TY - GEN A1 - González-Castaño, Miriam A1 - Baena-Moreno, Francisco Manuel A1 - Navarro de Miguel, Juan Carlos A1 - Miah, Kamal Uddin Mohammad A1 - Arroyo-Torralvo, Fátima A1 - Ossenbrink, Ralf A1 - Odriozola, José Antonio A1 - Benzinger, Walther A1 - Hensel, Andreas A1 - Wenka, Achim A1 - Arellano-García, Harvey T1 - 3D-printed structured catalysts for CO2 methanation reaction: Advancing of gyroid-based geometries T2 - Energy Conversion and Management N2 - This work investigates the CO2 methanation rate of structured catalysts by tuning the geometry of 3D-printed metal Fluid Guiding Elements (FGEs) structures based on periodically variable pseudo-gyroid geometries. The enhanced performance showed by the structured catalytic systems is mostly associated with the capability of the FGEs substrate geometries for efficient heat usages. Thus, variations on the channels diameter resulted in ca. 25% greater CO2 conversions values at intermediate temperature ranges. The highest void fraction evidenced in the best performing catalyst (3D-1) favored the radial heat transfer and resulted in significantly enhanced catalytic activity, achieving close to equilibrium (75%) conversions at 400 ◦C and 120 mL/min. For the 3D-1 catalyst, a mathematical model based on an experimental design was developed thus enabling the estimation of its behavior as a function of temperature, spatial velocity, hydrogen to carbon dioxide (H2/CO2) ratio, and inlet CO2 concentration. Its optimal operating conditions were established under 3 different scenarios: 1) no restrictions, 2) minimum H2:CO2 ratios, and 3) minimum temperatures and H2/CO2 ratio. For instance, for the lattest scenario, the best CO2 methanation conditions require operating at 431 ◦C, 200 mL/min, H2/CO2 = 3 M ratio, and inlet CO2 concentration = 10 %. KW - 3D-printing KW - Triply periodic minimal surfaces KW - Fluid guiding elements KW - CO2 methanation KW - Structured catalysts KW - Experiment design Y1 - 2022 U6 - https://doi.org/10.1016/j.enconman.2022.115464 SN - 2590-1745 VL - 258 ER -