<?xml version="1.0" encoding="utf-8"?>
<export-example>
  <doc>
    <id>30377</id>
    <completedYear/>
    <publishedYear>2023</publishedYear>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2988</pageFirst>
    <pageLast>2994</pageLast>
    <pageNumber/>
    <edition/>
    <issue>6</issue>
    <volume>127</volume>
    <type>articler</type>
    <publisherName/>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>0</belongsToBibliography>
    <completedDate>2023-02-24</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Oxygen Storage by Tin Oxide Monolayers on Pt3Sn(111)</title>
    <abstract language="eng">The high performance of platinum–tin catalysts for oxidation reactions has been linked to the formation of tin oxides at the metal surface, but little is known about the structure of these oxides or the chemical behavior that determines their catalytic properties. We show here how surface oxides on Pt3Sn(111) incorporate oxygen at the metal interface, which may be subsequently removed by reaction with CO. The storage mechanism, where oxygen uptake occurs without loss of interfacial Pt–Sn bonds, is enabled by the peculiar asymmetrical coordination state of Sn2+. O atoms are bound at pocket sites in the 2D oxide sheet between these outward-buckled Sn atoms and metallic Sn in the alloy surface below.</abstract>
    <parentTitle language="eng">The Journal of Physical Chemistry. C</parentTitle>
    <identifier type="issn">1932-7447</identifier>
    <identifier type="issn">1932-7455</identifier>
    <identifier type="doi">10.1021/acs.jpcc.2c09041</identifier>
    <enrichment key="BTU">an der BTU erstellt / created at BTU</enrichment>
    <enrichment key="opus.source">publish</enrichment>
    <enrichment key="Fprofil">1 Energiewende und Dekarbonisierung / Energy Transition and Decarbonisation</enrichment>
    <enrichment key="Fprofil">4 Künstliche Intelligenz und Sensorik / Artificial Intelligence and Sensor Technology</enrichment>
    <author>
      <firstName>Lindsay R.</firstName>
      <lastName>Merte</lastName>
    </author>
    <submitter>
      <firstName>Karsten</firstName>
      <lastName>Henkel</lastName>
    </submitter>
    <author>
      <firstName>Nicolas</firstName>
      <lastName>Braud</lastName>
    </author>
    <author>
      <firstName>Lars</firstName>
      <lastName>Buß</lastName>
    </author>
    <author>
      <firstName>Malthe Kjær</firstName>
      <lastName>Bisbo</lastName>
    </author>
    <author>
      <firstName>Harald J.</firstName>
      <lastName>Wallander</lastName>
    </author>
    <author>
      <firstName>Jon-Olaf</firstName>
      <lastName>Krisponeit</lastName>
    </author>
    <author>
      <firstName>Jan Ingo</firstName>
      <lastName>Flege</lastName>
    </author>
    <author>
      <firstName>Bjørk</firstName>
      <lastName>Hammer</lastName>
    </author>
    <author>
      <firstName>Jens</firstName>
      <lastName>Falta</lastName>
    </author>
    <author>
      <firstName>Edvin</firstName>
      <lastName>Lundgren</lastName>
    </author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>Oxygen storage</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>low-energy electron microscopy (LEEM)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>microprobe low-energy electron diffraction (μ-LEED)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>scanning tunneling microscopy (STM)</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>GOFEE algorithm</value>
    </subject>
    <collection role="institutes" number="1503">FG Angewandte Physik und Halbleiterspektroskopie</collection>
  </doc>
</export-example>
