<?xml version="1.0" encoding="utf-8"?>
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  <doc>
    <id>33110</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>775</pageFirst>
    <pageLast>784</pageLast>
    <pageNumber/>
    <edition/>
    <issue>1</issue>
    <volume>39</volume>
    <type>articler</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2024-03-27</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">NH3NO interaction at low-temperatures: an experimental and modeling study</title>
    <abstract language="eng">The present work provides new insight into NH3single bondNO interaction under low-temperature conditions. The oxidation process of neat NH3 and NH3 doped with NO (450, 800 ppm) was experimentally investigated in a Jet Stirred Flow Reactor at atmospheric pressure for the temperature range 900–1350 K. Results showed NO concentration is entirely controlled by DeNOx reactions in the temperature range 1100–1250 K, while NH3single bondNO interaction does not develop through a sensitizing NO effect, for these operating conditions.&#13;
&#13;
A detailed kinetic model was developed by systematically updating rate constants of controlling reactions and declaring new reactions for N2H2 isomers (cis and trans). The proposed mechanism well captures target species as NO and H2 profiles. For NH3single bondNO mixtures, NO profiles were properly reproduced through updated DeNOx chemistry, while NH2 recombination reactions were found to be essential for predicting the formation of H2. The role of ammonia as a third-body species is implemented in the updated mechanism, with remarkable effects on species predictions. For neat NH3 mixture, the reaction H+O2(+M)=HO2(+M) was crucial to predict NO formation via the reaction NH2+HO2double bondH2NO+OH.</abstract>
    <parentTitle language="eng">Proceedings of the Combustion Institute</parentTitle>
    <identifier type="doi">10.1016/j.proci.2022.09.027</identifier>
    <identifier type="issn">1873-2704</identifier>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="opus.doi.autoCreate">false</enrichment>
    <enrichment key="opus.urn.autoCreate">false</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Maria Virginia</firstName>
      <lastName>Manna</lastName>
    </author>
    <submitter>
      <firstName>Yvonne</firstName>
      <lastName>Teetzen</lastName>
    </submitter>
    <author>
      <firstName>Pino</firstName>
      <lastName>Sabia</lastName>
    </author>
    <author>
      <firstName>Krishna Prasad</firstName>
      <lastName>Shrestha</lastName>
    </author>
    <author>
      <firstName>Lars</firstName>
      <lastName>Seidel</lastName>
    </author>
    <author>
      <firstName>Raffaele</firstName>
      <lastName>Ragucci</lastName>
    </author>
    <author>
      <firstName>Fabian</firstName>
      <lastName>Mauß</lastName>
    </author>
    <author>
      <firstName>Mara</firstName>
      <lastName>De Joannon</lastName>
    </author>
    <collection role="institutes" number="3207">FG Thermodynamik / Thermische Verfahrenstechnik</collection>
  </doc>
</export-example>
