@misc{IngenboschQuintDyllickBrenzingeretal., author = {Ingenbosch, Kim N. and Quint, Stephan and Dyllick-Brenzinger, Melanie and Wunschik, Dennis S. and Kiebist, Jan and S{\"u}ss, Philipp and Liebelt, Ute and Zuhse, Ralf and Menyes, Ulf and Scheibner, Katrin and Mayer, Christian and Opwis, Klaus and Gutmann, Jochen S. and Hoffmann-Jacobsen, Kerstin}, title = {Singlet oxygen generation by peroxidases and peroxygenases for chemo-enzymatic synthesis}, series = {ChemBioChem}, volume = {22}, journal = {ChemBioChem}, number = {2}, issn = {1439-7633}, doi = {10.1002/cbic.202000326}, pages = {398 -- 407}, abstract = {Singlet oxygen is a reactive oxygen species undesired in living cells but a rare and valuable reagent in chemical synthesis. We present a fluorescence spectroscopic analysis of the singlet-oxygen formation activity of commercial peroxidases and novel peroxygenases. Singlet-oxygen sensor green (SOSG) is used as fluorogenic singlet oxygen trap. Establishing a kinetic model for the reaction cascade to the fluorescent SOSG endoperoxide permits a kinetic analysis of enzymatic singlet-oxygen formation. All peroxidases and peroxygenases show singlet-oxygen formation. No singlet oxygen activity could be found for any catalase under investigation. Substrate inhibition is observed for all reactive enzymes. The commercial dye-decolorizing peroxidase industrially used for dairy bleaching shows the highest singlet-oxygen activity and the lowest inhibition. This enzyme was immobilized on a textile carrier and successfully applied for a chemical synthesis. Here, ascaridole was synthesized via enzymatically produced singlet oxygen.}, language = {en} } @book{AndersDonatDurkaetal., author = {Anders, Kenneth and Donat, Ralf and Durka, Walter and Elmer, Michael and Fischer, Lars and Gailing, Ludger and Hoffmann, Melanie and Hornemann, Gitte and H{\"u}ttl, Reinhard F. and Peschel, Tim and Rißmann, Cornelia and R{\"o}hring, Andreas and Siedschlag, Yvonne and Pilarski, Monika and Vetter, Andreas and Vorwald, J{\"o}rn and W{\"o}llecke, Jens and Wiegleb, Gerhard and Xylander, Willi E. R.}, title = {Neulandschafft - Leben in den Schlabendorfer Feldern - Natur und Mensch : eine Publikation der Landschaftswerkstatt Schlabendorfer Felder im Rahmen des Forschungsverbundes SUBICON}, editor = {Anders, Kenneth and Fischer, Lars and R{\"o}hring, Andreas and Peschel, Tim and Donat, Ralf}, publisher = {B{\"u}ro f{\"u}r Landschaftskommunikation}, address = {Bad Freienwalde}, pages = {120}, language = {de} } @book{HoffmannAndersFischeretal., author = {Hoffmann, Melanie and Anders, Kenneth and Fischer, Lars and B{\"o}llmann, J{\"o}rg and Br{\"u}ckner, Ardo and Brunk, Ingo and Donath, Helmut and Donat, Ralf and Elmer, Michael and G{\"u}th, Mareike and H{\"a}ußler, Robert and Mrzljak, Jadranka and Mudra, Dieter and M{\"u}ller, Markus and Peschel, Tim and Pilz, Wilfried and Sawade, Wolfgang and Schonert, P. and Siedschlag, Marina and Siedschlag, Yvonne and Wanner, Manfred and W{\"o}llecke, Jens}, title = {Kolonisten gesucht! Steckbriefe nat{\"u}rlicher und sozialer Besiedler der Bergbaufolgelandschaft Schlabendorfer Felder}, editor = {Hoffmann, Melanie and Anders, Kenneth and Fischer, Lars}, publisher = {B{\"u}ro f{\"u}r Landschaftskommunikation}, address = {Bad Freienwalde}, pages = {52}, language = {de} }