Batres, Carlota A1 - Beaudry, Jennifer L. A1 - Cova, Florian A1 - Ďurbisová, Simona A1 - Cramblet Alvarez, Leslie D. A1 - Feldman, Gilad A1 - Godbersen, Hendrik A1 - Gottfried, Jaroslav A1 - Haeffel, Gerald J. A1 - Hartanto, Andree A1 - Isloi, Chris A1 - McFall, Joseph P. A1 - Milyavskaya, Marina A1 - Moreau, David A1 - Nosáľová, Ester A1 - Papaioannou, Kostas A1 - Ruiz-Fernandez, Susana A1 - Schrötter, Jana A1 - Storage, Daniel A1 - Vezirian, Kevin A1 - Volz, Leonhard A1 - Weisberg, Yanna J. A1 - Xiao, Qinyu A1 - Awlia, Dana A1 - Branit, Hannah W. A1 - Dunn, Megan R. A1 - Groyecka-Bernard, Agata A1 - Haneda, Ricky A1 - Kielinska, Julita A1 - Kolle, Caroline A1 - Lubomski, Paweł A1 - Miller, Alexys M. A1 - Mækelæ, Martin J. A1 - Pantazi, Mytro A1 - Ribeiro, Rafael R. A1 - Ross, Robert M. A1 - Sorokowska, Agnieszka A1 - Aberson, Christopher L. A1 - Vassiliou, Xanthippi Alexi A1 - Baker, Bradley J. A1 - Bognar, Miklos A1 - Cong, Chin Wen A1 - Danvers, Alex F. A1 - Davis, William E. A1 - Dranseika, Vilius A1 - Dumbravă, Andrei A1 - Farmer, Harry A1 - Field, Andy P. A1 - Forscher, Patrick S. A1 - Graton, Aurélien A1 - Hajdu, Nandor A1 - Howlett, Peter A. A1 - Kabut, Radosław A1 - Larsen, Emmett M. A1 - Lee, Sean T. H. A1 - Legate, Nicole A1 - Levitan, Carmel A. A1 - Levy, Neil A1 - Lu, Jackson G. A1 - Misiak, Michał A1 - Morariu, Roxana E. A1 - Novak, Jennifer A1 - Pronizius, Ekaterina A1 - Prusova, Irina A1 - Rathnayake, Athulya S. A1 - Romanova, Marina O. A1 - Röer, Jan P. A1 - Sampaio, Waldir M. A1 - Schild, Christoph A1 - Schulte-Mecklenbeck, Michael A1 - Stephen, Ian D. A1 - Szecsi, Peter A1 - Takacs, Elizabeth A1 - Teeter, Julia N. A1 - Thiele-Evans, Elian H. A1 - Valeiro-Paterlini, Julia A1 - Vilares, Iris A1 - Villafana, Louise A1 - Wang, Ke A1 - Wu, Raymond A1 - Álvarez-Solas, Sara A1 - Moshontz, Hannah A1 - Buchanan, Erin M. T1 - Registered Replication Report: A Large Multilab Cross-Cultural Conceptual Replication of Turri et al. (2015) T2 - Advances in Methods and Practices in Psychological Science Y1 - 2024 U6 - https://doi.org/10.1177/25152459241267902 SN - 2515-2459 VL - 7 IS - 4 SP - 1 EP - 38 PB - SAGE Publications ER -