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<export-example>
  <doc>
    <id>27284</id>
    <completedYear/>
    <publishedYear>2021</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue>4</issue>
    <volume>11</volume>
    <type>articler</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2021-04-07</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Nickel Phosphide Catalysts as Efficient Systems for CO2 Upgrading via Dry Reforming of Methane</title>
    <abstract language="eng">This work establishes the primordial role played by the support’s nature when aimed at the constitution of Ni2P active phases for supported catalysts. Thus, carbon dioxide reforming of methane was studied over three novel Ni2P catalysts supported on Al2O3, CeO2 and SiO2-Al2O3 oxides. The catalytic performance, shown by the catalysts’ series, decreased according to the sequence: Ni2P/Al2O3 &gt; Ni2P/CeO2 &gt; Ni2P/SiO2-Al2O3. The depleted CO2 conversion rates discerned for the Ni2P/SiO2-Al2O3 sample were associated to the high sintering rates, large amounts of coke deposits and lower fractions of Ni2P constituted in the catalyst surface. The strong deactivation issues found for the Ni2P/CeO2 catalyst, which also exhibited small amounts of Ni2P species, were majorly associated to Ni oxidation issues. Along with lower surface areas, oxidation reactions might also affect the catalytic behaviour exhibited by the Ni2P/CeO2 sample. With the highest conversion rate and optimal stabilities, the excellent performance depicted by the Ni2P/Al2O3 catalyst was mostly related to the noticeable larger fractions of Ni2P species established</abstract>
    <parentTitle language="eng">Catalysts</parentTitle>
    <identifier type="doi">10.3390/catal11040446</identifier>
    <identifier type="issn">2073-4344</identifier>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="Artikelnummer">446</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">false</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Miriam</firstName>
      <lastName>González-Castaño</lastName>
    </author>
    <submitter>
      <firstName>Renate</firstName>
      <lastName>Choyna</lastName>
    </submitter>
    <author>
      <firstName>Estelle le</firstName>
      <lastName>Saché</lastName>
    </author>
    <author>
      <firstName>Cameron</firstName>
      <lastName>Berry</lastName>
    </author>
    <author>
      <firstName>Laura</firstName>
      <lastName>Pastor-Pérez</lastName>
    </author>
    <author>
      <firstName>Harvey</firstName>
      <lastName>Arellano-García</lastName>
    </author>
    <author>
      <firstName>Qiang</firstName>
      <lastName>Wang</lastName>
    </author>
    <author>
      <firstName>Tomas</firstName>
      <lastName>Ramirez Reina</lastName>
    </author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Ni2P</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>supported catalysts</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>dry reforming of methane</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Al2O3</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>CeO2</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>SiO2-Al2O3</value>
    </subject>
    <collection role="institutes" number="3603">FG Prozess- und Anlagentechnik</collection>
  </doc>
  <doc>
    <id>30149</id>
    <completedYear/>
    <publishedYear>2022</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1250</pageFirst>
    <pageLast>1280</pageLast>
    <pageNumber/>
    <edition/>
    <issue>4</issue>
    <volume>4</volume>
    <type>articler</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2023-01-24</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Development of Power-to-X Catalytic Processes for CO2 Valorisation: From the Molecular Level to the Reactor Architecture</title>
    <abstract language="eng">Nowadays, global climate change is likely the most compelling problem mankind is facing. In this scenario, decarbonisation of the chemical industry is one of the global challenges that the scientific community needs to address in the immediate future. Catalysis and catalytic processes are called to play a decisive role in the transition to a more sustainable and low-carbon future. This critical review analyses the unique advantages of structured reactors (isothermicity, a wide range of residence times availability, complex geometries) with the multifunctional design of efficient catalysts to synthesise chemicals using CO2 and renewable H2 in a Power-to-X (PTX) strategy. Fine-chemistry synthetic methods and advanced in situ/operando techniques are essential to elucidate the changes of the catalysts during the studied reaction, thus gathering fundamental information about the&#13;
active species and reaction mechanisms. Such information becomes crucial to refine the catalyst’s formulation and boost the reaction’s performance. On the other hand, reactors architecture allows&#13;
flow pattern and temperature control, the management of strong thermal effects and the incorporation of specifically designed materials as catalytically active phases are expected to significantly contribute&#13;
to the advance in the valorisation of CO2 in the form of high added-value products. From a general perspective, this paper aims to update the state of the art in Carbon Capture and Utilisation (CCU)&#13;
and PTX concepts with emphasis on processes involving the transformation of CO2 into targeted fuels and platform chemicals, combining innovation from the point of view of both structured reactor&#13;
design and multifunctional catalysts development.</abstract>
    <parentTitle language="eng">Chemistry</parentTitle>
    <identifier type="url">https://www.mdpi.com/2624-8549/4/4/83</identifier>
    <identifier type="doi">10.3390/chemistry4040083</identifier>
    <identifier type="issn">2624-8549</identifier>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="Publikationsweg">Open Access</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Luis F.</firstName>
      <lastName>Bobadilla</lastName>
    </author>
    <submitter>
      <firstName>Bogdan</firstName>
      <lastName>Dorneanu</lastName>
    </submitter>
    <author>
      <firstName>Lola</firstName>
      <lastName>Azancot</lastName>
    </author>
    <author>
      <firstName>Ligia A.</firstName>
      <lastName>Luque-Alvarez</lastName>
    </author>
    <author>
      <firstName>Guillermo</firstName>
      <lastName>Torres-Sempere</lastName>
    </author>
    <author>
      <firstName>Miriam</firstName>
      <lastName>Gonzalez-Castano</lastName>
    </author>
    <author>
      <firstName>Laura</firstName>
      <lastName>Pastor-Perez</lastName>
    </author>
    <author>
      <firstName>Jie</firstName>
      <lastName>Yu</lastName>
    </author>
    <author>
      <firstName>Tomas</firstName>
      <lastName>Ramirez Reina</lastName>
    </author>
    <author>
      <firstName>Svetlana</firstName>
      <lastName>Ivanova</lastName>
    </author>
    <author>
      <firstName>Miguel Angel</firstName>
      <lastName>Centeno</lastName>
    </author>
    <author>
      <firstName>José Antonio</firstName>
      <lastName>Odriozola</lastName>
    </author>
    <collection role="institutes" number="3603">FG Prozess- und Anlagentechnik</collection>
  </doc>
  <doc>
    <id>30101</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst/>
    <pageLast/>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>7</volume>
    <type>articler</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2023-01-19</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Influence of Reaction Parameters on the Catalytic Upgrading of an Acetone, Butanol and Ethanol (ABE) Mixture: Exploring New Routes for Modern Biorefineries</title>
    <abstract language="eng">Here we present a comprehensive study on the effect of reaction parameters on the upgrade of an acetone, butanol and ethanol mixture – key molecules and platform products of great interest within the chemical sector. Using a selected high performing catalyst, Fe/MgO-Al2O3, the variation of temperature, reaction time, catalytic loading and reactant molar ratio have been examined in this reaction. This work is aiming to not only optimise the reaction conditions previously used, but to step towards using less energy, time and material by testing those conditions and analysing the sufficiency of the results. Herein we demonstrate that this reaction is favoured at higher temperatures and longer reaction time. Also, we observe that increasing the catalyst loading had a positive effect on the product yields, while reactant ratios have shown to produce varied results due to the role of each reactant in the complex reaction network. In line with the aim of reducing energy and costs, this work showcases that the products from the upgrading route have significantly higher market value than the reactants; highlighting that this process represents an appealing route to be implemented in modern biorefineries.</abstract>
    <parentTitle language="eng">Frontiers in Chemistry</parentTitle>
    <identifier type="url">https://www.frontiersin.org/articles/10.3389/fchem.2019.00906/full</identifier>
    <identifier type="doi">10.3389/fchem.2019.00906</identifier>
    <identifier type="issn">2296-2646</identifier>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="Artikelnummer">906</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="Publikationsweg">Open Access</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Elham</firstName>
      <lastName>Ketabchi</lastName>
    </author>
    <submitter>
      <firstName>Bogdan</firstName>
      <lastName>Dorneanu</lastName>
    </submitter>
    <author>
      <firstName>Laura</firstName>
      <lastName>Pastor-Perez</lastName>
    </author>
    <author>
      <firstName>Harvey</firstName>
      <lastName>Arellano-García</lastName>
    </author>
    <author>
      <firstName>Tomas</firstName>
      <lastName>Ramirez Reina</lastName>
    </author>
    <collection role="institutes" number="3603">FG Prozess- und Anlagentechnik</collection>
  </doc>
  <doc>
    <id>30102</id>
    <completedYear/>
    <publishedYear>2020</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>1065</pageFirst>
    <pageLast>1075</pageLast>
    <pageNumber/>
    <edition/>
    <issue/>
    <volume>156</volume>
    <type>articler</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2023-01-19</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Catalytic upgrading of acetone, butanol and ethanol (ABE): A step ahead for the production of added value chemicals in bio-refineries</title>
    <abstract language="eng">With the aim of moving towards sustainability and renewable energy sources, we have studied the production of long chain hydrocarbons from a renewable source of biomass to reduce negative impacts of greenhouse gas emissions while providing a suitable alternative for fossil fuel-based processes. Herein we report a catalytic strategy for Acetone, Butanol and Ethanol (ABE) upgrading using economically viable catalysts with potential impact in modern bio-refineries. Our catalysts based on transition metals such as Ni, Fe and Cu supported on MgO–Al2O3 have been proven to perform exceptionally with outstanding conversions towards the production of a broad range of added value chemicals from C2 to C15. Although all catalysts displayed meritorious performance, the Fe catalyst has shown the best results in terms conversion (89%). Interestingly, the Cu catalyst displays the highest selectivity towards long chain hydrocarbons (14%). Very importantly, our approach suppresses the utilization of solvents and additives resulting directly in upgraded hydrocarbons that are of use in the chemical and/or the transportation industry. Overall, this seminal work opens the possibility to consider ABE upgrading as a viable route in bio-refineries to produce renewably sourced added value products in an economically favorable way. In addition, the described process can be envisaged as a cross-link stream among bio and traditional refineries aiming to reduce fossil fuel sources involved and incorporate “greener” solutions.</abstract>
    <parentTitle language="eng">Renewable Energy</parentTitle>
    <identifier type="url">https://www.sciencedirect.com/science/article/pii/S096014812030690X?via%3Dihub</identifier>
    <identifier type="doi">10.1016/j.renene.2020.04.152</identifier>
    <identifier type="issn">1879-0682</identifier>
    <identifier type="issn">0960-1481</identifier>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Elham</firstName>
      <lastName>Ketabchi</lastName>
    </author>
    <submitter>
      <firstName>Bogdan</firstName>
      <lastName>Dorneanu</lastName>
    </submitter>
    <author>
      <firstName>Laura</firstName>
      <lastName>Pastor-Perez</lastName>
    </author>
    <author>
      <firstName>Tomas</firstName>
      <lastName>Ramirez Reina</lastName>
    </author>
    <author>
      <firstName>Harvey</firstName>
      <lastName>Arellano-García</lastName>
    </author>
    <collection role="institutes" number="3603">FG Prozess- und Anlagentechnik</collection>
  </doc>
</export-example>
