TY - GEN A1 - Das, Chittaranjan A1 - Kot, Małgorzata A1 - Hellmann, Tim A1 - Wittich, Carolin A1 - Mankel, Eric A1 - Zimmermann, Iwan A1 - Schmeißer, Dieter A1 - Nazeeruddin, Mohammad Khaja A1 - Jaegermann, Wolfram T1 - Atomic Layer-Deposited Aluminum Oxide Hinders Iodide Migration and Stabilizes Perovskite Solar Cells T2 - Cell Reports Physical Science N2 - Iodide migration causes degradation of the perovskite solar cells. Here,we observe the direct migration of iodide into the hole-transport layer in a device. We demonstrate that ultrathin room temperature atomic layer-deposited Al2O3 on the perovskite surface very effectively hinders the migration. The perovskite-Al2O3 interface enables charge transfer across the Al2O3 layer in the solar cells, without causing any drastic changes in the properties of the perovskite absorber. Furthermore, it helps to preserve the initial properties of the perovskite film during exposure to light and air under real operating conditions, and thus, improves the stability of the solar cells. The ultrathin Al2O3 layer deposited at room temperature significantly increases the lifetime of the perovskite solar cells, and we hope this may be a step toward the mass production of stable devices. KW - perovskite solar cells KW - iodine migration KW - stability KW - X-ray photoelectron spectroscopy (XPS) KW - atomic layer deposition (ALD) KW - aluminum oxide (Al2O3) Y1 - 2020 U6 - https://doi.org/10.1016/j.xcrp.2020.100112 SN - 2666-3864 VL - 1 IS - 7 ER - TY - CHAP A1 - Jaegermann, Wolfram A1 - Schmeißer, Dieter T1 - Elementary Processes at Solid/Electrolyte Interfaces Y1 - 2001 ER - TY - GEN A1 - Beerbom, Martin A1 - Mayer, Thomas A1 - Jaegermann, Wolfram A1 - Batchelor, David R. A1 - Schmeißer, Dieter T1 - Electrochemically Induced Redox-Reactions on GaAs-Surfaces: High Resolution Photoemission Spectra Taken at the U49/2 Beamline Y1 - 2001 ER - TY - JOUR A1 - Kraft, D. A1 - Thißen, A. A1 - Mayer, Thomas A1 - Klein, A. A1 - Jaegermann, Wolfram A1 - Hoffmann, Patrick A1 - Batchelor, David R. A1 - Schmeißer, Dieter T1 - Backcontact Formation on CdTe Thin Film Solar Cells Y1 - 2001 ER - TY - JOUR A1 - Heller, Thomas A1 - Böhme, O. A1 - Tonti, D. A1 - Klein, A. A1 - Jaegermann, Wolfram A1 - Schmeißer, Dieter T1 - Na interaction with relaxed WO3 thin films Y1 - 1998 ER - TY - GEN A1 - Beerbom, Martin A1 - Mayer, Thomas A1 - Jaegermann, Wolfram A1 - Batchelor, David R. A1 - Schmeißer, Dieter T1 - Synchrotron-induced photoemission of GaAs electrodes after electrochemical treatment in aqueous electrolytes N2 - Electrochemically-induced oxidation and reduction reactions of UHV-cleaved GaAs(110) surfaces have been studied after emersion under potential control using highresolution synchrotron-induced photoelectron spectroscopy. High quality spectra of the As and Ga core 3d lines and the valence band region have been obtained. Thespectra of the anodic oxide show strong emission of bulk-like Ga2O3 and some As2O3 with the admixture of suboxides and hydroxides. Ga2O3 and As2O3 arecathodically reduced leaving the GaAs surface covered mostly with elemental As, some As-H and remnants of Ga-suboxides and -hydroxides. KW - GAAS(110) KW - GaAs KW - Electrochemistry KW - Aqueous electrolytes KW - Surface engineering Y1 - 2002 ER - TY - JOUR A1 - Hoffmann, Patrick A1 - Schmeißer, Dieter A1 - Klein, A. A1 - Jaegermann, Wolfram A1 - Pettenkofer, Christian A1 - Follath, Rolf T1 - Spectro-Microscopy with PEEM / µESCA Y1 - 2000 ER - TY - JOUR A1 - Jäckel, B. A1 - Thißen, A. A1 - Hunger, Ralf A1 - Klein, A. A1 - Jaegermann, Wolfram A1 - Hoffmann, Patrick A1 - Schmeißer, Dieter T1 - Focus IS-PEEM investigations at U49/II: experimental determination of a magnification function, the contrast mechanism and the spectral resolution Y1 - 2002 ER - TY - GEN A1 - Schmeißer, Dieter A1 - Schmidt, Stephan A1 - Seibold, Götz A1 - Cherkashinin, Gennady A1 - Jaegermann, Wolfram T1 - Localized Gap States in LiCoO2 and their Influence on the Transport Properties in Li-Ion Batteries T2 - ECS Transactions Y1 - 2010 SN - 1938-5862 VL - 25 IS - 35 SP - 37 EP - 45 ER -