@misc{SchmidtHohmannNilgesetal., author = {Schmidt, Peer and Hohmann, Andrea and Nilges, Tom and K{\"o}pf, Marianne and Weihrich, Richard}, title = {Synthesis of Element Allotropes of Arsenic and Phosphorus by Application of Electromotive Series of Solids}, series = {Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie}, volume = {640}, journal = {Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie}, number = {11}, issn = {1521-3749}, doi = {10.1002/zaac.201490026}, pages = {2386}, abstract = {Calculation of electromotive series of solids allows easy prediction of reaction pathways[1]. Using the electromotive series of systems As-P-O and As-P-X (X = F, Cl, Br, I) the formation of element allotropes via the oxide and halide compounds in thermite type reactions can be deduced: phosphorous will reduce the arsenic oxides to elemental arsenic, forming grey or black allotrope, depending on reaction mixture composition.}, language = {en} }