TY - GEN A1 - Ewert, Moritz A1 - Schmidt, Thomas A1 - Flege, Jan Ingo A1 - Heidmann, Inga A1 - Grzela, Tomasz A1 - Klesse, Wolfgang Matthias A1 - Förster, M. A1 - Aballe, Lucia A1 - Schröder, Thomas T1 - Morphology and Chemical Composition of Co Germanide islands on Ge(001): in-situ nanoscale insights into contact formation for Ge-based device technology T2 - Nanotechnology Y1 - 2016 SN - 1361-6528 SN - 0957-4484 VL - 27 IS - 32 SP - 325705 ER - TY - GEN A1 - Danielzyk, Rainer A1 - Eberhard, Lisa A1 - Eltges, Markus A1 - Erb, Katrin A1 - Flamm, Lena A1 - Huhold, Carola A1 - Knippschild, Robert A1 - Knorr-Siedow, Thomas A1 - Korzer, Tanja A1 - Leuschner, Silke A1 - Liebmann, Heike A1 - Maikämper, Moritz A1 - Matern, Antje A1 - Nagler, Heinz A1 - Prytula, Michael A1 - Schmidt-Lauber, Brigitta Johanna A1 - Stevens, James Miller A1 - Thiel, Fabian A1 - Weidner, Silke A1 - Zimmermann, Lars ED - Flamm, Lena ED - Klöden-Billemont, Agnès ED - Maikämper, Moritz ED - Stevens, James Miller ED - Weidner, Silke T1 - Provinzstädte – Neu definiert N2 - Der 2. Hochschultag vor Ort der Nationalen Stadtentwicklungspolitik „Provinzstädte - Neu definiert“ lud am 23. und 24. Mai 2017 ein, im lokalen Kontext der Region Cottbus über die räumliche Entwicklung von Städten zwischen Metropole und Dorf zu diskutieren. Die dabei entstandenen Ideen für Praxis, Wissenschaft und Lehre sind in dieser Broschüre dokumentiert. KW - Provinzstädte KW - Stadtplanung KW - Hochschultag KW - Klein- und Mittelstädte KW - Nationale Stadtentwicklungspolitik Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:co1-opus4-44230 UR - https://opus4.kobv.de/opus4-btu/frontdoor/index/index/docId/4423 SN - 978-3-940471-38-3 PB - Brandenburgische Technische Universität CY - Cottbus ; Senftenberg ER - TY - GEN A1 - Fragner, Moritz M. A1 - Schmidt, Heiko T1 - Investigating Asymptotic Suction Boundary Layers using a One-Dimensional Stochastic Turbulence Model T2 - Journal of turbulence N2 - The turbulent asymptotic suction boundary layer is studied using a one-dimensional turbulence (ODT) model. ODT is a fully resolved, unsteady stochastic simulation technique. While flow properties reside on a one-dimensional domain, turbulent advection is represented using mapping events whose occurrences are governed by a random process. Due to its reduced spatial dimensionality, ODT achieves major cost reductions compared to three-dimensional (3D) simulations. A comparison to recent direct numerical simulation (DNS) data at moderate Reynolds number (Re = u∞/v0 = 333, where u∞ and v0 are the free stream and suction velocity, respectively) suggests that theODT model is capable of reproducing several velocity statistics, i.e.mean velocity and turbulent kinetic energy budgets, while peak turbulent stresses are under-estimated by ODT. Variation of the Reynolds number in the range Re ∈ [333, 400, 500, 1000] shows that ODT can reproduce various trends observed as a result of increased suction in turbulent asymptotic suction boundary layers, i.e. the reduction of Reynolds stresses and enhanced skin friction. While up to Re = 500 our results can be directly compared to recent LES data, the simulation at Re = 1000 is currently not feasible through full 3D simulations, hence ODTmay assist the design of future DNS or LES simulations at larger Reynolds numbers. Y1 - 2017 SN - 1468-5248 VL - 18 IS - 10 SP - 899 EP - 928 ER - TY - CHAP A1 - Fragner, Moritz M. A1 - Schmidt, Heiko T1 - Investigating Asymptotic Suction Boundary Layers using a One-Dimensional Stochastic Turbulence Modeling Approach T2 - 10th International Symposium on Turbulence and Shear Flow Phenomena (TSFP10), Chicago, USA, July, 2017 Y1 - 2017 UR - http://www.tsfp-conference.org/proceedings/2017/2/132.pdf ER - TY - CHAP A1 - Fragner, Moritz M. A1 - Schmidt, Heiko T1 - Investigating Asymptotic Suction Boundary Layers using a One-Dimensional Stochastic Turbulence Model T2 - 88th Annual Meeting of the International Association of Applied Mathematics and Mechanics March 6-10, 2017 Weimar, Germany, Book of abstracts Y1 - 2017 UR - https://www.tu-ilmenau.de/fileadmin/media/analysis/trunk/170304_BoA_GAMM_2017.pdf SP - S. 361 PB - GAMM ER - TY - GEN A1 - Fragner, Moritz M. A1 - Schmidt, Heiko T1 - Investigating Asymptotic Suction Boundary Layers using a One-Dimensional Stochastic Turbulence Model T2 - Proceedings in applied mathematics and mechanics : PAMM Y1 - 2017 UR - https://onlinelibrary.wiley.com/doi/pdf/10.1002/pamm.201710288 U6 - https://doi.org/10.1002/pamm.201710288 SN - 1617-7061 VL - 17 IS - 1 SP - 637 EP - 638 ER - TY - GEN A1 - Schmidt, Thomas A1 - Buß, Lars A1 - Ewert, Moritz A1 - Schönhoff, Gunnar A1 - Wehling, Tim Oliver A1 - Falta, Jens T1 - Adsorption of sulfur on Si(111) T2 - Surface Science N2 - The adsorption of S on Si(111)- 7 × 7 has been investigated for different preparation schemes and parameters. S was supplied from an electrochemical Ag2S cell. For room temperature adsorption and subsequent annealing, no ordered S induced reconstruction can be observed with spot profile analysis low-energy electron diffraction (SPALEED). S deposition at temperatures above about 400°C, however, leads to a well-ordered reconstruction. Judging from the LEED pattern, the same reconstruction was already observed by Metzner et al. [Surf. Sci. 377–379(1997) 71–74] who identified it as 4 × 4 reconstruction. The upper temperature limit for the pre-paration of this superstructure depends on S flux, which is needed to compensate for desorption. Prolonged S exposure leads to surface roughening, as observed with SPALEED and scanning tunneling microscopy (STM), pointing to surface etching by S. From our SPALEED data, we can conclude that the observed reconstruction is not a 4 × 4 reconstruction, but a 20/12 superstructure with a rectangular unit cell that exists in three rotational domains, as confirmed by STM. Different structural trial models have been assessed with density functional theory. Among these model structures, a configuration with dimers adsorbed on bridging sites, with a S coverage of 1 monolayer, is most likely, since it is energetically favorable and is in agreement with all experimental results. KW - Passivation KW - Low-energy electron diffraction KW - Scanning tunneling microscopy KW - Density functional theory KW - Auger electron spectroscopy Y1 - 2020 U6 - https://doi.org/10.1016/j.susc.2019.121561 SN - 0039-6028 SN - 1879-2758 VL - 694 ER - TY - GEN A1 - Fahrion, Marc-Steffen A1 - Draeger, Susan A1 - Lakatos, Michael A1 - Schmidt, Timo A1 - Nickl, Christoph A1 - Brombacher, Moritz A1 - Bangalore, Deekshitha A1 - Sundermann, Wolfgang T1 - KLIBAU – Weiterentwicklung und Konkretisierung des Klimaangepassten Bauens : Handlungsempfehlungen für Planer und Architekten Y1 - 2019 UR - https://www.bbsr.bund.de/BBSR/DE/forschung/programme/zb/Auftragsforschung/5EnergieKlimaBauen/2018/klibau/handlungsempfehlungen.pdf?__blob=publicationFile&v=4 ER - TY - RPRT A1 - Schmidt, Peer A1 - Donath, Ines A1 - Wels, Martin A1 - Pinnau, Sebastian A1 - Grau Turuelo, Constantino A1 - Breitkopf, Cornelia A1 - Hack, Klaus A1 - Baben, Moritz to A1 - Reis, Bruno A1 - Müller, Michael A1 - Sergeev, Dmitry A1 - Qi, Jia T1 - PCM Screening - Evaluierung eutektischer Gemische für den Einsatz als PCM: thermodynamische Modellierung und experimentelle Methoden : Energie Speicher: PCM-Screening : Schlussbericht N2 - Ein wichtiges Ziel der Bundesregierung ist der Ausbau des Anteils erneuerbarer Energien an der gesamten Stromerzeugung. Die Entwicklung optimierter Wärme- und Kältespeicher stellt einen wichtigen Baustein bei der Erreichung dieser Zielstellung dar. Elektrisch betriebene Wärmepumpen und Kompressionskältemaschinen sowie dezentrale Klein-BHKW bieten in Verbindung mit entsprechend dimensionierten, thermischen Speichern ein großes Potential zum Lastmanagement in Smart Grids und somit zur Netzintegration von Strom aus erneuerbaren Energien. Die im Projekt entwickelte Methodik zur Suche nach neuen Latentspeichermedien kann für ein breites Anwendungsfeld von Heiz- und Kühlanwendungen in Gebäuden bis hin zur Kraftwerkstechnik eingesetzt werden. Innerhalb der Fördermaßnahme „Anwendungsorientierte Forschung und Entwicklung zur nichtnuklearen Energieforschung“ im 6. Energieforschungsprogramm der Bundesregierung wurde durch die Projektarbeiten das Schwerpunktthema Energiespeicher (3.8) adressiert, wobei der Aspekt der Entwicklung neuer Materialien mit reduzierten Kosten für einen wirtschaftlichen Betrieb im Vordergrund stand. Speziell wurden dabei die Unterpunkte 3.8.4 Thermische Speicher zur Weiterentwicklung, Optimierung und Erprobung von PCM sowie 3.8.5 Übergeordnete Themen mit Modellen und Simulationswerkzeugen für die Auswahl und Bewertung neuer Speichermaterialien adressiert. Die Projektergebnisse besitzen aber auch Berührungspunkte mit den Schwerpunkten 3.12 Energieeffizienz in Industrie, Gewerbe, Handel und Dienstleistungen sowie 3.4 Solarthermische Kraftwerke, da mit der entwickelten Screening-Methode für diese Anwendungsfälle neue Wärmespeichermaterialien auf der Basis wasserfreier Salze mit höheren Prozesstemperaturen gefunden werden können. Durch den Einsatz von Methoden zur Modellierung und Simulation von Prozessen erfolgt gleichermaßen die Umsetzung einer energie- und ressourcenschonenden Forschungstätigkeit. Das im Projekt entwickelte Vorgehen hilft dabei, einen äußerst sparsamen Einsatz von Chemikalien, eine niedrige Belastung der Umwelt durch verringerten Entsorgungsaufwand der verbrauchten Stoffe sowie einen deutlich geringeren Aufwand und Energieeinsatz für die Messtechnik zu ermöglichen. Damit wurde zugleich das Schwerpunktthema 3.8.5 Modelle und Simulationswerkzeuge für die Auswahl und Bewertung neuer Speichermaterialien angesprochen. KW - Latentwärmespeicher KW - Phase diagram KW - Thermodynamic modeling KW - Thermal analysis Y1 - 2021 UR - https://www.tib.eu/de/suchen/id/TIBKAT:177643451X/ U6 - https://doi.org/10.2314/KXP:177643451X PB - TIB – Leibniz-Informationszentrum Technik und Naturwissenschaften CY - Hannover ER - TY - GEN A1 - Pożarowska, Emilia A1 - Pleines, Linus A1 - Ewert, Moritz A1 - Prieto, Mauricio J. A1 - Tănase, Liviu Christian A1 - Souza Caldas, Lucas de A1 - Tiwari, Aarti A1 - Schmidt, Thomas A1 - Falta, Jens A1 - Krasovskii, Eugene A1 - Morales, Carlos A1 - Flege, Jan Ingo T1 - Preparation and stability of the hexagonal phase of samarium oxide on Ru(0001) T2 - Ultramicroscopy N2 - We have used low-energy electron microscopy (LEEM), micro-illumination low-energy electron diffraction (µLEED) supported by ab initio calculations, and X-ray absorption spectroscopy (XAS) to investigate in-situ and in real-time the structural properties of Sm2O3 deposits grown on Ru(0001), a rare-earth metal oxide model catalyst. Our results show that samarium oxide grows in a hexagonal A-Sm2O3 phase on Ru(0001), exhibiting a (0001) oriented-top facet and (113) side facets. Upon annealing, a structural transition from the hexagonal to cubic phase occurs, in which the Sm cations exhibit the +3 oxidation state. The unexpected initial growth in the A-Sm2O3 hexagonal phase and its gradual transition to a mixture with cubic C-Sm2O3 showcases the complexity of the system and the critical role of the substrate in the stabilization of the hexagonal phase, which was previously reported only at high pressures and temperatures for bulk samaria. Besides, these results highlight the potential interactions that Sm could have with other catalytic compounds with respect to the here gathered insights on the preparation conditions and the specific compounds with which it interacts. KW - Samarium oxide (Sm2O3) KW - low-energy electron microscopy (LEEM) KW - X-ray photoemission electron microscopy (XPEEM) KW - Facets KW - Epitaxy KW - Hexagonal phase Y1 - 2023 U6 - https://doi.org/10.1016/j.ultramic.2023.113755 SN - 0304-3991 SN - 1879-2723 VL - 250 ER - TY - GEN A1 - Schmidt, Moritz A1 - Skerencak-Frech, Andrej A1 - Panak, Petra J. A1 - Huittinen, Nina T1 - Curium(III) luminescence spectroscopy as a tool for species determination T2 - Chemical Society reviews N2 - Curium is an artificial transuranic element with atomic number 96. It is typically found in its +III oxidation state, which is stabilized by a 5f7 electron configuration. CmIII exhibits intense lumi-nescence from its first excited 6D’7/2 to its 8S’7/2 ground state in the red part of the visual spec-trum. Due to the nature of the 5f electron shell, this luminescence is sensitive to changes in the chemical environment of the CmIII probe, while being detectable in the trace concentration range. This unique combination has established CmIII luminescence spectroscopy as an ideal tool for speciation studies in complex systems, particularly those relevant to the nuclear fuel cycle. In this review, we present an overview of the developments and applications of CmIII lumines-cence spectroscopy in the last 20 years since the last comprehensive review was published. The discussed studies have been categorized according to their chemical environment into reactions at the water/mineral interface, studies of solids containing CmIII, aqueous complexation studies, spectroscopy in non-aqueous systems, and interaction of CmIII with biomolecules and biota. These systems correlate in large parts with areas of application in nuclear waste disposal sci-ence, separation processes within current and proposed nuclear fuel cycles, and radioecological research. We summarize the most important findings in the studies, identify emerging trends and persistent challenges in the field of CmIII luminescence spectroscopy. Finally, we offer an outlook on potential future developments and research directions in this area. Y1 - 2025 U6 - https://doi.org/10.1039/d5cs00764j PB - Royal Society of Chemistry CY - London ER - TY - GEN A1 - Balas, Johannes A1 - Urbank, Christian A1 - Kaden, Peter A1 - Patzschke, Michael A1 - März, Juliane A1 - Kvashnina, Kristina O. A1 - Schmidt, Moritz A1 - Stumpf, Thorsten A1 - Gericke, Robert T1 - Bonding trends in pyridine-2-thiolato complexes of tetravalent actinides T2 - Inorganic chemistry N2 - Complexes of tetravalent actinides (An: Th, U, Np, Pu) with the bidentate (N,S)-donor ligand pyridine-2-thiolate (2-PyS, PyS−) were synthesized in 1:4 or 1:5 ratios. This includes the first structurally characterized Np complex with (N,S)-donor ligands, filling a notable gap in An coordination chemistry. An improved synthetic approach with PyS–SiMe3 enabled efficient formation of the 1:4 complexes in THF as coordinating solvent. The compounds were comprehensively characterized in solution and in solid phase, supported by quantum chemical calculations. Experimental and theoretical results show matching trends in the binding behavior of AnIV. The covalent bond contributions in An–N and An–S bonding increase along the series of An from Th to Pu. The bonds to the soft sulfur donors consistently have the highest covalent contributions with a remarkably high percentage for Pu–S (IQA analysis: >34%) over the harder N donors or An–O bonds of coordinating THF. High-resolution X-ray absorption and infrared spectroscopy indicate similar electronic and structural properties across AnIV complexes, while SQUID magnetometry uncovered significant differences in magnetic behavior at low temperatures depending on the complex compositions. This work advances the understanding of An-ligand bonding, emphasizing covalency and electronic structures, and expands fundamental insights into An chemistry. KW - Actinides KW - Single-crystal X-ray diffraction KW - Bonding trends KW - HERFD-XANES KW - SQUID Y1 - 2025 U6 - https://doi.org/10.1021/acs.inorgchem.5c03369 SN - 1520-510X VL - 64 IS - 44 SP - 21919 EP - 21931 PB - American Chemical Society CY - Washington, DC ER -