TY - CHAP A1 - Lange, Ulrich A1 - Roznyatovskaya, Nataliya V. A1 - Hao, Qingli A1 - Mirsky, Vladimir M. ED - Mirsky, Vladimir M. ED - Yatsimirsky, Anatoly K. T1 - Conducting polymers as artificial receptors in chemical sensors T2 - Artificial receptors for chemical sensors KW - artificial receptors polyaniline KW - chemosensors KW - conducting polymers KW - polyaniline KW - transducers Y1 - 2011 SN - 978-3-527-32357-9 U6 - https://doi.org/10.1002/9783527632480.ch12 SP - 363 EP - 392 PB - Wiley-VCH CY - Weinheim ER - TY - GEN A1 - Lange, Ulrich A1 - Roznyatovskaya, Nataliya V. A1 - Mirsky, Vladimir M. T1 - Conducting polymers in chemical sensors and arrays (invited review) T2 - Analytica Chimica Acta N2 - The review covers main applications of conducting polymers in chemical sensors and biosensors. The first part is focused on intrinsic and induced receptor properties of conducting polymers, such as pH sensitivity, sensitivity to inorganic ions and organic molecules as well as sensitivity to gases. Induced receptor properties can be also formed by molecularly imprinted polymerization or by immobilization of biological receptors. Immobilization strategies are reviewed in the second part. The third part is focused on applications of conducting polymers as transducers and includes usual optical (fluorescence, SPR, etc.) and electrical (conductometric, amperometric, potentiometric, etc.) transducing techniques as well as organic chemosensitive semiconductor devices. An assembly of stable sensing structures requires strong binding of conducting polymers to solid supports. These aspects are discussed in the next part. Finally, an application of combinatorial synthesis and high-throughput analysis to the development and optimization of sensing materials is described. KW - Conducting polymers KW - Chemical sensors KW - Electroactive polymers KW - Gas sensors KW - Combinatorial techniques KW - Electropolymerization KW - Sensor array Y1 - 2008 U6 - https://doi.org/10.1016/j.aca.2008.02.068 SN - 0003-2670 VL - 614 IS - 1 SP - 1 EP - 26 ER - TY - GEN A1 - Roznyatovskaya, Nataliya V. A1 - Laurinavichyute, Veronika K. A1 - Tsirlina, Galina A. A1 - Mirsky, Vladimir M. T1 - Electrochemistry and catalytic behavior of immobilized binuclear complexes of copper(II) and nickel(II) with Robson type ligand T2 - Journal of Solid State Electrochemistry N2 - Various systems containing immobilized binuclear copper(II) and nickel(II) complexes with Robson type ligand ([M2L]Cl2) are studied and compared in relation to catalysis of hydrogen peroxide reduction. Molecular complexes adsorbed on mercury and gold, crystalline complexes immobilized in the carbon paste electrode, and complex species entrapped into polyphenol-modified gold electrodes are considered. Electrocatalysis is assumed to result from the formation of H2O2–[M2L]Cl2 adduct, not from mediating redox transformations. Possible geometry of the formed reaction layers supporting adduct formation is discussed. KW - Binuclear copper macrocyclic complex KW - Cyclic voltammetry KW - Adsorption KW - Carbon paste electrodes KW - Electroreduction Y1 - 2007 U6 - https://doi.org/10.1007/s10008-006-0235-7 SN - 1432-8488 SN - 1433-0768 VL - 11 IS - 7 SP - 981 EP - 992 ER -