@inproceedings{ZaplataKollmannUlrichetal., author = {Zaplata, Markus K. and Kollmann, Johannes and Ulrich, Werner and Winter, Susanne and Schaaf, Wolfgang and Elmer, Michael and Gerwin, Werner and Fischer, Anton}, title = {Cover balance or degree of autocorrelation? It is the same and integratively traces pattern formation during succession}, series = {Gf{\"O} 43rd Annual Meeting, Building bridges in ecology, linking systems, scales and disciplines, September 9 to 13, 2013, Potsdam, Germany}, booktitle = {Gf{\"O} 43rd Annual Meeting, Building bridges in ecology, linking systems, scales and disciplines, September 9 to 13, 2013, Potsdam, Germany}, editor = {Jeltsch, Florian and Joshi, Jasmin}, pages = {228 -- 229}, abstract = {It is widely acknowledged that increasing complexity is a key attribute of ecosystem genesis. This is particularly true for primary succession on homogeneous substrates. However, a mechanistic understanding of spatial colonisation and pattern formation during primary succession has not been achieved yet. Thus, we studied this topic for 7 years within an experimental catchment (6 ha) established in the post-mining landscape of eastern Germany. Equidistant permanent plots (120 plots {\`a} 25m²) allowed for autocorrelation analyses, and thus tracing the spatial development of species cover performance. For each species tested, the "cover balance" first increased due to colonization, while decreasing in the course of succession. Drawing a benefit from these temporal trends, we suggested cover balance levels revealed by autocorrelation analyses to best indicate well-defined phases in primary succession at spatial entities. Hence, with the help of this spatial approach, terrestrial succession can be understood now much better at the most general level of the hierarchy provided by Pickett et al. (1987). In accordance with these authors, at subordinated levels of the causal hierarchy differential species performance might get collectively explained by contributing processes or conditions, such as ecophysiological traits, life history strategies, competition and allelopathy of the occurring plant species. Further research is needed to understand their relative contributions to the pattern formation.}, language = {en} } @incollection{KoegelKnabnerBensHuettletal., author = {K{\"o}gel-Knabner, Ingrid and Bens, Oliver and H{\"u}ttl, Reinhard F. and Fischer, Thomas and D{\"u}mig, Alexander and Spr{\"o}te, Roland}, title = {Project A3 - Initial stages of humus development}, series = {Structures and processes of the initial ecosystem development phase in an artificial water catchment (Final report CRC/TR 38)}, booktitle = {Structures and processes of the initial ecosystem development phase in an artificial water catchment (Final report CRC/TR 38)}, editor = {H{\"u}ttl, Reinhard F. and K{\"o}gel-Knabner, Ingrid and Schulin, Rainer and Gerwin, Werner}, publisher = {BTU Forschungszentrum Landschaftsentwicklung und Bergbaulandschaften (FZLB)}, address = {Cottbus}, pages = {25 -- 35}, language = {en} } @phdthesis{Sproete, author = {Spr{\"o}te, Roland}, title = {Entwicklung von Benetzungshemmung auf sandigen Substraten unter dem Einfluss biologischer Bodenkru sten und h{\"o}herer Vegetationsentwicklung}, publisher = {BTU, LS Bodenschutz und Rekultivierung}, address = {Cottbus}, pages = {121}, abstract = {Mit dieser Arbeit wurde der Einfluss von biologischen Bodenkrusten auf die Benetzungshemmung / Hydrophobizit{\"a}t auf sandigen, anthropogen gesch{\"u}tteten, rekultivierten B{\"o}den der Tagebaufolgelandschaft und auf sandigen, sich mehr oder weniger nat{\"u}rlich entwickelnden B{\"o}den in Flugsandarealen und D{\"u}nengebieten S{\"u}dbrandenburgs untersucht. Gezeigt wurde, dass sich in der Bergbaufolgelandschaft auf dem sandigen anthropogen gesch{\"u}tteten Substrat andere Krustenarten auf der Substratoberfl{\"a}che ansiedeln als auf der Substratoberfl{\"a}che von Flugsandgebieten und D{\"u}nen. Der Effekt der Benetzungshemmung ist bei den Krustenarten der rekultivierten Bergbaufl{\"a}chen st{\"a}rker ausgepr{\"a}gt als bei den nat{\"u}rlichen Flugsandgebieten und D{\"u}nen, wo die Benetzungshemmung im Krustentstadium mit Einfluss von Moosen wieder zur{\"u}ckgeht. Gerade Flechten haben in Bergbaufolgelandschaften negativen Einfluss auf die Infiltration von Niederschlag. Auch die Bindungskr{\"a}fte zwischen den Partikeln spielen bei der Betrachtung des Einflusses der Benetzungshemmung / Hydrophobizit{\"a}t eine Rolle, denn es zeigt sich bei Betrachtung der Korngr{\"o}ßenverteilung, dass das Substrat in den Rekultivierungsgebieten der Bergbaufolgelandschaft unsortiert ist und hohe Anteile an Feinmaterial (Schluff und Ton) aufweisen kann. Auf den Flugsandgebieten findet eine nat{\"u}rliche Sortierung der Partikel durch Wind und Wasser statt, wobei das Substrat meist locker lagernd vorkommt und lediglich im Lee von h{\"o}heren Pflanzen zur Ruhe kommen kann. Dort {\"u}bernehmen dann biologische Bodenkrusten und andere Mikroorganismen die Bindung und Festigung der Partikel z. B. durch extrazellul{\"a}re polymere Substanzen. Es wurde deutlich, dass die Akkumulation organischer Substanz bei Bewuchs mit Laubgeh{\"o}lzen in gr{\"o}ßerem Maße stattfindet als bei Bewuchs mit Nadelgeh{\"o}lzen. Jedoch weisen die Chlorophyll a-Gehalte auf mehr Biomasse durch biologische Bodenkrusten bei den Nadelgeh{\"o}lzen hin. Insgesamt ist festzuhalten, dass jeder untersuchte Standort separat f{\"u}r sich betrachtet werden muss und nicht von einer Chronosequenz im Sinne einer eindeutig zeitlichen Abfolge bei Betrachtung der Alter der Standorte ausgegangen werden kann. Lediglich die Standorte in der Bergbaufolgelandschaftf{\"u}r sich sowie die Standorte in den relativ nat{\"u}rlich entwickelten Flugsand- und D{\"u}nengebieten k{\"o}nnen gemeinsam betrachtet werden. Wie gezeigt wurde, beeinflussen biologische Bodenkrusten gerade schon in der Initialphase der Bodenbildung den Wasserhaushalt durch Porenverschluss, durch hydrophob wirkende Exsudate, aber auch durch Rhizoide der Moose, insbesondere im brandenburgischen {\"U}bergangsklima vom maritimen zum kontinentalen Klima. Durch die Regulierung des Wasserhaushalts des Bodens durch die biologischen Bodenkrusten wird die Bodenentwicklung in bestimmte Richtungen gelenkt. Hierf{\"u}r sind allerdings Langzeitbeobachtungen und eine m{\"o}glichst gewissenhafte Auswahl an Chronosequenzen notwendig.}, language = {de} } @misc{SchaafElmerFischeretal., author = {Schaaf, Wolfgang and Elmer, Michael and Fischer, Anton and Gerwin, Werner and Nenov, Rossen and Pretzsch, Hans and Seifert, Stefan and Winter, Susanne and Zaplata, Markus K.}, title = {Monitoring the formation of structures and patterns during initial development of an artificial catchment}, series = {Environmental Monitoring and Assessment}, volume = {Vol. 185}, journal = {Environmental Monitoring and Assessment}, number = {7}, issn = {0167-6369}, doi = {10.1007/s10661-012-2998-x}, pages = {5965 -- 5986}, abstract = {The objective of this paper is to present observations, results from monitoring measurements, and preliminary conclusions about the development of patterns and structures during the first 5 years of development of an artificial catchment starting from point zero. We discuss the high relevance of initial system traits and external events for the system development and draw conclusions for further research. These investigations as part of a Collaborative Research Center, aim to disentangle and understand the feedback mechanisms and interrelationships of processes and their co-development with spatial and temporal structures and patterns by studying an initial, probably less complex ecosystem. Therefore, intensive measurements were carried out in the catchment with regard to the development of surface structures, hydrological patterns, vegetation dynamics, water chemistry, and element budgets. During the first 5 years, considerable changes within the catchment were observed. Both internal and external factors could be identified as driving forces for the formation of structures and patterns in the artificial catchment. Initial structures formed by the construction process and initial substrate characteristics were decisive for the distribution and flow of water. External factors like episodic events triggered erosion and dissection during this initial phase, promoted by the low vegetation cover, and the unconsolidated sandy substrate. The transformation of the initial geosystem into areas with evolving terrestrial or aquatic characteristics and from a very episodic to a more permanent stream network and discharge, together with the observed vegetation dynamics increased site diversity and heterogeneity with respect to water and nutrient availability and transformation processes compared with the more homogenous conditions at point zero. The processes and feedback mechanisms in the initial development of a new landscape may deviate in rates, intensity, and dominance from those known from mature ecosystems. It is therefore crucial to understand these early phases of ecosystem development and to disentangle the increasingly complex interactions between the evolving terrestrial and aquatic, biotic, and abiotic compartments of the system. Long-term monitoring of initial ecosystems may provide important data and parameters on processes and the crucial role of spatial and temporal structures and patterns to solve these problems. Artificially created catchments could be a suitable tool to study these initial developments at the landscape scale under known, designed, and defined boundary conditions.}, language = {en} } @inproceedings{HinzGerwinSchaafetal., author = {Hinz, Christoph and Gerwin, Werner and Schaaf, Wolfgang and Elmer, Michael and Fl{\"u}hler, Hannes and Holl{\"a}nder, Hartmut M. and H{\"u}ttl, Reinhard F.}, title = {State transitions in the artificial catchment Huehnerwasser (Chicken Creek): Ecosystems development 8 years after initialization : abstract}, series = {Soil-mediated Drivers of Coupled Biogeochemical and Hydrological Processes across Scales, AGU Chapman Conference Biosphere II, Tucson, Arizona, USA, 21-24 October 2013}, booktitle = {Soil-mediated Drivers of Coupled Biogeochemical and Hydrological Processes across Scales, AGU Chapman Conference Biosphere II, Tucson, Arizona, USA, 21-24 October 2013}, pages = {S. 34}, language = {en} } @misc{SchaafElmerFischeretal., author = {Schaaf, Wolfgang and Elmer, Michael and Fischer, Anton and Gerwin, Werner and Nenov, Rossen and Pretzsch, Hans and Zaplata, Markus K.}, title = {Feedbacks between vegetation, surface structures and hydrology during initial development of the artificial catchment 'Chicken Creek'}, series = {Procedia Environmental Sciences}, volume = {19}, journal = {Procedia Environmental Sciences}, issn = {1878-0296}, doi = {10.1016/j.proenv.2013.06.010}, pages = {86 -- 95}, abstract = {Our investigations at the artificial catchment ´Chicken Creek´ in Lusatia/Germany aim to disentangle and understand the feedback mechanisms and interrelationships of processes and their co-development with spatial and temporal structures and patterns by studying this initial, probably less complex ecosystem. Intensive measurements were carried out in the catchment with regard to the development of surface structures, hydrological patterns, and vegetation dynamics. During the first seven years, considerable changes within the catchment were observed. Both internal and external factors could be identified as driving forces for the formation of structures and patterns in the artificial catchment. Initial structures formed by the construction process and initial substrate characteristics were decisive for the distribution and flow of water. External factors like episodic events triggered erosion and dissection during this initial phase, promoted by the low vegetation cover and the unconsolidated sandy substrate. The transformation of the initial geo-system into areas with evolving terrestrial or aquatic characteristics and from a very episodic to a more permanent stream network and discharge, together with the observed vegetation dynamics increased site diversity and heterogeneity with respect to water and nutrient availability and transformation processes compared to the more homogenous conditions at point zero. The processes and feedback mechanisms in the initial development of a new landscape may deviate in rates, intensity and dominance from those known from mature ecosystems. It is therefore crucial to understand these early phases of ecosystem development and to disentangle the increasingly complex interactions between the evolving terrestrial and aquatic, biotic and abiotic compartments of the system. Artificially created catchments could be a suitable tool to study these initial developments at the landscape scale under known, designed and defined boundary conditions.}, language = {en} } @misc{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas}, title = {Long-Term Release of Iron-Cyanide Complexes from the Soil of a Manufactured Gas Plant Site}, series = {Journal of Environmental Protection}, volume = {4}, journal = {Journal of Environmental Protection}, number = {11B}, issn = {2152-2219}, doi = {10.4236/jep.2013.411A2002}, pages = {8 -- 19}, abstract = {Iron-cyanide (Fe-CN) complexes have been detected at Manufactured Gas Plant sites (MGP) worldwide. The risk of groundwater contamination depends mainly on the dissolution of ferric ferrocyanide. In order to design effective reme- diation strategies, it is relevant to understand the contaminant's fate and transport in soil, and to quantify and mathe- matically model a release rate. The release of iron-cyanide complexes from four contaminated soils, originating from the former MGP in Cottbus, has been studied by using a column experiment. Results indicated that long-term cyanide (CN) release is governed by two phases: one readily dissolved and one strongly fixed. Different isotherm and kinetic equations were used to investigate the driving mechanisms for the ferric ferrocyanide release. Applying the isotherm equations assumed an approach by which two phases were separate in time, whereas the multiple first order equation considered simultaneous occurrence of both cyanide pools. Results indicated varying CN release rates according to the phase and soil. According to isotherm and kinetic models, the long-term iron cyanide release from the MGP soils is a complex phenomenon driven by various mechanisms parallely involving desorption, diffusion and transport processes. Phase I (rapid release) is presumably mainly constrained by the transport process of readily dissolved iron-cyanide complexes combined with desorption of CN bound to reactive heterogeneous surfaces that are in direct contact with the aqueous phase (outer-sphere complexation). Phase II (limited rate) is presumably driven by the diffusion controlled processes involving dissolution of precipitated ferric ferrocyanide from the mineral or inner-sphere complexation of fer- ricyanides. CN release rates in phase I and II were mainly influenced by the pH, organic matter (OM) and the total CN content. The cyanide release rates increased with increasing pH, decreased with low initial CN concentration and were retarded by the increase in OM content.}, language = {en} } @inproceedings{SutLohmannRepmannRaab, author = {Sut-Lohmann, Magdalena and Repmann, Frank and Raab, Thomas}, title = {Release of iron-cyanide complexes form contaminated soils - Batch and column experiments on substrates from Manufactured Gas Plant (MGP) site}, series = {European Geosciences Union General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, booktitle = {European Geosciences Union General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Soils of former Manufactured Gas Plants (MGPs) are often contaminated with iron-cyanide (Fe-CN) complexes that originate from gas purification process. Cyanide is a potentially toxic substance and its presence in soil and groundwater may cause risk for human health as well as for the environment. MGPs were commonly built on the city suburban areas, which have spread ever since. Nowadays, these sites are typically located in inner cities, causing environmental thread, due to the leaching of pollutants. More recently, columns and batch experiments have been used to study fate and mobility of contaminants is soil. The release of iron-cyanide complexes under unsaturated flow conditions was evaluated with eight columns of 30 cm length and a diameter of 5,4 cm. Cyanide concentrations in the collected leachates were measured with Flow Injection Analysis (FIA). Additionally pH, electrical conductivity (EC) and various ion concentrations were determined. In order to compare the release of Fe-CN complexes in saturated conditions a batch experiment was conducted, where in defined time intervals, 1 ml of the extract water phase was analyzed for CN concentration. Study revealed an analogous trend of cyanide release in both experiments indicating primarily the release of formerly dissolved phase (hexacyanoferrates) followed by continual dissolution of ferric ferrocyanide. We conclude that batch experiments, conducted prior to column analysis, can serve as preliminary prediction of the water soluble cyanide fraction under unsaturated conditions.}, language = {en} } @inproceedings{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas}, title = {Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil}, series = {European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, booktitle = {European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {In Germany, at more than 1000 sites, soil is polluted with an anthropogenic contaminant in form of iron-cyanide complexes. These contaminations are caused by former Manufactured Gas Plants (MGPs), where electricity for lighting was produced in the process of coal gasification. The production of manufactured gas was restrained in 1950, which caused cessation of MGPs. Our study describes the application of Polychromix Handheld Field Portable Near-Infrared (NIR) Analyzer to predict the cyanide concentrations in soil. In recent times, when the soil remediation is of major importance, there is a need to develop rapid and non-destructive methods for contaminant determination in the field. In situ analysis enables determination of 'hot spots', is cheap and time saving in comparison to laboratory methods. This paper presents a novel usage of NIR spectroscopy, where a calibration model was developed, using multivariate calibration algorithms, in order to determine NIR spectral response to the cyanide concentration in soil samples. As a control, the contaminant concentration was determined using conventional Flow Injection Analysis (FIA). The experiments revealed that portable near-infrared spectrometers could be a reliable device for identification of contamination 'hot spots', where cyanide concentration are higher than 2400 mg kg-1 in the field and >1750 mg kg-1 after sample preparation in the laboratory, but cannot replace traditional laboratory analyses due to high limits of detection.}, language = {en} } @incollection{HuettlFluehlerGerkeetal., author = {H{\"u}ttl, Reinhard F. and Fl{\"u}hler, Hannes and Gerke, Horst H. and Maurer, Thomas and Schneider, Anna}, title = {Project C5 - Development of a structure and process model}, series = {Structures and processes of the initial ecosystem development phase in an artificial water catchment (Final report CRC/TR 38)}, booktitle = {Structures and processes of the initial ecosystem development phase in an artificial water catchment (Final report CRC/TR 38)}, editor = {H{\"u}ttl, Reinhard F. and K{\"o}gel-Knabner, Ingrid and Schulin, Rainer and Gerwin, Werner}, publisher = {BTU, Forschungszentrum Landschaftsentwicklung und Bergbaulandschaften (FZLB)}, address = {Cottbus}, pages = {101 -- 110}, language = {en} }