TY - GEN A1 - Schmidt, Peer A1 - Hohmann, Andrea A1 - Nilges, Tom A1 - Köpf, Marianne A1 - Weihrich, Richard T1 - Synthesis of Element Allotropes of Arsenic and Phosphorus by Application of Electromotive Series of Solids T2 - Zeitschrift für Anorganische und Allgemeine Chemie N2 - Calculation of electromotive series of solids allows easy prediction of reaction pathways[1]. Using the electromotive series of systems As-P-O and As-P-X (X = F, Cl, Br, I) the formation of element allotropes via the oxide and halide compounds in thermite type reactions can be deduced: phosphorous will reduce the arsenic oxides to elemental arsenic, forming grey or black allotrope, depending on reaction mixture composition. KW - Element allotropes KW - Arsenic KW - Phosphorus Y1 - 2014 UR - http://onlinelibrary.wiley.com/doi/10.1002/zaac.201490026/full U6 - https://doi.org/10.1002/zaac.201490026 SN - 1521-3749 VL - 640 IS - 11 SP - 2386 ER -