TY - CHAP A1 - Bärwolff, Manuela A1 - Böhm, Christian A1 - Schmidt, C. A1 - Schwarz, K.- U. A1 - Vetter, A. T1 - Combining short rotation coppice with annual crops - modern agroforestry systems for sustainable land use T2 - Proceedings of the 19th European Biomass Conference and Exhibition: From Research to Industry and Markets, 6-9 Juni 2011 in Berlin, Deutschland Y1 - 2011 SN - 978-88-89407-55-4 U6 - https://doi.org/10.5071/19thEUBCE2011-OB1.5 SP - 55 EP - 60 ER - TY - CHAP A1 - Grünewald, Holger A1 - Bärwolff, Manuela A1 - Böhm, Christian A1 - Schwarz, K.- U. A1 - Schmidt, C. T1 - Ökologische und ökonomische Bewertung von Agroforstsystemen in der landwirtschaftlichen Praxis T2 - Holzerzeugung in der Landwirtschaft Y1 - 2008 SN - 978-3-937728-05-6 N1 - Verbundforschungsvorhaben DENDROM SP - 213 EP - 216 PB - BTU CY - Cottbus ER - TY - CHAP A1 - Böhm, Christian A1 - Freese, Dirk A1 - Schmidt, C. A1 - Hüttl, Reinhard F. T1 - Alley cropping - an option to combine crop and woody biomass production at degraded post-mining sites in Germany T2 - Book of Abstracts, 2nd World Congress of Agroforestry, Agroforestry - The Future of Global Land Use Y1 - 2009 UR - http://www.worldagroforestry.org/wca2009/reports/docs/Book%20of%20Abstracts-Final%20with%20Index%20new.pdf SN - 978-92-9059-255-6 SP - S. 253 PB - World Agroforestry Centre CY - Nairobi, Kenya ER - TY - CHAP A1 - Grünewald, Holger A1 - Bärwolff, Manuela A1 - Böhm, Christian A1 - Schwarz, K.- U. A1 - Schmidt, C. T1 - Establishment of alley-cropping systems with short rotation woody crops in Germany T2 - Book of Abstracts, 2nd World Congress of Agroforestry, Agroforestry - The Future of Global Land Use Y1 - 2009 UR - http://www.worldagroforestry.org/wca2009/reports/docs/Book%20of%20Abstracts-Final%20with%20Index%20new.pdf SN - 978-92-9059-255-6 SP - S. 119 PB - World Agroforestry Centre CY - Nairobi, Kenya ER - TY - GEN A1 - Pożarowska, Emilia A1 - Pleines, Linus A1 - Prieto, Mauricio J. A1 - Tănase, Liviu C. A1 - de Souza Caldas, Lucas A1 - Tiwari, Aarti A1 - Schmidt, Thomas A1 - Falta, Jens A1 - Morales, Carlos A1 - Flege, Jan Ingo T1 - The relationship between Sm alloying and structure sensitivity of ceria(111)- and (100)-oriented nanoislands on Cu(111) T2 - Physical chemistry, chemical physics N2 - We have investigated the complex dynamics of samarium deposition on ceria islands of different orientations, namely (111) and (100), grown side by side on a Cu(111) single-crystal substrate, followed by post-oxidation and annealing under ultra-high vacuum conditions. Only the (100)-oriented ceria islands undergo substantial initial reduction upon samarium deposition at 740 K via a pathway similar to the strong Ce–ceria interfacial interaction, while the (111)-oriented islands remain in the Ce4+ oxidation state. This remarkable structure sensitivity is explained by the different energies required for oxygen vacancy formation for both oxide orientations. Subsequent mild re-oxidation with O2 results in the complete recovery of the Ce4+ oxidation state in the (100)-oriented islands, indicating the complete healing of oxygen vacancies. In contrast, extended annealing at moderate temperatures likely induces persistent samarium incorporation into the cerium oxide matrix. Our results provide new insights into the complex structure–activity relationships in mixed rare-earth metal oxide systems and have promising implications for optimizing catalytic reactions over such compounds in reducing environments. KW - LEEM Y1 - 2025 U6 - https://doi.org/10.1039/D5CP01171J SN - 1463-9076 VL - 27 IS - 29 SP - 15691 EP - 15703 PB - Royal Society of Chemistry (RSC) CY - Cambridge ER - TY - GEN A1 - Ackermann, G. A1 - Peil, M. A1 - Quarz, C. A1 - Schmidt, A. A1 - Halaczkiewicz, M. A1 - Thomas, A. D. A1 - Stegmüller, S. A1 - Richling, E. A1 - Manolikakes, G. A1 - Christmann, M. A1 - Küpper, Jan-Heiner A1 - Schrenk, D. A1 - Fahrer, J. T1 - Molecular dosimetry of estragole and 1′-hydroxyestragole-induced DNA adduct formation, clastogenicity and cytotoxicity in human liver cell models T2 - Archives of toxicology N2 - The phenylpropene estragole (ES) is found in essential oils of herbs and spices, such as bitter fennel and basil. Humans are exposed to ES through the diet and phytomedicines. After its absorption, ES undergoes metabolic activation by CYP1A2 and SULT1A1 in the liver, which can give rise to DNA adducts and hepatocarcinogenesis. Until now, quantitative genotoxicity data for ES in human liver cells are scarce, correlating DNA adduct levels with critical effects such as clastogenicity. Here, we used human HepG2 and HepG2-CYP1A2 cells as well as primary human hepatocytes (PHH) to study the genotoxic, clastogenic and cytotoxic potential of ES and its crucial metabolite 1′-hydroxyestragole (1′OH-ES). In addition, primary rat hepatocytes (PRH) were used for selected endpoints. Treatment of HepG2-CYP1A2 cells with ES (0–2 mM) led to the concentration-dependent formation of E3′- N 2 -dG adducts. Apart from a moderate γH2AX induction, neither p53 accumulation nor cytotoxicity was observed. However, clastogenicity was demonstrated at ES concentrations ≥ 1 mM. Incubation of HepG2 cells with 1′OH-ES (0—35 µM) led to 10–50-fold higher E3′- N 2 -dG adduct levels compared to equimolar ES concentrations. Furthermore, 1′OH-ES caused γH2AX formation, p53 accumulation and cytotoxicity, which was confirmed in PHH. In agreement, 1′OH-ES induced clastogenicity at concentrations ≥ 25 µM. Molecular dosimetry revealed that a certain E3′- N 2 -dG adduct level is required to trigger clastogenicity and cytotoxicity. This was confirmed by Benchmark Concentration (BMC) modelling, showing that the BMC for clastogenicity is 12–17-fold higher than the respective BMC for DNA adduct formation. Our data indicate that a threshold level of DNA adducts is required, both in rat and human liver cells, to trigger markers of clastogenicity. These levels are unlikely to be reached in humans following chronic ES exposure through phytomedicines or the diet. KW - Plant toxin KW - Phenylpropanoids KW - Estragole KW - Human hepatocytes KW - Liver damage KW - Cytotoxicity KW - Genotoxicity KW - Clastogenicity KW - Concentration–response modelling Y1 - 2025 U6 - https://doi.org/10.1007/s00204-025-04084-2 SN - 0340-5761 SN - 1432-0738 VL - 99 IS - 9 SP - 3769 EP - 3785 PB - Springer CY - Berlin ; Heidelberg ER - TY - GEN A1 - Braud, N. A1 - Wallander, H.J. A1 - Buß, L. A1 - Löfstrand, M. A1 - Blomqvist, J. A1 - Berschauer, C. A1 - Rodriguez, A. Morales A1 - Kofoed, P.M. A1 - Resta, A. A1 - Krisponeit, J.-O. A1 - Schmidt, T. A1 - Lundgren, E. A1 - Flege, J.I. A1 - Falta, J. A1 - Merte, L.R. T1 - Growth, structure, and morphology of ultra-thin tin oxide phases forming on Pt₃Sn(111) single crystals upon exposure to oxygen T2 - Surface science N2 - Here we report an investigation of ultrathin tin oxide films on Pt3Sn(111) using low-energy electron microscopy (LEEM), microspot low-energy electron diffraction (𝜇-LEED), scanning tunneling microscopy (STM), surface X-ray diffraction (SXRD), and high-resolution X-ray photoelectron spectroscopy (XPS). Oxidation at ∼390–410 ◦C produces triangular, two-dimensional oxide islands that nucleate rapidly and exhibit self-limited lateral growth, attributed to limited Sn diffusion from the subsurface of the crystal. 𝜇-LEED shows that the initially formed (4 × 4) Sn oxide is subsequently converted to a more oxygen-rich (2 × 2𝑛) ‘‘stripe’’ phase. At 630 ◦C, enhanced Sn mobility enables a closed (4 × 4) film. The (2 × 2𝑛) phase is shown to consist of a (2 × 2) Sn lattice modulated by 1D stripe defects with spacings of 𝑛 = 4–6 atomic rows; LEED and SXRD measurements show diffraction features corresponding to this striped superstructure. The two oxides can be distinguished in XPS by their O 1s lineshapes: the (4 × 4) phase shows a clear doublet attributable to distinct O species, whereas the (2 × 2𝑛) phase exhibits a broader envelope consistent with a distribution of O coordination environments. The Sn 3d5∕2 spectra are similar for both phases, reflecting closely related Sn bonding motifs. The spectra are consistent with those of previous near-ambient-pressure XPS measurements, suggesting that the surface oxides forming under CO oxidation conditions are similar to those studied here. KW - Tin oxide KW - Platinum-tin KW - LEEM KW - STM KW - SnOx KW - SXRD Y1 - 2026 U6 - https://doi.org/10.1016/j.susc.2025.122927 SN - 0039-6028 SN - 1879-2758 VL - 767 SP - 1 EP - 8 PB - Elsevier BV CY - Amsterdam ER -