TY - GEN A1 - Böttger, Philipp A1 - Meyer, Marcel A1 - Martin, Jörg A1 - Otto, Thomas Walter A1 - Geßner, Thomas A1 - Seidlitz, Holger A1 - Kroll, Lothar ED - Geßner, Thomas T1 - Integrateable light sources based on semiconductor nanocrystal T2 - Smart Systems Integration 2014, Aachen, 2014 Y1 - 2014 SN - 978-3-86359-201-1 SP - 451 EP - 454 PB - Apprimus Verlag CY - Aachen ER - TY - GEN A1 - Kiebist, Jan A1 - Schmidtke, Kai-Uwe A1 - Zimmermann, Jörg A1 - Kellner, Harald A1 - Jehmlich, Nico A1 - Ullrich, René A1 - Zänder, Daniel A1 - Hofrichter, Martin A1 - Scheibner, Katrin T1 - A peroxygenase from Chaetomium globosum catalyzes the selective oxygenation of testosterone T2 - ChemBioChem N2 - Unspecific peroxygenases (UPO, EC 1.11.2.1) secreted by fungi open an efficient way to selectively oxyfunctionalize diverse organic substrates including less activated hydrocarbons by transferring peroxide-borne oxygen. Herein, we investigated a cell-free approach to incorporate epoxy and hydroxyl functionalities directly into the bulky molecule of testosterone by a novel unspecific peroxygenase that was produced by the ascomycetous fungus Chaetomium globosum in a complex medium rich in carbon and nitrogen. Purification by fast protein liquid chromatography revealed two enzyme fractions with the same molecular mass of 36 kDa and specific activities of 4.4 to 12 U mg-1. Whereas well-known UPOs of Agrocybe aegerita (AaeUPO) and Marasmius rotula (MroUPO) failed to convert testosterone in a comparative study, the UPO of C. globosum (CglUPO) accepted testosterone as substrate and converted it with up to 7,000 total turnovers (TTN) into two oxygenated products: the 4,5-epoxide of testosterone in β-configuration and 16α-hydroxytestosterone. The reaction was performed at 100-mg scale resulting in the formation of about 90 % of the epoxide and 10 % of the hydroxylation product, which both could be isolated with purities above 96 %. Thus, CglUPO may be a promising biocatalyst for the oxyfunctionalization of bulky steroids and provide a useful tool for the synthesis of pharmaceutically relevant steroidal molecules. KW - peroxidase KW - hydroxylation Y1 - 2017 UR - http://onlinelibrary.wiley.com/doi/10.1002/cbic.201600677/abstract U6 - https://doi.org/10.1002/cbic.201600677 SN - 1439-7633 VL - 18 IS - 6 SP - 563 EP - 569 ER - TY - CHAP A1 - Schwartz, Bernhard A1 - Oehme, Michael A1 - Körner, Roman A1 - Bechler, Stefan A1 - Schulze, Jörg A1 - Kittler, Martin T1 - Luminescence of strained Ge on GeSn virtual substrate grown on Si (001) T2 - Silicon Photonics XII, 30 January-1 February 2017, San Francisco, California, United States Y1 - 2017 SN - 978-1-5106-0657-9 U6 - https://doi.org/10.1117/12.2249564 PB - SPIE CY - Bellingham, Washington ER - TY - GEN A1 - Boch, Steffen A1 - Allan, Eric A1 - Birkhofer, Klaus A1 - Bossdorf, Oliver A1 - Blüthgen, Nico A1 - Christ-Breulmann, Sabina A1 - Diekötter, Tim A1 - Dormann, Carsten F. A1 - Gossner, Martin M. A1 - Hallmann, Christine A1 - Hemp, Andreas A1 - Hölzel, Norbert A1 - Jung, Kirsten A1 - Klaus, Valentin H. A1 - Klein, Alexandra M. A1 - Kleinebecker, Till A1 - Lange, Markus A1 - Müller, Jörg A1 - Nacke, Heiko A1 - Prati, Daniel A1 - Renner, Swen C. A1 - Rothenwöhrer, Christoph A1 - Schall, Peter A1 - Schulze, Ernst-Detlef A1 - Socher, Stephanie A. A1 - Tscharntke, Teja A1 - Türke, Manfred A1 - Weiner, Christiane N. A1 - Weisser, Wolfgang W. A1 - Westphal, Catrin A1 - Wolters, Volkmar A1 - Wubet, Tesfaye A1 - Fischer, Markus T1 - Extensive und jährlich wechselnde Nutzungsintensität fördert den Artenreichtum im Grünland T2 - ANLIEGEN NATUR Y1 - 2016 UR - https://www.biom.uni-freiburg.de/mitarbeiter/dormann/boch2016anliegennatur.pdf SN - 1864-0729 VL - 38 IS - 1 SP - 86 EP - 95 ER - TY - GEN A1 - Schlipf, Jon A1 - Martin, Elena A1 - Stchakovsky, Michel A1 - Benedetti, Alessandro A1 - Fischer, Inga Anita A1 - Schulze, Jörg A1 - Chiussi, Stefano T1 - Ellipsometric analysis of concentration gradients induced in semiconductor crystals by pulsed laser induced epitaxy T2 - Journal of Vacuum Science & Technology B Y1 - 2019 U6 - https://doi.org/10.1116/1.5122777 SN - 2166-2754 VL - 37 IS - 6 ER - TY - GEN A1 - Augel, Lion A1 - Fischer, Inga Anita A1 - Gollhofer, Martin A1 - Oehme, Michael A1 - Schulze, Jörg T1 - Comparing Fourier transform infrared spectroscopy results with photocurrent measurements for Ge-on-Si PIN photodetectors with and without Al nanoantennas T2 - Journal of Applied Physics Y1 - 2020 U6 - https://doi.org/10.1063/5.0012279 SN - 1089-7550 VL - 128 IS - 1 SP - 013105-1 EP - 013105-8 ER - TY - RPRT A1 - Mensing, Klaus A1 - Anders, Ulrike A1 - Fanelli-Falcke, Jörg A1 - Hauschild, Arndt A1 - Löwer, Markus A1 - Mansfeld, Ulrike A1 - Nußbaum, Jens A1 - Ribbeck-Lampel, Juliane A1 - Rohr, Götz von A1 - Schulze, Juana A1 - Sondermann, Martin A1 - Wiellowics, Kathrin T1 - Zukunft der (Stadt-)Zentren ohne Handel? Neue Impulse und Nutzungen für Zentren mit Zukunft N2 - Wenn die Leitfunktion des Handels in den Zentren von Klein- und Mittelstädten sowie Stadtteilzentren größerer Städte abnimmt, steht die räumliche Planung in Bezug auf die (Weiter-)Entwicklung urbaner Zentren vor neuen Herausforderungen. Ausgehend von aktuellen Trends der Zentrenentwicklung werden Konsequenzen für alte und neue Nutzungen aufgezeigt und Handlungsempfehlungen entwickelt: Es bedarf Transformationsstrategien, die im Kern eine neue multifunktionale Nutzungsmischung durch Ansiedlung ergänzender, frequenzbringender Nutzungen neben dem Handel beinhalten, um lebendige und attraktive (Stadt-)Zentren zu erhalten. Die öffentlichen Räume als „gute Stube“ sind um nicht kommerzielle Aufenthaltsqualitäten aufzuwerten, um die Identifikation der Einwohnerinnen und Einwohner mit „ihrem“ Zentrum zu fördern. Die Zentrenentwicklung wird als eine Gemeinschaftsaufgabe gesehen, an der unter Federführung von Stadtpolitik und -verwaltung die verschiedenen Akteursgruppen aktiv mitwirken. Zudem werden Instrumente der Zentrentransformation vorgestellt, mit denen schnell, flexibel und situationsangepasst zukünftige Entwicklungen gestaltet werden können. KW - Innenstadt KW - Stadtteilzentren KW - Handel KW - Zentrenentwicklung KW - Zentrentransformation KW - Nutzungen KW - Instrumente Y1 - 2020 UR - https://www.econstor.eu/bitstream/10419/221915/1/1702653838.pdf ER - TY - GEN A1 - Carrillo-Rojas, Galo A1 - Schulz, Hans Martin A1 - Orellana-Alvear, Johanna A1 - Ochoa‐Sánchez, Ana A1 - Trachte, Katja A1 - Célleri, Rolando A1 - Bendix, Jörg T1 - Atmosphere-surface fluxes modeling for the high Andes: The case of páramo catchments of Ecuador T2 - Science of the Total Environment N2 - Interest in atmosphere-surface flux modeling over the mountainous regions of the globe has increased recently, with a major focus on the prediction of water, carbon and other functional indicators in natural and disturbed conditions. However, less research has been centered on exploring energy fluxes (net radiation; sensible, latent and soil heat) and actual evapotranspiration (ETa) over the Neotropical Andean biome of the páramo. The present study assesses the implementation and parameterization of a state-of-art Land-Surface Model (LSM) for simulation of these fluxes over two representative páramo catchments of southern Ecuador. We evaluated the outputs of the LSM Community Land Model (CLM ver. 4.0) with (i) ground-level flux observations from the first (and highest) Eddy Covariance (EC) tower of the Northern Andean páramos; (ii) spatial ETa estimates from the energy balance-based model METRIC (based on Landsat imagery); and (iii) derived ETa from the closure of the water balance (WB). CLM’s energy predictions revealed a significant underestimation on net radiation, which impacts the sensible and soil heat fluxes (underestimation), and delivers a slight overestimation on latent heat flux. Modeled CLM ETa showed acceptable goodness-of-fit (Pearson R = 0.82) comparable to ETa from METRIC (R = 0.83). Contrarily, a poor performance of ETa WB was observed (R = 0.46). These findings provide solid evidence on the CLM’s accuracy for the ETa modeling, and give insights in the selection of other ETa methods. The study contributes to a better understanding of ecosystem functioning in terms of water loss through evaporative processes, and might help in the development of future LSMs’ implementations focused on climate / land use change scenarios for the páramo. KW - Tropical Andes KW - Páramo KW - CLM KW - METRIC KW - Evapotranspiration KW - Eddy covariance Y1 - 2020 U6 - https://doi.org/10.1016/j.scitotenv.2019.135372 SN - 0048-9697 IS - 704 ER - TY - GEN A1 - Juhlke, Tobias R. A1 - Geldern, Robert van A1 - Barth, Johannes A. C. A1 - Bendix, Jörg A1 - Bräuning, Achim A1 - Garel, Emilie A1 - Häusser, Martin A1 - Huneau, Frédéric A1 - Knerr, Isabel A1 - Santoni, Sébastien A1 - Szymczak, Sonja A1 - Trachte, Katja T1 - Temporal offset between precipitation and water uptake of Mediterranean pine trees varies with elevation and season T2 - Science of the Total Environment N2 - For climate models that use paleo-environment data to predict future climate change, tree-ring isotope variations are one important archive for the reconstruction of paleo-hydrological conditions. Due to the rather complicated pathway of water, starting from precipitation until its uptake by trees and the final incorporation of its components into tree-ring cellulose, a closer inspection of seasonal variations of tree water uptake is important. In this study, branch and needle samples of two pine species (Pinus pinaster and Pinus nigra subsp. laricio) and several water compartments (precipitation, creek, soil) were sampled over a two-year period and analyzed for the temporal variations of their oxygen and hydrogen stable isotope ratios (δ18O and δ2H) at five sites over an elevation gradient from sea level to around 1600 m a.s.l. on the Mediterranean island of Corsica (France). A new model was established to disentangle temporal relationships of source water uptake of trees. It uses a calculation method that incorporates the two processes mostly expected to affect source water composition: mixing of waters and evaporation. The model results showed that the temporal offset from precipitation to water uptake is not constant and varies with elevation and season. Overall, seasonal source water origin was shown to be dominated by precipitation from autumn and spring. While autumn precipitation was a more important water source for trees growing at mid- (~800–1000 m a.s.l) and high-elevation (~1600 m a.s.l.) sites, trees at coastal sites mostly took up water from late winter and spring. These findings show that predicted decreases in precipitation amounts during the wet season in the Mediterranean can have strong impacts on water availability for pine trees, especially at higher elevations. KW - Oxygen isotopes KW - Hydrogen isotopes KW - Mediterranean KW - Soil water KW - Water uptake KW - Pine trees Y1 - 2021 U6 - https://doi.org/10.1016/j.scitotenv.2020.142539 VL - 755 IS - 2 ER - TY - GEN A1 - Szymczak, Sonja A1 - Barth, Johannes A. C. A1 - Bendix, Jörg A1 - Huneau, Frédéric A1 - Garel, Emilie A1 - Häusser, Martin A1 - Juhlke, Tobias R. A1 - Knerr, Isabel A1 - Santoni, Sébastien A1 - Mayr, Christoph C. A1 - Trachte, Katja A1 - Geldern, Robert van A1 - Bräuning, Achim T1 - First indications of seasonal and spatial variations of water sources in pine trees along an elevation gradient in a Mediterranean ecosystem derived from δ18O T2 - Chemical Geology N2 - Water availability is the most important factor for the vitality of forest ecosystems, especially in dry environments. The Mediterranean region is one of the hotspots of future climate change; therefore, data on the water cycle are urgently needed. We measured oxygen isotope compositions in creek water, precipitation, stem water, needle water, and tree-ring cellulose over one growing season to establish the relationship between isotope compositions in different compartments along a fractionation pathway. We analyzed plant material from pine trees (Pinus nigra J.F. Arn subsp. laricio (Poiret) Maire var. Corsicana Hyl. and Pinus pinaster Aiton) at five locations along an elevation gradient from sea level to 1600 m asl. We traced back the oxygen isotope composition from source to sink in tree-ring cellulose in order to identify the water sources used by the trees, and to quantify the extent of isotope fractionation processes. Our results showed that the trees used different water sources over the course of the growing season, ranging from winter snow meltwater to summer precipitation at higher sites and deep soil water reservoirs at coastal sites. Needle water enrichment was higher at higher elevation sites than at coastal locations, highlighting the importance of site-specific climate conditions on the isotopic composition values in tree material. Water availability seems to be most restricted at the highest site, making these trees most vulnerable to climate change. KW - Oxygen isotopes KW - Pinus nigra KW - Pinus pinaster KW - Needle water enrichment KW - Xylem water KW - Water source Y1 - 2020 U6 - https://doi.org/10.1016/j.chemgeo.2020.119695 VL - 2020 IS - 549 ER - TY - GEN A1 - Szymczak, Sonja A1 - Häusser, Martin A1 - Garel, Emilie A1 - Santoni, Sébastien A1 - Huneau, Frédéric A1 - Knerr, Isabel A1 - Trachte, Katja A1 - Bendix, Jörg T1 - How Do Mediterranean Pine Trees Respond to Drought and Precipitation Events along an Elevation Gradient T2 - Forests N2 - Drought is a major factor limiting tree growth and plant vitality. In the Mediterranean region,the length and intensity of drought stress strongly varies with altitude and site conditions. We usedelectronic dendrometers to analyze the response of two native pine species to drought and precipitationevents. The five study sites were located along an elevation gradient on the Mediterranean islandof Corsica (France). Positive stem increment in the raw dendrometer measurements was separatedinto radial stem growth and stem swelling/shrinkage in order to determine which part of the trees’response to climate signals can be attributed to growth. Precipitation events of at least 5 mm anddry periods of at least seven consecutive days without precipitation were determined over a periodof two years. Seasonal dynamics of stem circumference changes were highly variable among thefive study sites. At higher elevations, seasonal tree growth showed patterns characteristic for coldenvironments, while low-elevation sites showed bimodal growth patterns characteristic of droughtprone areas. The response to precipitation events was uniform and occurred within the first six hoursafter the beginning of a precipitation event. The majority of stem circumference increases were causedby radial growth, not by stem swelling due to water uptake. Growth-induced stem circumferenceincrease occurred at three of the five sites even during dry periods, which could be attributed tostored water reserves within the trees or the soils. Trees at sites with soils of low water-holdingcapacity were most vulnerable to dry periods. KW - dendrometer; stem circumference changes; climate response; Mediterranean;Pinus nigra;Pinus pinaster Y1 - 2020 U6 - https://doi.org/10.3390/f11070758 VL - 7 IS - 11 ER -