TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Repmann, Frank A1 - Raab, Thomas T1 - Stability of Prussian Blue in Soils of a Former Manufactured Gas Plant Site T2 - Soil and Sediment Contamination N2 - Soil contamination with iron-cyanide complexes is a common problem at former manufactured gas plant (MGP) sites. Dissolution of the cyanide, from Prussian Blue (ferric ferrocyanide), creates an environmental hazard, whereas the risk of groundwater contamination depends on the stability of dissolved iron–cyanide complexes. Lack of a standard leaching method to determine the water-soluble (plant-available) cyanide fraction generates potential limitations for implementing remediation strategies like phytoremediation. Applicability of neutral solution extraction to determine the water-soluble cyanide fraction and the stability of Prussian Blue in surface and near-surface soils of an MGP site in Cottbus, undersaturated and unsaturated water conditions, was studied in column leaching and batch extraction experiments. MGP soils used in the long-term tests varied according to the pH (5.0–7.7) and the total cyanide content (40–1718 mg kg−1). Column leaching, after four months of percolation, still yielded effluent concentrations exceeding the German drinking water limit (> 50 μg L−1) and the solubility of Prussian Blue reported in the literature (< 1 mg L−1) from both alkaline and acidic soils. Long-term (1344 h) extraction of MGP soils with distilled water was sufficient to dissolve 97% of the total cyanide from the slightly alkaline soils and up to 78% from the acidic soils. Both experiments revealed that dissolution of ferric ferrocyanide under circum-neutral pH and oxic water conditions is a function of time, where the released amount is dependent on the soil pH and total cyanide content. Unexpectedly high and continuous solubility of Prussian Blue, both in acidic and slightly alkaline MGP soils, implies the need to introduce an additional cyanide fraction (“readily soluble fraction”) to improve and specify cyanide leaching methods. Long-term extraction of cyanide-contaminated soil in neutral solution seems to be a promising approach to evaluate the potential hazard of groundwater pollution at the MGP sites. Y1 - 2014 U6 - https://doi.org/10.1080/15320383.2014.839626 SN - 1549-7887 VL - 23 IS - 5 SP - 504 EP - 522 ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Boldt-Burisch, Katja A1 - Raab, Thomas T1 - Effect of ryegrass (Lolium perenne L.) roots inoculation using different arbuscular mycorrhizal fungi (AMF) species on sorption of iron-cyanide (Fe-CN) complexes T2 - European Geosciences Union, General Assembly 2016, Vienna, Austria, 17 April – 22 May 2016 N2 - Soils and groundwater on sites of the former Manufactured Gas Plants (MGPs) are contaminated with various complex iron-cyanides (Fe-CN). Phytoremediation is a promising tool in stabilization and remediation of Fe-CN affected soils, however, it can be a challenging task due to extreme adverse and toxic conditions. Phytoremediation may be enhanced via rhizosphere microbial activity, which can cooperate on the degradation, transformation and uptake of the contaminants. Recently, increasing number of scientist reports improved plants performance in the removal of toxic compounds with the support of arbuscular mycorrhizae fungi (AMF). Series of batch experiments using potassium hexacyanoferrate (II) solutions, in varying concentrations, were used to study the effect of ryegrass roots (Lolium perenne L.) inoculation with Rhizophagus irregularis and a mixture of Rhizophagus irregularis, Funneliformis mosseae, Rhizophagus aggregatus, and Claroideoglomus etunicatum on Fe-CN sorption. Results indicated significantly higher colonization of R. irregularis than for the mixture of AMF species on ryegrass roots. Sorption experiments revealed significantly higher reduction of total CN and free CN content in the mycorrhizal roots, indicating greater cyanide decrease in the treatment inoculated with R. irregularis. Our study indicates contribution of AM fungi in phytoremediation of Fe-CN contaminated soil. Y1 - 2016 UR - http://meetingorganizer.copernicus.org/EGU2016/EGU2016-4223-2.pdf N1 - EGU2016-4223-2 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Repmann, Frank A1 - Raab, Thomas T1 - Retardation of iron-cyanide complexes in the soil of a former manufactured gas plant site T2 - Journal of Environmental Science and Health, Part A N2 - The soil in the vicinities of former Manufactured Gas Plant (MGP) sites is commonly contaminated with iron-cyanide complexes (ferric ferrocyanide). The phenomenon of cyanide mobility in soil, according to the literature, is mainly governed by the dissolution and precipitation of ferric ferrocyanide, which is only slightly soluble (<1 mg L¡1) under acidic conditions. In this paper, retention properties of the sandy loam soil and the potential vertical movement of the solid iron-cyanide complexes, co-existing with the dissolution, sorption and precipitation reactions were investigated. Preliminary research conducted on a former MGP site implied colloidal transport of ferric ferricyanide from the initial deposition in the wastes layer towards the sandy loam material (secondary accumulation), which possibly retarded the mobility of cyanide (CN). A series of batch and column experiments were applied in order to investigate the retardation of iron-cyanide complexes by the sandy loam soil. Batch experiments revealed that in circumneutral pH conditions sandy loam material decreases the potassium ferro- and ferricyanide concentration. In column experiments a minor reduction in CN concentration was observed prior to addition of iron sulfide (FeS) layer, which induced the formation of the Prussian blue colloids in circumneutral pH conditions. Precipitated solid iron-cyanide complexes were mechanically filtered by the coherent structure of the investigated soil. Additionally, the reduction of the CN concentration of the percolation solutions by the sandy loam soil was presumably induced due to the formation of potassium manganese iron-cyanide (K2Mn[Fe(CN)6]). Y1 - 2015 U6 - https://doi.org/10.1080/10934529.2015.981116 SN - 1532-4117 SN - 1093-4529 VL - 50 IS - 3 SP - 282 EP - 291 ER - TY - GEN A1 - Sut-Lohmann, Magdalena A1 - Boldt-Burisch, Katja A1 - Raab, Thomas T1 - Possible evidence for contribution of arbuscular mycorrhizal fungi (AMF) in phytoremediation of iron–cyanide (Fe–CN) complexes T2 - Ecotoxicology N2 - Arbuscular mycorrhizal fungi (AMF) are integral functioning parts of plant root systems and are widely recognized for enhancing contaminants uptake and metabolism on severely disturbed sites. However, the patterns of their influence on the phytoremediation of iron–cyanide (Fe–CN) complexes are unknown. Fe–CN complexes are of great common interest, as iron is one of the most abundant element in soil and water. Effect of ryegrass (Lolium perenne L.) roots inoculation, using mycorrhizal fungi (Rhizophagus irregularis and a mixture of R. irregularis, Funneliformis mosseae, Rhizophagus aggregatus, and Claroideoglomus etunicatum), on iron–cyanide sorption was studied. Results indicated significantly higher colonization of R. irregularis than the mixture of AMF species on ryegrass roots. Series of batch experiments using potassium hexacyanoferrate (II) solutions, in varying concentrations revealed significantly higher reduction of total CN and free CN content in the mycorrhizal roots, indicating greater cyanide decrease in the treatment inoculated with R. irregularis. Our study is a first indication of the possible positive contribution of AM fungi on the phytoremediation of iron–cyanide complexes. Y1 - 2016 UR - http://link.springer.com/article/10.1007%2Fs10646-016-1678-y U6 - https://doi.org/10.1007/s10646-016-1678-y SN - 1573-3017 VL - 25 IS - 6 SP - 1260 EP - 1269 ER - TY - GEN A1 - Dimitrova, Tsvetelina A1 - Repmann, Frank A1 - Raab, Thomas A1 - Freese, Dirk T1 - Uptake of ferrocyanide in willow and poplar trees in a long term greenhouse experiment T2 - Ecotoxicology N2 - Phytoremediation of sites contaminated with iron cyanides can be performed using poplar and willow trees. Poplar and willow trees were grown in potting substrate spiked with ferrocyanide concentrations of up to 2,000 mg kg-1 for 4 and 8 weeks respectively. Soil solution and leaf tissue of different age were sampled for total cyanide analysis every week. Chlorophyll content in the leaves was determined to quantify cyanide toxicity. Results showed that cyanide in the soil solution of spiked soils differed between treatments and on weekly basis and ranged from 0.5 to 1,200 mg l-1. The maximum cyanide content in willow and poplar leaves was 518 mg kg-1 fresh weight (FW) and 148 mg kg-1 FW respectively. Cyanide accumulated in the leaves increased linearly with increasing cyanide concentration in the soil solution. On the long term, significantly more cyanide was accumulated in old leaf tissue than in young tissue. Chlorophyll content in poplar decreased linearly with increasing cyanide in the soil solution and in leaf tissue, and over time. The inhibitory concentration (IC50) value for poplars after 4 weeks of exposure was 173 mg l-1 and for willow after 8 weeks of exposure—768 mg l-1. Results show that willows tolerate much more cyanide and over a longer period than poplars, making them very appropriate for remediating sites highly contaminated with iron cyanides. Y1 - 2015 U6 - https://doi.org/10.1007/s10646-014-1398-0 SN - 1573-3017 VL - 24 IS - 3 SP - 510 ER - TY - CHAP A1 - Kappler, Christoph A1 - Kaiser, Knut A1 - Ganzenmüller, Raphael A1 - Küster, Mathias A1 - Nicolay, Alexander A1 - Fülling, Alexander A1 - Bens, Oliver A1 - Raab, Thomas ED - Schwab, Markus J. ED - Theuerkauf, Martin ED - Brauer, Achim ED - Wilmking, Martin ED - Lampe, Reinhard T1 - A review of geochronological data from northeastern Germany: evaluating late Quaternary soil formation and land surface dynamics T2 - 3rd Annual ICLEA Workshop 2014, Dynamics of Climate and Landscape Evolution of Cultural Landscapes in the Northern Central European Lowlands since the Last Ice Age Y1 - 2014 U6 - https://doi.org/10.2312/GFZ.b103-14028 SP - 43 PB - GFZ German Research Centre for Geosciences CY - Potsdam ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Boldt-Burisch, Katja A1 - Raab, Thomas T1 - Influence of Arbuscular Mycorrhizal Fungus (AMF) on degradation of iron-cyanide complexes T2 - European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015 KW - arbuscular mycorrhizal fungus Y1 - 2015 UR - http://meetingorganizer.copernicus.org/EGU2015/EGU2015-250.pdf N1 - EGU2015-250 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Repmann, Frank A1 - Raab, Thomas T1 - Vertical movement of iron-cyanide complexes in soils of a former Manufactured Gas Plant site T2 - European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015 Y1 - 2015 UR - http://meetingorganizer.copernicus.org/EGU2015/EGU2015-9980.pdf N1 - EGU2015-9980 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Sut-Lohmann, Magdalena A1 - Repmann, Frank A1 - Raab, Thomas T1 - Release of iron-cyanide complexes form contaminated soils - Batch and column experiments on substrates from Manufactured Gas Plant (MGP) site T2 - European Geosciences Union General Assembly 2013, Vienna, Austria, 07 – 12 April 2013 N2 - Soils of former Manufactured Gas Plants (MGPs) are often contaminated with iron-cyanide (Fe-CN) complexes that originate from gas purification process. Cyanide is a potentially toxic substance and its presence in soil and groundwater may cause risk for human health as well as for the environment. MGPs were commonly built on the city suburban areas, which have spread ever since. Nowadays, these sites are typically located in inner cities, causing environmental thread, due to the leaching of pollutants. More recently, columns and batch experiments have been used to study fate and mobility of contaminants is soil. The release of iron-cyanide complexes under unsaturated flow conditions was evaluated with eight columns of 30 cm length and a diameter of 5,4 cm. Cyanide concentrations in the collected leachates were measured with Flow Injection Analysis (FIA). Additionally pH, electrical conductivity (EC) and various ion concentrations were determined. In order to compare the release of Fe-CN complexes in saturated conditions a batch experiment was conducted, where in defined time intervals, 1 ml of the extract water phase was analyzed for CN concentration. Study revealed an analogous trend of cyanide release in both experiments indicating primarily the release of formerly dissolved phase (hexacyanoferrates) followed by continual dissolution of ferric ferrocyanide. We conclude that batch experiments, conducted prior to column analysis, can serve as preliminary prediction of the water soluble cyanide fraction under unsaturated conditions. Y1 - 2013 UR - http://meetingorganizer.copernicus.org/EGU2013/EGU2013-1983.pdf N1 - EGU2013-1983 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - GEN A1 - Rodionov, Andrei A1 - Nii-Annang, Seth A1 - Bens, Oliver A1 - Trimborn, Manfred A1 - Schillem, Steffi A1 - Schneider, Bernd Uwe A1 - Raab, Thomas A1 - Hüttl, Reinhard F. T1 - Impacts of Soil Additives on Crop Yield and C-Sequestration in Post Mine Substrates of Lusatia, Germany T2 - Pedosphere Y1 - 2012 SN - 1002-0160 VL - 22 IS - 3 SP - 343 EP - 350 ER - TY - GEN A1 - Krümmelbein, Julia A1 - Horn, Rainer A1 - Raab, Thomas A1 - Bens, Oliver A1 - Hüttl, Reinhard F. T1 - Soil physical parameters of a recently established agricultural recultivation site after brown coal mining in Eastern Germany T2 - Soil & Tillage Research N2 - Our study deals with agricultural recultivation of open cast brown coal mining areas in Lusatia, Eastern Germany. In this region the largest brown coal (lignite) mining area of Germany is located. Lignite mining activities lead to major disturbances of the landscape. Recultivation efforts attempt to regenerate mining areas for agricultural land use options. The geological “parent” material is of saaleian origin, has a sandy texture and was excavated from several meters depths before mining and is now used for recultivating the excavated area. Consequently, it is free of recent soil organic carbon. The substrate itself is unstructured. The partly wet or dry substrate is subjected to strong mechanical stresses during the excavation, deposition, refilling and levelling processes throughout the year. This practice leads to more or less compacted soils/substrates which may result in small yields of agricultural crops. In this context we investigate the effect of different organic soil additives in combination with different recultivation crop rotations on the development of soil structure for improved agricultural land use. Our experimental site has been heaped up and levelled off in 2006 and 2007. On each of the 24 experimental sub areas undisturbed soil samples have been taken to characterise the substrates according to their mechanical and hydraulic parameters and to determine the scattering of these parameters on a site that is assumed to be recultivated as homogenously as possible. First results of our ongoing experimental study indicate that the soil physical properties such as texture, bulk density, precompression stress, air permeability and saturated hydraulic conductivity are not identical on each of the 24 subplots. The soil physical properties behave differently in relation to each other. E.g. we found a negative correlation between bulk density (∼1.35–∼1.90 g/cm3) and precompression stress (∼30–70 kPa) and no decisive interrelation between bulk density and air permeability or saturated hydraulic conductivity. Y1 - 2010 UR - http://www.sciencedirect.com/science/article/pii/S0167198710001443 U6 - https://doi.org/10.1016/j.still.2010.08.006 SN - 0167-1987 VL - 111 IS - 1 SP - 19 EP - 25 ER - TY - GEN A1 - Raab, Thomas A1 - Hürkamp, Kerstin A1 - Völkel, Jörg T1 - Stratigraphy and chronology of late Quaternary floodplain sediments in a historic mining area, Vils River Valley, East Bavaria, Germany T2 - Physical Geography N2 - Analysis of 288 percussion drillings from depths of up to seven meters and a 120 m long excavated section provide new and detailed information on the Late Quaternary to Late Holocene floodplain evolution from the most important Central European iron-mining region of the 15th century. The generalized sequence of the Vils River floodplain is built of five units representing facies of different genesis (rock/saprolite, gravel, sand, loam, peat) that are identified by physical, chemical, and mineralogical parameters (grain size, clast shape, and content, TOC, bulk mineralogy). Along the 87 km length of the valley, different units/facies are found at the Upper Vils River (UVR 1-5) and at the Lower Vils River (LVR 1-4b). In both river sections, fine-grained material (flood loam) forms the major part (up to 4 m) of the alluvial sequence. 29 age determinations (24 14C, 4 IRSL, 1 tree-ring analysis) show increasing accumulation of flood loam in the last millennium. The data correlate with the beginning of mining at the Vils River and hence suggest a causal connection with mining activities in the catchment—both on the slopes and in the floodplain—with intense deposition of flood loams. Y1 - 2010 UR - http://www.tandfonline.com/doi/abs/10.2747/0272-3646.31.4.357 U6 - https://doi.org/10.2747/0272-3646.31.4.357 SN - 1930-0557 SN - 0272-3646 VL - 31 IS - 4 SP - 357 EP - 384 ER - TY - GEN A1 - Nii-Annang, Seth A1 - Rodionov, Andrei A1 - Raab, Thomas A1 - Bens, Oliver A1 - Hüttl, Reinhard F. A1 - Dilly, Oliver T1 - Impact of Commercial Soil Additives on Microbial Activity and Carbon Isotopic Characteristics of Recultivated Post Lignite Mine Soils T2 - Geomicrobiology Journal Y1 - 2011 SN - 1521-0529 VL - 28 IS - 7 SP - 567 EP - 573 ER - TY - GEN A1 - Raab, Thomas A1 - Leopold, Matthias A1 - Völkel, Jörg T1 - Character, Age, and ecological significance of pleistocene periglacial slope deposits in Germany T2 - Physical Geography Y1 - 2007 U6 - https://doi.org/10.2747/0272-3646.28.6.451 SN - 1930-0557 VL - 28 IS - 6 SP - 451 EP - 473 ER - TY - CHAP A1 - Stock, Oliver A1 - Bens, Oliver A1 - Helbach, Christoph A1 - Narra, Satyanarayana A1 - Downes, Nigel K. A1 - Hüttl, Reinhard F. A1 - Raab, Thomas ED - Hüttl, Reinhard F. ED - Schneider, Bernd Uwe T1 - Bodenphysikalische, wachstumskundliche und rechtliche Aspekte der Melioration stark toniger Kippsubstrate mit REA-Gips T2 - Neue Ansätze in der land- und forstwirtschaftlichen Rekultivierung Y1 - 2009 SN - 978-3-937728-06-3 SN - 3-937728-06-6 SP - 45 EP - 77 PB - BTU CY - Cottbus ER - TY - GEN A1 - Hürkamp, Kerstin A1 - Raab, Thomas A1 - Völkel, Jörg T1 - Two and three-dimensional quantification of lead contamination in alluvial soils of a historic mining area using field portable X-ray fluorescence (FPXRF) analysis T2 - Geomorphology Y1 - 2009 U6 - https://doi.org/10.1016/j.geomorph.2008.12.021 VL - 110 IS - 1-2 SP - 28 EP - 36 ER - TY - GEN A1 - Hürkamp, Kerstin A1 - Raab, Thomas A1 - Völkel, Jörg T1 - Lead Pollution of Floodplain Soils in a Historic Mining Area - Age, Distribution and Binding Forms T2 - Water Air Soil Pollution Y1 - 2009 U6 - https://doi.org/10.1007/s11270-008-9948-9 SN - 1573-2932 VL - 201 IS - 1-4 SP - 331 EP - 345 ER - TY - BOOK A1 - Gerwin, Werner A1 - Schillem, Steffi A1 - Asch, Folkard A1 - Bens, Oliver A1 - Bestajovsky, Jürgen A1 - Bruns, Christian A1 - Gattinger, Andreas A1 - Hattig, Tom A1 - Hoogen, Heiner A1 - Hüttl, Reinhard F. A1 - Raab, Thomas A1 - Rodionov, Andrei A1 - Schaaf, Wolfgang A1 - Schneider, Bernd Uwe A1 - Trimborn, Manfred ED - Hüttl, Reinhard F. ED - Gerwin, Werner T1 - Bodenmelioration und Anbauverfahren für trockenheitsgefährdete Standorte (BAtroS) Y1 - 2011 SN - 978-3-937728-14-8 PB - FZLB CY - Cottbus ER - TY - CHAP A1 - Gerwin, Werner A1 - Raab, Thomas A1 - Dimitrov, M. T1 - Interactions between surface structures, runoff and erosion in an artificial watershed during the initial ecosystem development T2 - EGU General Assembly 2009, Vienna, Austria, 19 – 24 April 2009 Y1 - 2009 N1 - EGU2009-1406 PB - European Geophysical Society CY - Katlenburg-Lindau ER - TY - CHAP A1 - Stock, Oliver A1 - Bens, Oliver A1 - Hüttl, Reinhard F. A1 - Raab, Thomas ED - Hüttl, Reinhard F. ED - Schneider, Bernd Uwe T1 - Initiale Bodenbildung an landwirtschaftlichen Rekultivierungsstandorten aus saalezeitlichem Geschiebemergel T2 - Neue Ansätze in der land- und forstwirtschaftlichen Rekultivierung Y1 - 2009 SN - 978-3-937728-06-3 SN - 3-937728-06-6 SP - 3 EP - 43 PB - BTU CY - Cottbus ER - TY - CHAP A1 - Völkel, Jörg A1 - Leopold, Matthias A1 - Raab, Thomas ED - Maier, Jörg T1 - Ostbayerische Mittelgebirge T2 - Exkursionsführer zu ausgewählten Fachthemen Oberfrankens, Nürnbergs und der Nördlichen Oberpfalz Y1 - 2007 SN - 978-3-9809181-9-0 SP - 209 EP - 224 PB - Fachgruppe Geowissenschaften Universität Bayreuth CY - Bayreuth ER -