TY - GEN A1 - Romero-Zaliz, Rocio A1 - Cantudo, Antonio A1 - Pérez, Eduardo A1 - Jimenez-Molinos, Francisco A1 - Wenger, Christian A1 - Roldan, Juan Bautista T1 - An Analysis on the Architecture and the Size of Quantized Hardware Neural Networks Based on Memristors T2 - Electronics (MDPI) N2 - We have performed different simulation experiments in relation to hardware neural networks (NN) to analyze the role of the number of synapses for different NN architectures in the network accuracy, considering different datasets. A technology that stands upon 4-kbit 1T1R ReRAM arrays, where resistive switching devices based on HfO2 dielectrics are employed, is taken as a reference. In our study, fully dense (FdNN) and convolutional neural networks (CNN) were considered, where the NN size in terms of the number of synapses and of hidden layer neurons were varied. CNNs work better when the number of synapses to be used is limited. If quantized synaptic weights are included, we observed thatNNaccuracy decreases significantly as the number of synapses is reduced; in this respect, a trade-off between the number of synapses and the NN accuracy has to be achieved. Consequently, the CNN architecture must be carefully designed; in particular, it was noticed that different datasets need specific architectures according to their complexity to achieve good results. It was shown that due to the number of variables that can be changed in the optimization of a NN hardware implementation, a specific solution has to be worked in each case in terms of synaptic weight levels, NN architecture, etc. KW - RRAM KW - memristive device KW - neural network Y1 - 2021 U6 - https://doi.org/10.3390/electronics10243141 SN - 2079-9292 VL - 10 IS - 24 ER - TY - GEN A1 - Stanke, Sandra A1 - Wenger, Christian A1 - Bier, Frank F. A1 - Hölzel, Ralph T1 - AC electrokinetic immobilization of influenza virus T2 - Electrophoresis N2 - The use of alternating current (AC) electrokinetic forces, like dielectrophoresis and AC electroosmosis, as a simple and fast method to immobilize sub-micrometer objects onto nanoelectrode arrays is presented. Due to its medical relevance, the influenza virus is chosen as a model organism. One of the outstanding features is that the immobilization of viral material to the electrodes can be achieved permanently, allowing subsequent handling independently from the electrical setup. Thus, by using merely electric fields, we demonstrate that the need of prior chemical surface modification could become obsolete. The accumulation of viral material over time is observed by fluorescence microscopy. The influences of side effects like electrothermal fluid flow, causing a fluid motion above the electrodes and causing an intensity gradient within the electrode array, are discussed. Due to the improved resolution by combining fluorescence microscopy with deconvolution, it is shown that the viral material is mainly drawn to the electrode edge and to a lesser extent to the electrode surface. Finally, areas of application for this functionalization technique are presented. KW - dielectrophoresis KW - immobilization KW - virus Y1 - 2022 U6 - https://doi.org/10.1002/elps.202100324 SN - 1522-2683 VL - 43 IS - 12 SP - 1309 EP - 1321 ER - TY - GEN A1 - Bischoff, Carl A1 - Leise, Jakob A1 - Perez-Bosch Quesada, Emilio A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Kloes, Alexander T1 - Implementation of device-to-device and cycle-to-cycle variability of memristive devices in circuit simulations T2 - Solid-State Electronics N2 - We present a statistical procedure for the extraction of parameters of a compact model for memristive devices. Thereby, in a circuit simulation the typical fluctuations of the current–voltage (I-V) characteristics from device-to-device (D2D) and from cycle-to-cycle (C2C) can be emulated. The approach is based on the Stanford model whose parameters play a key role to integrating D2D and C2C dispersion. The influence of such variabilities over the model’s parameters is investigated by using a fitting algorithm fed with experimental data. After this, the statistical distributions of the parameters are used in a Monte Carlo simulation to reproduce the I-V D2D and C2C dispersions which show a good agreement to the measured curves. The results allow the simulation of the on/off current variation for the design of RRAM cells or memristor-based artificial neural networks. KW - RRAM KW - circuit simulation KW - HfO2 Y1 - 2022 U6 - https://doi.org/10.1016/j.sse.2022.108321 SN - 0038-1101 VL - 194 ER - TY - GEN A1 - Mannocci, Piergiulio A1 - Baroni, Andrea A1 - Melacarne, Enrico A1 - Zambelli, Cristian A1 - Olivo, Piero A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Ielmini, Daniele T1 - In-Memory Principal Component Analysis by Crosspoint Array of Rresistive Switching Memory T2 - IEEE Nanotechnology Magazine N2 - In Memory Computing (IMC) is one of the most promising candidates for data-intensive computing accelerators of machine learning (ML). A key ML algorithm for dimensionality reduction and classification is principal component analysis (PCA), which heavily relies on matrixvector multiplications (MVM) for which classic von Neumann architectures are not optimized. Here, we provide the experimental demonstration of a new IMCbased PCA algorithm based on power iteration and deflation executed in a 4-kbit array of resistive switching random-access memory (RRAM). The classification accuracy of the Wisconsin Breast Cancer data set reaches 95.43%, close to floatingpoint implementation. Our simulations indicate a 250× improvement in energy efficiency compared to commercial GPUs, thus supporting IMC for energy-efficient ML in modern data-intensive computing. KW - RRAM KW - Multilevel switching KW - neural network Y1 - 2022 U6 - https://doi.org/10.1109/MNANO.2022.3141515 SN - 1932-4510 VL - 16 IS - 2 SP - 4 EP - 13 ER - TY - GEN A1 - Strobel, Carsten A1 - Alvarado Chavarin, Carlos A1 - Leszczynski, Sebastian A1 - Richter, Karola A1 - Knaut, Martin A1 - Reif, Johanna A1 - Völkel, Sandra A1 - Albert, Matthias A1 - Wenger, Christian A1 - Bartha, Johann Wolfgang A1 - Mikolajick, Thomas T1 - Improved Graphene-base Heterojunction Transistor with Different Collector Semi-conductors for High-frequency Applications T2 - Advanced Materials Letters N2 - A new kind of transistor device with a graphene monolayer embedded between two n-type silicon layers is fabricated and characterized. The device is called graphene-base heterojunction transistor (GBHT). The base-voltage controls the current of the device flowing from the emitter via graphene to the collector. The transit time for electrons passing by the ultrathin graphene layer is extremely short which makes the device very promising for high frequency RF-electronics. The output current of the device is saturated and clearly modulated by the base voltage. Further, the silicon collector of the GBHT is replaced by germanium to improve the device performance. This enabled the collector current to be increased by almost three orders of magnitude. Also, the common-emitter current gain (Ic/Ib) increased from 10-3 to approximately 0.3 for the newly designed device. However, the ON-OFF ratio of the improved germanium based GBHT has so far been rather low. Further optimizations are necessary in order to fully exploit the potential of the graphene-base heterojunction transistor. KW - Graphene KW - transistor Y1 - 2022 U6 - https://doi.org/10.5185/amlett.2022.011688 SN - 0976-3961 VL - 13 IS - 1 ER - TY - GEN A1 - Fritscher, Markus A1 - Knödtel, Johannes A1 - Mallah, Maen A1 - Pechmann, Stefan A1 - Perez-Bosch Quesada, Emilio A1 - Rizzi, Tommaso A1 - Wenger, Christian A1 - Reichenbach, Marc T1 - Mitigating the Effects of RRAM Process Variation on the Accuracy of Artifical Neural Networks T2 - Embedded Computer Systems: Architectures, Modeling, and Simulation. SAMOS 2021. Lecture Notes in Computer Science N2 - Weight storage is a key challenge in the efficient implementation of artificial neural networks. Novel memory technologies such as RRAM are able to greatly improve density and introduce non-volatility and multibit capabilities to this component of ANN accelerators. The usage of RRAM in this domain comes with downsides, mainly caused by cycle-to-cycle and device-to-device variability leading to erroneous readouts, greatly affecting digital systems. ANNs have the ability to compensate for this by their inherent redundancy and usually exhibit a gradual deterioration in the accuracy of the task at hand. This means, that slight error rates can be acceptable for weight storage in an ANN accelerator. In this work we link device-to-device variability to the accuracy of an ANN for such an accelerator. From this study, we can estimate how strongly a certain net is affected by a certain device parameter variability. This methodology is then used to present three mitigation strategies and to evaluate how they affect the reaction of the network to variability: a) Dropout Layers b) Fault-Aware Training c) Redundancy. These mitigations are then evaluated by their ability to improve accuracy and to lower hardware overhead by providing data for a real-word example. We improved this network’s resilience in such a way that it could tolerate double the variation in one of the device parameters (standard deviation of the oxide thickness can be 0.4 nm instead of 0.2 nm while maintaining sufficient accuracy.) KW - RRAM KW - memristive device KW - neural network Y1 - 2022 SN - 978-3-031-04579-0 SN - 978-3-031-04580-6 U6 - https://doi.org/10.1007/978-3-031-04580-6_27 SN - 0302-9743 SN - 1611-3349 SP - 401 EP - 417 PB - Springer ER - TY - GEN A1 - Mahadevaiah, Mamathamba Kalishettyhalli A1 - Pérez, Eduardo A1 - Lisker, Marco A1 - Schubert, Markus Andreas A1 - Perez-Bosch Quesada, Emilio A1 - Wenger, Christian A1 - Mai, Andreas T1 - Modulating the Filamentary-Based Resistive Switching Properties of HfO2 Memristive Devices by Adding Al2O3 Layers T2 - Electronics : open access journal N2 - The resistive switching properties of HfO2 based 1T-1R memristive devices are electrically modified by adding ultra-thin layers of Al2O3 into the memristive device. Three different types of memristive stacks are fabricated in the 130 nm CMOS technology of IHP. The switching properties of the memristive devices are discussed with respect to forming voltages, low resistance state and high resistance state characteristics and their variabilities. The experimental I–V characteristics of set and reset operations are evaluated by using the quantum point contact model. The properties of the conduction filament in the on and off states of the memristive devices are discussed with respect to the model parameters obtained from the QPC fit. KW - RRAM KW - HfO2 KW - filamentary switching Y1 - 2022 U6 - https://doi.org/10.3390/electronics11101540 SN - 2079-9292 VL - 11 IS - 10 ER - TY - GEN A1 - Glukhov, Artem A1 - Milo, Valerio A1 - Baroni, Andrea A1 - Lepri, Nicola A1 - Zambelli, Cristian A1 - Olivo, Piero A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Ielmini, Daniele T1 - Statistical model of program/verify algorithms in resistive-switching memories for in-memory neural network accelerators T2 - 2022 IEEE International Reliability Physics Symposium (IRPS) N2 - Resistive-switching random access memory (RRAM) is a promising technology for in-memory computing (IMC) to accelerate training and inference of deep neural networks (DNNs). This work presents the first physics-based statistical model describing (i) multilevel RRAM device program/verify (PV) algorithms by controlled set transition, (ii) the stochastic cycle-to-cycle (C2C) and device-to-device (D2D) variations within the array, and (iii) the impact of such imprecisions on the accuracy of DNN accelerators. The model can handle the full chain from RRAM materials/device parameters to the DNN performance, thus providing a valuable tool for device/circuit codesign of hardware DNN accelerators. KW - RRAM KW - Multilevel switching KW - neural network Y1 - 2022 SN - 978-1-6654-7950-9 SN - 978-1-6654-7951-6 U6 - https://doi.org/10.1109/IRPS48227.2022.9764497 SN - 2473-2001 SP - 3C.3-1 EP - 3C.3-7 PB - Institute of Electrical and Electronics Engineers (IEEE) ER - TY - GEN A1 - Janowitz, Christoph A1 - Mahmoodinezhad, Ali A1 - Kot, Małgorzata A1 - Morales, Carlos A1 - Naumann, Franziska A1 - Plate, Paul A1 - Zöllner, Marvin Hartwig A1 - Bärwolf, Florian A1 - Stolarek, David A1 - Wenger, Christian A1 - Henkel, Karsten A1 - Flege, Jan Ingo T1 - Toward controlling the Al2O3/ZnO interface properties by in situ ALD preparation T2 - Dalton Transactions N2 - An Al2O3/ZnO heterojunction was grown on a Si single crystal substrate by subsequent thermal and plasma-assisted atomic layer deposition (ALD) in situ. The band offsets of the heterointerface were then studied by consecutive removal of the layers by argon sputtering, followed by in situ X-ray photoelectron spectroscopy. The valence band maximum and conduction band minimum of Al2O3 are found to be 1.1 eV below and 2.3 eV above those of ZnO, resulting in a type-I staggered heterojunction. An apparent reduction of ZnO to elemental Zn in the interface region was detected in the Zn 2p core level and Zn L3MM Auger spectra. This suggests an interface formation different from previous models. The reduction of ZnO to Zn in the interface region accompanied by the creation of oxygen vacancies in ZnO results in an upward band bending at the interface. Therefore, this study suggests that interfacial properties such as the band bending as well as the valence and conduction band offsets should be in situ controllable to a certain extent by careful selection of the process parameters. KW - ALD heterojunction KW - band alignement KW - ZnO KW - Al2O3 KW - interface properties Y1 - 2022 U6 - https://doi.org/10.1039/D1DT04008A SN - 1477-9234 SN - 1477-9226 VL - 51 SP - 9291 EP - 9301 ER - TY - GEN A1 - Pérez, Eduardo A1 - Mahadevaiah, Mamathamba Kalishettyhalli A1 - Perez-Bosch Quesada, Emilio A1 - Wenger, Christian T1 - In-depth characterization of switching dynamics in amorphous HfO2 memristive arrays for the implementation of synaptic updating rules T2 - Japanese Journal of Applied Physics N2 - Accomplishing truly analog conductance modulation in memristive arrays is crucial in order to implement the synaptic plasticity in hardware-based neuromorphic systems. In this paper, such a feature was addressed by exploiting the inherent stochasticity of switching dynamics in amorphous HfO2 technology. A thorough statistical analysis of experimental characteristics measured in 4 kbit arrays by using trains of identical depression/potentiation pulses with different voltage amplitudes and pulse widths provided the key to develop two different updating rules and to define their optimal programming parameters. The first rule is based on applying a specific number of identical pulses until the conductance value achieves the desired level. The second one utilized only one single pulse with a particular amplitude to achieve the targeted conductance level. In addition, all the results provided by the statistical analysis performed may play an important role in understanding better the switching behavior of this particular technology. KW - RRAM KW - memristive device KW - HfO2 KW - memristive switching Y1 - 2022 U6 - https://doi.org/10.35848/1347-4065/ac6a3b SN - 0021-4922 VL - 61 SP - 1 EP - 7 ER - TY - GEN A1 - Baroni, Andrea A1 - Glukhov, Artem A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Calore, Enrico A1 - Schifano, Sebastiano Fabio A1 - Olivo, Piero A1 - Ielmini, Daniele A1 - Zambelli, Cristian T1 - An energy-efficient in-memory computing architecture for survival data analysis based on resistive switching memories T2 - Frontiers in Neuroscience N2 - One of the objectives fostered in medical science is the so-called precision medicine, which requires the analysis of a large amount of survival data from patients to deeply understand treatment options. Tools like Machine Learning and Deep Neural Networks are becoming a de-facto standard. Nowadays, computing facilities based on the Von Neumann architecture are devoted to these tasks, yet rapidly hitting a bottleneck in performance and energy efficiency. The In-Memory Computing (IMC) architecture emerged as a revolutionary approach to overcome that issue. In this work, we propose an IMC architecture based on Resistive switching memory (RRAM) crossbar arrays to provide a convenient primitive for matrix–vector multiplication in a single computational step. This opens massive performance improvement in the acceleration of a neural network that is frequently used in survival analysis of biomedical records, namely the DeepSurv. We explored how the synaptic weights mapping strategy and the programming algorithms developed to counter RRAM non-idealities expose a performance/energy trade-off. Finally, we assessed the benefits of the proposed architectures with respect to a GPU-based realization of the same task, evidencing a tenfold improvement in terms of performance and three orders of magnitude with respect to energy efficiency. KW - RRAM KW - In-Memory Computing KW - Multilevel switching Y1 - 2022 U6 - https://doi.org/10.3389/fnins.2022.932270 SN - 1662-4548 VL - Vol. 16 SP - 1 EP - 16 ER - TY - GEN A1 - Bogun, Nicolas A1 - Perez-Bosch Quesada, Emilio A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Kloes, Alexander A1 - Schwarz, Mike T1 - Analytical Calculation of Inference in Memristor-based Stochastic Artificial Neural Networks T2 - 29th International Conference on Mixed Design of Integrated Circuits and System (MIXDES), 23-24 June 2022 , Wrocław, Poland N2 - The impact of artificial intelligence on human life has increased significantly in recent years. However, as the complexity of problems rose aswell, increasing system features for such amount of data computation became troublesome due to the von Neumann’s computer architecture. Neuromorphic computing aims to solve this problem by mimicking the parallel computation of a human brain. For this approach, memristive devices are used to emulate the synapses of a human brain. Yet, common simulations of hardware based networks require time consuming Monte-Carlo simulations to take into account the stochastic switching of memristive devices. This work presents an alternative concept making use of the convolution of the probability distribution functions (PDF) of memristor currents by its equivalent multiplication in Fourier domain. An artificial neural network is accordingly implemented to perform the inference stage with handwritten digits. KW - RRAM KW - neural network Y1 - 2022 SN - 978-83-63578-22-0 SN - 978-83-63578-21-3 SN - 978-1-6654-6176-4 U6 - https://doi.org/10.23919/MIXDES55591.2022.9838321 SP - 83 EP - 88 ER - TY - GEN A1 - Lukosius, Mindaugas A1 - Lukose, Rasuolė A1 - Lisker, Marco A1 - Luongo, G. A1 - Elviretti, M. A1 - Mai, Andreas A1 - Wenger, Christian T1 - Graphene Research in 200 mm CMOS Pilot Line T2 - 45th Jubilee International Convention on Information, Communication and Electronic Technology (MIPRO), 2022 N2 - Due to the unique electronic structures, graphene and other 2D Materials are considered as materials which can enable and extend the functionalities and performance in a large variety of applications, among them in microelectronics. At this point, the investigation and preparation of graphene devices in conditions resembling as close as possible the Si technology environment is of highest importance.Towards these goals, this paper focuses on the full spectra of graphene research aspects in 200mm pilot line. We investigated different process module developments such as CMOS compatible growth of high quality graphene on germanium and its growth mechanisms, transfer related challenges on target substrates, patterning, passivation and various concepts of contacting of graphene on a full 200 mm wafers. Finally, we fabricated proof-of-concept test structures e.g. TLM, Hall bars and capacitor structures to prove the feasibility of graphene processing in the pilot line of IHP. KW - Graphene KW - CMOS Y1 - 2022 SN - 978-953-233-103-5 SN - 978-953-233-102-8 SN - 978-1-6654-8434-3 U6 - https://doi.org/10.23919/MIPRO55190.2022.9803362 SN - 2623-8764 SN - 1847-3938 SP - 113 EP - 117 ER - TY - GEN A1 - Strobel, Carsten A1 - Alvarado Chavarin, Carlos A1 - Richter, Karola A1 - Knaut, Martin A1 - Reif, Johanna A1 - Völkel, Sandra A1 - Jahn, Andreas A1 - Albert, Matthias A1 - Wenger, Christian A1 - Kirchner, Robert A1 - Bartha, Johann Wolfgang A1 - Mikolajick, Thomas T1 - Novel Graphene Adjustable-Barrier Transistor with Ultra-High Current Gain T2 - ACS Applied Materials & Interfaces N2 - A graphene-based three terminal barristor device was proposed to overcome the low on/off ratios and insufficient current saturation of conventional graphene field effect transistors. In this study, we fabricated and analyzed a novel graphene-based transistor, which resembles the structure of the barristor but uses a different operating condition. This new device, termed graphene adjustable-barriers transistor (GABT), utilizes a semiconductor-based gate rather than a metal−insulator gate structure to modulate the device currents. The key feature of the device is the two graphene-semiconductor Schottky barriers with different heights that are controlled simultaneously by the gate voltage. Due to the asymmetry of the barriers, the drain current exceeds the gate current by several orders of magnitude. Thus, the GABT can be considered an amplifier with an alterable current gain. In this work, a silicon−graphene−germanium GABT with an ultra-high current gain (ID/IG up to 8 × 106) was fabricated, and the device functionality was demonstrated. Additionally, a capacitance model is applied to predict the theoretical device performance resulting in an on−off ratio above 106, a swing of 87 mV/dec, and a drivecurrent of about 1 × 106 A/cm2. KW - Graphene KW - Transistor Y1 - 2022 U6 - https://doi.org/10.1021/acsami.2c10634 SN - 1944-8244 SN - 1944-8252 VL - 14 IS - 34 SP - 39249 EP - 39254 ER - TY - GEN A1 - Baroni, Andrea A1 - Glukhov, Artem A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Ielmini, Daniele A1 - Olivo, Piero A1 - Zambelli, Cristian T1 - Low Conductance State Drift Characterization and Mitigation in Resistive Switching Memories (RRAM) for Artificial Neural Networks T2 - IEEE Transactions on Device and Materials Reliability N2 - The crossbar structure of Resistive-switching random access memory (RRAM) arrays enabled the In-Memory Computing circuits paradigm, since they imply the native acceleration of a crucial operations in this scenario, namely the Matrix-Vector-Multiplication (MVM). However, RRAM arrays are affected by several issues materializing in conductance variations that might cause severe performance degradation. A critical one is related to the drift of the low conductance states appearing immediately at the end of program and verify algorithms that are mandatory for an accurate multi-level conductance operation. In this work, we analyze the benefits of a new programming algorithm that embodies Set and Reset switching operations to achieve better conductance control and lower variability. Data retention analysis performed with different temperatures for 168 hours evidence its superior performance with respect to standard programming approach. Finally, we explored the benefits of using our methodology at a higher abstraction level, through the simulation of an Artificial Neural Network for image recognition task (MNIST dataset). The accuracy achieved shows higher performance stability over temperature and time. KW - RRAM KW - neural network KW - Multilevel switching Y1 - 2022 U6 - https://doi.org/10.1109/TDMR.2022.3182133 SN - 1530-4388 VL - 22 IS - 3 SP - 340 EP - 347 ER - TY - GEN A1 - Prüfer, Mareike A1 - Wenger, Christian A1 - Bier, Frank F. A1 - Laux, Eva-Maria A1 - Hölzel, Ralph T1 - Activity of AC electrokinetically immobilized horseradish peroxidase T2 - Electrophoresis N2 - Dielectrophoresis(DEP) is an AC electrokinetic effect mainly used to manipulate cells.Smaller particles,like virions,antibodies,enzymes,andevendyemolecules can be immobilized by DEP as well. In principle, it was shown that enzymesare active after immobilization by DEP, but no quantification of the retainedactivity was reported so far. In this study, the activity of the enzyme horseradishperoxidase (HRP) is quantified after immobilization by DEP. For this, HRP is immobilized on regular arrays of titanium nitride ring electrodes of 500 nm diameter and 20 nm widths. The activity of HRP on the electrode chip is measured with a limit of detection of 60 fg HRP by observing the enzymatic turnover of Amplex Red and H2O2 to fluorescent resoruf in by fluorescence microscopy. The initial activity of the permanently immobilized HRP equals up to 45% of the activity that can be expected for an ideal monolayer of HRP molecules on all electrodes of the array. Localization of the immobilizate on the electrodesis accomplished by staining with the fluorescent product of the enzyme reac-tion.The high residual activity of enzymes after AC field induced immobilization shows the method’s suitability for biosensing and research applications. KW - dielectrophoresis KW - immobilization KW - nanoelectrodes Y1 - 2022 U6 - https://doi.org/10.1002/elps.202200073 SN - 1522-2683 VL - 43 IS - 18-19 SP - 1920 EP - 1933 ER - TY - GEN A1 - Franck, Max A1 - Dabrowski, Jaroslaw A1 - Schubert, Markus Andreas A1 - Wenger, Christian A1 - Lukosius, Mindaugas T1 - Towards the Growth of Hexagonal Boron Nitride on Ge(001)/Si Substrates by Chemical Vapor Deposition T2 - Nanomaterials N2 - The growth of hexagonal boron nitride (hBN) on epitaxial Ge(001)/Si substrates via high-vacuum chemical vapor deposition from borazine is investigated for the first time in a systematic manner. The influences of the process pressure and growth temperature in the range of 10−7–10−3 mbar and 900–980 °C, respectively, are evaluated with respect to morphology, growth rate, and crystalline quality of the hBN films. At 900 °C, nanocrystalline hBN films with a lateral crystallite size of ~2–3 nm are obtained and confirmed by high-resolution transmission electron microscopy images. X-ray photoelectron spectroscopy confirms an atomic N:B ratio of 1 ± 0.1. A three-dimensional growth mode is observed by atomic force microscopy. Increasing the process pressure in the reactor mainly affects the growth rate, with only slight effects on crystalline quality and none on the principle growth mode. Growth of hBN at 980 °C increases the average crystallite size and leads to the formation of 3–10 well-oriented, vertically stacked layers of hBN on the Ge surface. Exploratory ab initio density functional theory simulations indicate that hBN edges are saturated by hydrogen, and it is proposed that partial de-saturation by H radicals produced on hot parts of the set-up is responsible for the growth KW - Boron nitride KW - 2d materials KW - Chemical vapour deposition Y1 - 2022 U6 - https://doi.org/10.3390/nano12193260 SN - 2079-4991 VL - 12 IS - 19 ER - TY - GEN A1 - Glukhov, Artem A1 - Lepri, Nicola A1 - Milo, Valerio A1 - Baroni, Andrea A1 - Zambelli, Cristian A1 - Olivo, Piero A1 - Pérez, Eduardo A1 - Wenger, Christian A1 - Ielmini, Daniele T1 - End-to-end modeling of variability-aware neural networks based on resistive-switching memory arrays T2 - Proc. 30th IFIP/IEEE International Conference on Very Large Scale Integration (VLSI-SoC 2022) N2 - Resistive-switching random access memory (RRAM) is a promising technology that enables advanced applications in the field of in-memory computing (IMC). By operating the memory array in the analogue domain, RRAM-based IMC architectures can dramatically improve the energy efficiency of deep neural networks (DNNs). However, achieving a high inference accuracy is challenged by significant variation of RRAM conductance levels, which can be compensated by (i) advanced programming techniques and (ii) variability-aware training (VAT) algorithms. In both cases, however, detailed knowledge and accurate physics-based statistical models of RRAM are needed to develop programming and VAT methodologies. This work presents an end-to-end approach to the development of highly-accurate IMC circuits with RRAM, encompassing the device modeling, the precise programming algorithm, and the VAT simulations to maximize the DNN classification accuracy in presence of conductance variations. KW - RRAM KW - HfO2 KW - neural network KW - memristive switching Y1 - 2022 U6 - https://doi.org/10.1109/VLSI-SoC54400.2022.9939653 SP - 1 EP - 5 ER - TY - GEN A1 - Wen, Jianan A1 - Baroni, Andrea A1 - Pérez, Eduardo A1 - Ulbricht, Markus A1 - Wenger, Christian A1 - Krstic, Milos T1 - Evaluating Read Disturb Effect on RRAM based AI Accelerator with Multilevel States and Input Voltages T2 - 2022 IEEE International Symposium on Defect and Fault Tolerance in VLSI and Nanotechnology Systems (DFT) N2 - RRAM technology is a promising candidate for implementing efficient AI accelerators with extensive multiply-accumulate operations. By scaling RRAM devices to the synaptic crossbar array, the computations can be realized in situ, avoiding frequent weights transfer between the processing units and memory. Besides, as the computations are conducted in the analog domain with high flexibility, applying multilevel input voltages to the RRAM devices with multilevel conductance states enhances the computational efficiency further. However, several non-idealities existing in emerging RRAM technology may degrade the reliability of the system. In this paper, we measured and investigated the impact of read disturb on RRAM devices with different input voltages, which incurs conductance drifts and introduces errors. The measured data are deployed to simulate the RRAM based AI inference engines with multilevel states. KW - RRAM KW - Multilevel switching KW - AI accelarator Y1 - 2022 SN - 978-1-6654-5938-9 SN - 978-1-6654-5937-2 U6 - https://doi.org/10.1109/DFT56152.2022.9962345 SN - 2765-933X SP - 1 EP - 6 ER - TY - GEN A1 - Pérez, Eduardo A1 - Maldonado, David A1 - Perez-Bosch Quesada, Emilio A1 - Mahadevaiah, Mamathamba Kalishettyhalli A1 - Jimenez-Molinos, Francisco A1 - Wenger, Christian T1 - Parameter Extraction Methods for Assessing Device-to-Device and Cycle-to-Cycle Variability of Memristive Devices at Wafer Scale T2 - IEEE Transactions on Electron Devices N2 - The stochastic nature of the resistive switching (RS) process in memristive devices makes device-to-device (DTD) and cycle-to-cycle (CTC) variabilities relevant magnitudes to be quantified and modeled. To accomplish this aim, robust and reliable parameter extraction methods must be employed. In this work, four different extraction methods were used at the production level (over all the 108 devices integrated on 200-mm wafers manufactured in the IHP 130-nm CMOS technology) in order to obtain the corresponding collection of forming, reset, and set switching voltages. The statistical analysis of the experimental data (mean and standard deviation (SD) values) was plotted by using heat maps, which provide a good summary of the whole data at a glance and, in addition, an easy manner to detect inhomogeneities in the fabrication process. KW - RRAM KW - memristive device KW - cycle-to-cycle variability KW - device-to-device variability Y1 - 2023 U6 - https://doi.org/10.1109/TED.2022.3224886 SN - 0018-9383 VL - 70 IS - 1 SP - 360 EP - 365 ER -