<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>34269</id>
    <completedYear/>
    <publishedYear>2024</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>57878</pageFirst>
    <pageLast>57887</pageLast>
    <pageNumber>10</pageNumber>
    <edition/>
    <issue>42</issue>
    <volume>16</volume>
    <type>articler</type>
    <publisherName>American Chemical Society (ACS)</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2024-10-23</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Reaction dynamics between formamidinium lead iodide and Copper Oxide</title>
    <abstract language="eng">Copper oxide (CuOx) has been announced as a very promising hole-transporting layer for perovskite solar cells. However, in our previous work, we have shown that once a formamidinium lead triiodide (FAPI) perovskite is spin-coated on a spray-coated cuprous oxide (Cu2O) substrate, the Cu2O diffuses into and reacts with the FAPI film. In order to verify if the degradation products are related to the oxidation state of CuOx and/or its preparation method, in this work, we first prepared CuOx films by thermal oxidation at temperatures ranging from 120 to 300 °C. While increasing the process temperature, a transformation from copper I (Cu2O) to copper II (CuO) oxidation states was observed. For both oxidation states of copper, FAPI perovskite degradation was found; however, some alterations in the reaction products were noticed. In contrast to our expectations, the introduction of an ultrathin plasma-enhanced atomic layer deposited Al2O3 layer in between both films only partially blocked the CuOx migration into the FAPI film. It can be concluded that regardless of the chemical composition and/or preparation method of CuOx, the overlayered FAPI film gets decomposed. In order to use CuOx as a hole-transporting layer in solar cells, new strategies must be developed to limit these unwanted chemical reactions.</abstract>
    <parentTitle language="eng">ACS Applied Materials &amp; Interfaces</parentTitle>
    <identifier type="doi">10.1021/acsami.4c12990</identifier>
    <identifier type="issn">1944-8244</identifier>
    <enrichment key="opus_doi_flag">true</enrichment>
    <enrichment key="opus_doi_json">{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,10,12]],"date-time":"2024-10-12T04:10:52Z","timestamp":1728706252675},"reference-count":44,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2024,10,11]],"date-time":"2024-10-11T00:00:00Z","timestamp":1728604800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,10,11]],"date-time":"2024-10-11T00:00:00Z","timestamp":1728604800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,10,11]],"date-time":"2024-10-11T00:00:00Z","timestamp":1728604800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100021130","name":"Bundesministerium f?r Wirtschaft und Klimaschutz","doi-asserted-by":"publisher","award":["KK5087602BR1"],"id":[{"id":"10.13039\/100021130","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007047","name":"Norway Grants","doi-asserted-by":"publisher","award":["NOR\/SGS\/DMOPV\/0190\/2020-00"],"id":[{"id":"10.13039\/501100007047","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ACS Appl. Mater. Interfaces"],"DOI":"10.1021\/acsami.4c12990","type":"journal-article","created":{"date-parts":[[2024,10,11]],"date-time":"2024-10-11T16:52:06Z","timestamp":1728665526000},"source":"Crossref","is-referenced-by-count":0,"title":["Reaction Dynamics between Formamidinium Lead Iodide and Copper Oxide"],"prefix":"10.1021","author":[{"ORCID":"http:\/\/orcid.org\/0000-0002-7243-3855","authenticated-orcid":true,"given":"Katarzyna","family":"Gawli\u0144ska\u2212N\u0119cek","sequence":"first","affiliation":[{"name":"Institute of Metallurgy and Materials Science Polish Academy of Sciences, Reymonta 25 St., 30-059 Krakow, Poland"}]},{"given":"Ma\u0142gorzata","family":"Kot","sequence":"additional","affiliation":[{"name":"Applied Physics and Semiconductor Spectroscopy, Brandenburg University of Technology Cottbus-Senftenberg, Konrad-Zuse-Strasse 1, 03046 Cottbus, Germany"}]},{"given":"Zbigniew","family":"Starowicz","sequence":"additional","affiliation":[{"name":"Institute of Metallurgy and Materials Science Polish Academy of Sciences, Reymonta 25 St., 30-059 Krakow, Poland"}]},{"given":"Marta","family":"Janusz-Skuza","sequence":"additional","affiliation":[{"name":"Institute of Metallurgy and Materials Science Polish Academy of Sciences, Reymonta 25 St., 30-059 Krakow, Poland"}]},{"given":"Piotr","family":"Panek","sequence":"additional","affiliation":[{"name":"Institute of Metallurgy and Materials Science Polish Academy of Sciences, Reymonta 25 St., 30-059 Krakow, Poland"}]},{"given":"Ludwig","family":"Marth","sequence":"additional","affiliation":[{"name":"SENTECH Instruments GmbH, Schwarzschildstra\u00dfe 2, 12489 Berlin, Germany"}]},{"given":"Paul","family":"Plate","sequence":"additional","affiliation":[{"name":"SENTECH Instruments GmbH, Schwarzschildstra\u00dfe 2, 12489 Berlin, Germany"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-8346-6863","authenticated-orcid":true,"given":"Jan Ingo","family":"Flege","sequence":"additional","affiliation":[{"name":"Applied Physics and Semiconductor Spectroscopy, Brandenburg University of Technology Cottbus-Senftenberg, Konrad-Zuse-Strasse 1, 03046 Cottbus, Germany"}]}],"member":"316","published-online":{"date-parts":[[2024,10,11]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1243982"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1038\/nphoton.2014.134"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1021\/jz4020162"},{"key":"ref4\/cit4","unstructured":"National Renewable Energy Laboratory (NREL).  Best\nResearch-Cell Efficiency Chart. Retrieved from https:\/\/www.nrel.gov\/pv\/cell-efficiency.html (Rev: 22 July 2024) chrome-extension:\/\/efaidnbmnnnibpcajpcglclefindmkaj\/. https:\/\/www.nrel.gov\/pv\/assets\/pdfs\/best-research-cell-efficiencies.pdf."},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.9"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201502458"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601186"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201500963"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10985-5"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105635"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c01187"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00469"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.solmat.2019.110289"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201801434"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2020.100112"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1002\/ente.201900975"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49395-7"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402249"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE00413A"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201500477"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02787"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.1c04241"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.7b01500"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA14207J"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmrt.2021.03.107"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/cm404006p"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b01177"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.201700280"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.3390\/nano13081363"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/pip.3424"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201501330"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.166285"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1063\/1.5017002"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1143\/APEX.4.062301"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1016\/j.solener.2014.03.036"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.7567\/APEX.6.044101"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.7567\/APEX.9.052301"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c03440"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/sia.6239"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1016\/j.mssp.2020.105368"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2016.09.126"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.202100185"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c06342"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1107\/S0567739476001551"}],"container-title":["ACS Applied Materials &amp;amp; Interfaces"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsami.4c12990","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsami.4c12990","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,10,11]],"date-time":"2024-10-11T17:09:12Z","timestamp":1728666552000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/acsami.4c12990"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,10,11]]},"references-count":44,"alternative-id":["10.1021\/acsami.4c12990"],"URL":"http:\/\/dx.doi.org\/10.1021\/acsami.4c12990","relation":{},"ISSN":["1944-8244","1944-8252"],"issn-type":[{"value":"1944-8244","type":"print"},{"value":"1944-8252","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,10,11]]}}}</enrichment>
    <enrichment key="opus_crossrefDocumentType">journal-article</enrichment>
    <enrichment key="opus_crossrefLicence">https://doi.org/10.15223/policy-029</enrichment>
    <enrichment key="opus_import_origin">crossref</enrichment>
    <enrichment key="opus_doiImportPopulated">PersonAuthorFirstName_1,PersonAuthorLastName_1,PersonAuthorIdentifierOrcid_1,PersonAuthorFirstName_2,PersonAuthorLastName_2,PersonAuthorFirstName_3,PersonAuthorLastName_3,PersonAuthorFirstName_4,PersonAuthorLastName_4,PersonAuthorFirstName_5,PersonAuthorLastName_5,PersonAuthorFirstName_6,PersonAuthorLastName_6,PersonAuthorFirstName_7,PersonAuthorLastName_7,PersonAuthorFirstName_8,PersonAuthorLastName_8,PersonAuthorIdentifierOrcid_8,PublisherName,TitleMain_1,Language,TitleParent_1,PublishedYear,IdentifierIssn,Enrichmentopus_crossrefLicence</enrichment>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="Referiert">Beitrag ist referiert / Article peer-reviewed</enrichment>
    <enrichment key="Publikationsweg">Open Access</enrichment>
    <enrichment key="RelationnotEU">KK5087602BR1</enrichment>
    <enrichment key="BTUfunderNamenotEU">BMWi (ZIM)</enrichment>
    <enrichment key="opus.source">doi-import</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">false</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Katarzyna</firstName>
      <lastName>Gawlińska-Nęcek</lastName>
    </author>
    <submitter>
      <firstName>Karsten</firstName>
      <lastName>Henkel</lastName>
    </submitter>
    <author>
      <firstName>Małgorzata</firstName>
      <lastName>Kot</lastName>
    </author>
    <author>
      <firstName>Zbigniew</firstName>
      <lastName>Starowicz</lastName>
    </author>
    <author>
      <firstName>Marta</firstName>
      <lastName>Janusz-Skuza</lastName>
    </author>
    <author>
      <firstName>Piotr</firstName>
      <lastName>Panek</lastName>
    </author>
    <author>
      <firstName>Ludwig</firstName>
      <lastName>Marth</lastName>
    </author>
    <author>
      <firstName>Paul</firstName>
      <lastName>Plate</lastName>
    </author>
    <author>
      <firstName>Jan Ingo</firstName>
      <lastName>Flege</lastName>
    </author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>copper oxide hole-transporting layer</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>formamidinium lead iodide instability</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>perovskite solar cells</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>atomic layer deposition</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>aluminum oxide</value>
    </subject>
    <collection role="institutes" number="1503">FG Angewandte Physik und Halbleiterspektroskopie</collection>
  </doc>
</export-example>
