@misc{SutLohmannKnoopRaab, author = {Sut-Lohmann, Magdalena and Knoop, Christine and Raab, Thomas}, title = {Effect of drying, composing and pelletizing of biowaste-based digestates on providing water soluble nutrients and stabilizing iron-cyanide (Fe-CN) complexes}, series = {EGU General Assembly 2020, Online | 4-8 May 2020}, journal = {EGU General Assembly 2020, Online | 4-8 May 2020}, doi = {10.5194/egusphere-egu2020-8013}, language = {en} } @misc{JonczakSutLohmannPollakovaetal., author = {Jonczak, Jerzy and Sut-Lohmann, Magdalena and Poll{\´a}kov{\´a}, Nora and Parzych, Agnieszka and Šimansk{\´y}, Vladim{\´i}r and Donovan, Sally and Medinski, Tetiana}, title = {Comparison of bioaccumulation potential of eleven pine species in low polluted ecosystem}, series = {EGU General Assembly 2020, Online | 4-8 May 2020}, journal = {EGU General Assembly 2020, Online | 4-8 May 2020}, doi = {10.5194/egusphere-egu2020-8746}, language = {en} } @misc{DietrichWilkinsonHirschetal., author = {Dietrich, Nils and Wilkinson, Daniel and Hirsch, Florian and Sut-Lohmann, Magdalena and Geschke, Antonia and Raab, Thomas}, title = {Microplastics and earthworms in soils: A case study on translocation, toxicity and fate}, series = {EGU General Assembly 2020}, journal = {EGU General Assembly 2020}, doi = {10.5194/egusphere-egu2020-7430}, language = {en} } @misc{KaestnerSutLohmannRaabetal., author = {Kaestner, Friederike and Sut-Lohmann, Magdalena and Raab, Thomas and Feilhauer, Hannes and Chabrillat, Sabine}, title = {Remediation-related monitoring of heavy metal concentration of contaminated Technosol using hyperspectral measurements}, series = {EGU General Assembly 2021}, journal = {EGU General Assembly 2021}, doi = {10.5194/egusphere-egu21-11479}, language = {en} } @misc{RamezanySutLohmannKlosetal., author = {Ramezany, Shaghayegh and Sut-Lohmann, Magdalena and Klos, Friederike and Bonhage, Alexander and Raab, Thomas}, title = {Using Modified Tessier Scheme to Metal Speciation in a Former Sewage Farm and interpretation of the sequential extraction by FTIR}, series = {EGU General Assembly 2021}, journal = {EGU General Assembly 2021}, doi = {10.5194/egusphere-egu21-6482}, language = {de} } @misc{SutLohmannRamezanyKlosetal., author = {Sut-Lohmann, Magdalena and Ramezany, Shaghayegh and Klos, Friederike and Raab, Thomas}, title = {Spatial and vertical determination of chosen potentially toxic metals and soil properties on a former sewage farm near Berlin}, series = {EGU General Assembly 2021}, journal = {EGU General Assembly 2021}, doi = {10.5194/egusphere-egu21-4220}, language = {en} } @misc{SutLohmannRamezanyKaestneretal., author = {Sut-Lohmann, Magdalena and Ramezany, Shaghayegh and K{\"a}stner, Friederike and Raab, Thomas}, title = {Feasibility of pXRF to evaluate chosen heavy metals in soil highly influenced by municipal waste disposal - a Former Sewage Farm Monitoring Study}, series = {Land Degradation \& Development}, volume = {33}, journal = {Land Degradation \& Development}, number = {3}, issn = {1099-145X}, doi = {10.1002/ldr.4147}, pages = {439 -- 451}, language = {en} } @misc{SutLohmannRamezanyKaestneretal., author = {Sut-Lohmann, Magdalena and Ramezany, Shaghayegh and K{\"a}stner, Friederike and Raab, Thomas and Heinrich, Martina and Grimm, Mark}, title = {Using modified Tessier sequential extraction to specify potentially toxic metals at a former sewage farm}, series = {Journal of Environmental Management}, volume = {304}, journal = {Journal of Environmental Management}, issn = {1095-8630}, doi = {10.1016/j.jenvman.2021.114229}, pages = {10}, language = {en} } @misc{KaestnerSutLohmannRamezanyetal., author = {K{\"a}stner, Friederike and Sut-Lohmann, Magdalena and Ramezany, Shaghayegh and Raab, Thomas and Feilhauer, Hannes and Chabrillat, Sabine}, title = {Estimating heavy metal concentrations in Technosols with reflectance spectroscopy}, series = {Geoderma}, volume = {406}, journal = {Geoderma}, issn = {0016-7061}, doi = {10.1016/j.geoderma.2021.115512}, language = {en} } @misc{MatvejevaSutLohmannDietrichetal., author = {Matvejeva, Agne and Sut-Lohmann, Magdalena and Dietrich, Nils and Heinrich, Martina and Raab, Thomas}, title = {Fiber hemp as a feasible crop for enhancing carbon sequestration and cultivation under water scarcity in sandy agricultural soils}, series = {EGU General Assembly 2022, Vienna, Austria, 23-27 May 2022}, journal = {EGU General Assembly 2022, Vienna, Austria, 23-27 May 2022}, doi = {10.5194/egusphere-egu22-2564}, abstract = {Extended dry periods and increasing soil degradation compel the conventional agriculture to shift towards the sustainable practices. Hemp (Cannabis Sativa L.) accounts for crops that require low agricultural inputs and has a high potential to improve soil health hence fertility. The rapid hemp growth, high biomass production and remarkably expanded rooting zone have the vast potential in carbon (C) sequestration and nitrogen (N) fixation. Hemp fibers in the European Union (EU) are commonly used for pulp and paper industry and isolation materials. The study aims to (i) analyze hemp feasibility to grow and contribute to C sequestration under the water scarce conditions in initially nutrient-poor arable sandy soil with high and low canopy densities, and (ii) assess the use of hemp residues like shives and leaves as soil amendments for oat and corn crops in order to increase soil water holding capacity and serve as a long-term nutrient supply. Hemp, oat and corn crops were grown in a greenhouse experiment under LED illumination and wind ventilation for 17 h per day until the harvest. Hemp fibers were obtained through decortication. The biomass of all crops, hemp roots separated into fine and main, soil prior and after the experiment, and soil amendments were investigated for the total C and N content with an ELEMENTAR Vario Max Cube. Also, the elemental analysis for Ca, Mg, K, Zn, Cu, Fe, Al, Na was performed using HNO3 and MP-AES analyses. Total dry root mass for oat and corn crops was measured. Additionally, the soil pH and electrical conductivity (EC) were determined. The results showed that water scarcity had hindered hemp height and biomass production. While under the water limited conditions, the low hemp canopy density had showed slightly advanced growth in comparison to the high canopy density. Furthermore, the results of oat and corn experiment indicated difference between the treatments, where the soil amendment from hemp leaves compared to hemp shives showed enhanced growth in both plant and root biomass}, language = {en} } @misc{SutLohmannMatvejevaDietrichetal., author = {Sut-Lohmann, Magdalena and Matvejeva, Agne and Dietrich, Nils and Heinrich, Martina and Raab, Thomas}, title = {Cultivation of fiber hemp using solid and liquid residues from municipal composting in a closed system}, series = {EGU General Assembly 2022, Vienna, Austria, 23-27 May 2022}, journal = {EGU General Assembly 2022, Vienna, Austria, 23-27 May 2022}, doi = {10.5194/egusphere-egu22-1681}, abstract = {Progressing degradation of agricultural soil demands a change to more sustainable cropping systems accounting for crops that can sustain the soil health. Hemp is known for the improvement of soil physical, chemical and biological properties. The objective of the research is to analyze the hemp plant capability to grow under nutrient poor soil conditions and dense canopy and to assess hemp's ability to uptake plant nutrients applied with/by soil amendments produced from biowaste. Additionally, the research aims to analyze how the hemp nutrition affects its morphogenesis, thus the fiber content. In the greenhouse set up, Cannabis Sativa L. was grown in sandy substrate, with limited water supply that corresponded to the common drought periods in Brandenburg (Germany) and with addition of soil amendments in form of pellets from organic waste (OW) digestives. The treatments included: 5 control pots, 10 pots with pellets (19 kg soil / 230 g pellets according to the allowed application of 13 t/ha) and 10 pots with 19 kg soil / 3 kg pellets. When needed, a universal liquid fertilizer was applied which contained water soluble minerals like N, P2O5 and K2O. After 92 days, the plants were harvested, dried and weighted. The root structure was examined visually. The stems were decorticated using BMS-FLAKSY® (Rossmanith GmbH) to analyze the fiber content. The Elementar vario MAX cube analyzer device was used to analyse C and N contents. The results showed that hemp could still flourish in water and nutrient limited environment. A deeper and denser rooting was observed in the treatments with pellets. It was observed that fine roots were encircled and attached to the pellets to access the nutrients stored there. The highest C:N ratio in soil and in leaves was found in treatments that contained the most pellets. The option to apply pellets produced from OW in larger quantities instead of a fertilizer application had a striking effect on hemp growth and biomass accumulation hence, increased dry matter amount and fiber yield.}, language = {en} } @misc{KaestnerSutLohmannGrimmetal., author = {K{\"a}stner, Friederike and Sut-Lohmann, Magdalena and Grimm, Mark and Feilhauer, Hannes and K{\"u}ster, Theres and Raab, Thomas}, title = {Identification of potential toxic elements (PTE) in Technosols and in the hyperaccumulator plant Brassica juncea with imaging spectroscopy}, series = {12th EARSeL Workshop on Imaging Spectroscopy}, journal = {12th EARSeL Workshop on Imaging Spectroscopy}, pages = {152}, abstract = {Vital, fertile soil is a limited resource and must be considered equal to air and water in its status as a protected good. In Europe, there are around 2.5 million potentially contaminated due to natural and anthropogenic activities. One third of these areas have been identified and 15\% of them have already been remediated. An efficient approach for remediation is phytoremediation, a cost-effective and ecosystem-friendly method compared to conventional methods. We showed that hyperaccumulator plants, which have a high tolerance to the accumulation of potentially toxic elements (PTE), are suitable for phytoremediation methods. Imaging spectroscopy allowed us to monitor and optimize the process of accumulation. Our study was conducted in two steps: First we analysed the potential of multivariate procedures using Partial Least Squares Regression (PLSR) and Random Forest Regression (RFR) to predict highly contaminated areas with an inhomogeneous distribution of PTE concentrations from image data. Therefore, we used contaminated soil samples analysed for heavy metal contents as training data. The fully-trained models assisted to monitor PTE contaminated areas during phytoremediation. In a second step, we investigated hyperaccumulator plants and their spectral fingerprints during PTE uptake to detect the highest possible amount of PTE the plant can tolerate. Soil samples were measured after different preparation steps ("oven-dried", "sieved", "ground", "Loss on Ignition (LOI)") with a HySpex VNIR-1600 and HySpex SWIR 320m-e hyperspectral sensor under laboratory conditions. The spectral range of both sensors covers 450 nm to 2500 nm with a spectral sampling interval of 3.7 nm for the VNIR sensor and 6.25 nm for the SWIR sensor. The resulting spectral library was used for the PLSR and RFR analysis. Considering the optimal coefficient of determination (R2), PLSR showed an improving performance and accuracy with increasing preparation steps: R2_Cr: 0.52-0.78; R2_Cu: 0.36-0.73; R2_Ni: 0.19-0.42 and R2_Zn: 0.41-0.74. In comparison, RFR showed a weaker estimation performance, even when using higher sample preparation levels (R2_Cr:0.36-0.62; R2_Cu: 0.17-0.72; R2_Ni: 0.20-0.35 and R2_Zn: 0.26-0.67). The results indicate that PLSR provides a more robust estimation than the user-friendly RFR method. Additionally, the PTE estimation performance in strong heterogeneous soil samples can be improved by pre-treatment of soil samples in the laboratory. Second, we cultivated Brassica juncea in a greenhouse and applied the plants with different controlled zinc, nickel and copper concentration levels (low, medium, high). Measurements with a HySpex VNIR-SWIR hyperspectral sensor (408-2500 nm) and a point spectrometer PSR+ from Spectral Evolution (350-2500 nm) were conducted in-situ and in the laboratory. A principal component analysis (PCA) was performed on reflectance spectra to identify and visualize spectral changes with increasing PTE uptake. In addition, different indices were calculated, such as Leaf Area Index (LAI) and Red-Edge Inflection Point (REIP). First results revealed changes at the chlorophyll feature between 500-600 nm and at the REIP position with increasing PTE concentration. Further spectral features and indices will be investigated to check hyperspectral responses of PTE concentration. With reflectance imaging we are already able to detect differences of the PTE accumulation within the hyperaccumulator plants.}, language = {en} } @misc{SutLohmannGrimmHeinrichetal., author = {Sut-Lohmann, Magdalena and Grimm, Mark and Heinrich, Martina and Baig, Sawdha and Raab, Thomas}, title = {Soil nitrogen pool and its fractions in German apple orchards under organic vs conventional management}, series = {EGU General Assembly 2023, Vienna, Austria, 24-28 Apr 2023}, journal = {EGU General Assembly 2023, Vienna, Austria, 24-28 Apr 2023}, doi = {10.5194/egusphere-egu23-3208}, pages = {1}, abstract = {Agriculture is a massive production with intensive practices, like large variety of agro-chemicals, heavy machinery etc., that support food security. However, recently more and more attention is given to food safety in relation to human, environment and soil health. An alternative strategy is organic agriculture that avoids the use of synthetic chemicals and maintain the sustainable food production. But organic farming cannot completely support the worlds foods demand, so adaptation is needed to reach a sustainable productivity while protecting the environment. Soil nitrogen (N) pool consists of inorganic and organic fractions. Inorganic and a part of labile organic N is a primary nutrient source for plants and microbes. Different nitrogen fractions play various roles in soil ecosystems and can be strongly influenced by the site management. Soil nitrogen transformations are directly relatable to plant health, thus strongly influence healthy functioning of soil ecosystem. Knowledge about the soil nitrogen pools is necessary to assess the proper and sustainable fertilization approaches under various management practices. To evaluate various N fractions, fresh soil samples were sampled (20 cm depth, row and near tree) at 8 conventional and 8 organic apple farms (Germany: states of Brandenburg, Saxsony and Saxony-Anhalt), with various age, locations and management practices. Soil samples were analyzed using CNS, Kjeldhal digestion, spectrophotometer and chloroform fumigation. The aim of this study is to compare the total and labile (particulate organic, microbial biomass and water extractable organic) N fractions in soil samples considering various site management approaches, topography and climate.}, language = {de} } @misc{GrimmSutLohmannRaabetal., author = {Grimm, Mark and Sut-Lohmann, Magdalena and Raab, Thomas and Heinrich, Martina}, title = {Integrated analysis of Multifunctional Fruit production landscapes to promote ecosystem services and sustainable land-use under climate change (MultiFruit): Approaches and first results of soil sampling campaign}, series = {EGU General Assembly 2023, Vienna, Austria, 24-28 Apr 2023}, journal = {EGU General Assembly 2023, Vienna, Austria, 24-28 Apr 2023}, doi = {10.5194/egusphere-egu23-12714}, pages = {2}, abstract = {Beginning in 2020 the research of the MultiFruit cluster seeks to optimize food production and the provision of ecosystem services in multifunctional landscapes. Joining agricultural production with the provision of ecosystem services and the preservation of biological diversity, the outcomes of this project aim to provide comprehensive findings to farmers, and the agricultural community as a whole, that are also applicable in the face of climate change. Active apple orchards located in greater Brandenburg, Germany of both organic and conventional management practices have been selected as the sites of research. The present state of organic apple orchards in Germany can best be described as organic "conventionalization"; high yielding orchards with little to no plant diversity, with the major differences being the substitution of synthetic fertilizers, pesticides, herbicides, and fungicides with organic alternatives certified by the Federal Office of Consumer Protection and Food Safety (Bundesamt f{\"u}r Verbraucherschutz und Lebensmittelsicherheit). The project implements an interdisciplinary approach, with researchers of ecology, economics, soil and microbial sciences. The ecological subproject is investigating how local management measures and the surrounding landscapes affect natural pest control by beneficial insects. The soil group are investigating the toxicological and soil health impacts of conventional and organic practices through analysis of both plant and soil material collected from the orchards. Microbial studies seek to provide information on the microorganisms that promote the growth, health, and performance of fruit trees. The economic studies aim to assess the costs and benefits of management measures and resulting pest control services for fruit growers and society as a whole. The overall expected outcome of this cluster is to maximize ecosystem services provided by the orchards while optimizing yield and maintaining soil and orchard health. Here we show the preliminary results of the 2021 field campaign related to the soil group. The processed plant and soil material was analyzed at our laboratory and total elemental concentration of all constituents was determined using Microwave assisted MP-AES for select metals and cations (Zn, Cu, Fe, Al, Mg, Ca, K). These results, in conjunction with measured soil properties (pH, EC, Scheibler carbonate measurement, Total N, Total C) aid in the effort to determine the effects of the various management practices on the soil health and the mobility and translocation of metals and cations within the plant tissues.}, language = {en} } @misc{SutLohmannGrimmKaestneretal., author = {Sut-Lohmann, Magdalena and Grimm, Mark and K{\"a}stner, Friederike and Raab, Thomas}, title = {Brassica juncea as a Feasible Hyperaccumulator of chosen potentially toxic metals under extreme environmental conditions}, series = {International Journal of Environmental Research}, volume = {17}, journal = {International Journal of Environmental Research}, number = {3}, issn = {1735-6865}, doi = {10.1007/s41742-023-00528-8}, language = {de} } @misc{SutLohmannJonczakRaab, author = {Sut-Lohmann, Magdalena and Jonczak, Jerzy and Raab, Thomas}, title = {Optimizing pyrolysis conditions of biochars derived from byproducts of forest and food industry for soil amendments}, series = {Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, Einladung und Programm Halle (Saale), 2.-8. September 2023}, journal = {Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, Einladung und Programm Halle (Saale), 2.-8. September 2023}, language = {en} } @misc{GrimmSutLohmannRaab, author = {Grimm, Mark and Sut-Lohmann, Magdalena and Raab, Thomas}, title = {Impacts of Farming Practices on Potentially Toxic Elements (PTEs) and micronutrients in German Apple Orchards}, series = {Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, Einladung und Programm Halle (Saale), 2.-8. September 2023}, journal = {Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, Einladung und Programm Halle (Saale), 2.-8. September 2023}, pages = {78}, language = {en} } @misc{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas and Dimitrova, Tsvetelina}, title = {Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil}, series = {Water, Air and Soil Pollution}, volume = {223}, journal = {Water, Air and Soil Pollution}, number = {8}, issn = {1573-2932}, doi = {10.1007/s11270-012-1298-y}, pages = {5495 -- 5504}, abstract = {Vicinities of manufactured gas plants were often contaminated with solid iron-cyanide complexes as a result of the coal gasification process. During the remediation of affected soils, knowledge about contaminant concentrations is crucial, but laboratory methods are often expensive and time consuming. Rapid and non-destructive field methods for contaminant determination permit an analysis of large sample numbers and hence, facilitate identification of 'hot spots' of contamination. Diffuse near infrared reflectance spectroscopy has proven to be a reliable analytical tool in soil investigation. In order to determine the feasibility of a Polychromix Handheld Field Portable Near-Infrared Analyzer (FP NIR), various sample preparation methods were examined, including homogenizing, sieving, drying, and grinding. Partial least squares calibration models were developed to determine near infrared (NIR) spectral responses to the cyanide concentration in the soil samples. As a control, the contaminant concentration was determined using conventional flow injection analysis. The experiments revealed that portable near-infrared spectrometers could be a reliable device for detecting cyanide concentrations >2,400 mgkg-1 in the field and >1,750 mgkg-1 after sample preparation in the laboratory.We found that portable NIR spectrometry cannot replace traditional laboratory analyses due to high limits of detection, but that it could be used for identification of contamination 'hot spots'.}, language = {en} } @misc{SutLohmannRepmannRaab, author = {Sut-Lohmann, Magdalena and Repmann, Frank and Raab, Thomas}, title = {Stability of Prussian Blue in Soils of a Former Manufactured Gas Plant Site}, series = {Soil and Sediment Contamination}, volume = {23}, journal = {Soil and Sediment Contamination}, number = {5}, issn = {1549-7887}, doi = {10.1080/15320383.2014.839626}, pages = {504 -- 522}, abstract = {Soil contamination with iron-cyanide complexes is a common problem at former manufactured gas plant (MGP) sites. Dissolution of the cyanide, from Prussian Blue (ferric ferrocyanide), creates an environmental hazard, whereas the risk of groundwater contamination depends on the stability of dissolved iron-cyanide complexes. Lack of a standard leaching method to determine the water-soluble (plant-available) cyanide fraction generates potential limitations for implementing remediation strategies like phytoremediation. Applicability of neutral solution extraction to determine the water-soluble cyanide fraction and the stability of Prussian Blue in surface and near-surface soils of an MGP site in Cottbus, undersaturated and unsaturated water conditions, was studied in column leaching and batch extraction experiments. MGP soils used in the long-term tests varied according to the pH (5.0-7.7) and the total cyanide content (40-1718 mg kg-1). Column leaching, after four months of percolation, still yielded effluent concentrations exceeding the German drinking water limit (> 50 μg L-1) and the solubility of Prussian Blue reported in the literature (< 1 mg L-1) from both alkaline and acidic soils. Long-term (1344 h) extraction of MGP soils with distilled water was sufficient to dissolve 97\% of the total cyanide from the slightly alkaline soils and up to 78\% from the acidic soils. Both experiments revealed that dissolution of ferric ferrocyanide under circum-neutral pH and oxic water conditions is a function of time, where the released amount is dependent on the soil pH and total cyanide content. Unexpectedly high and continuous solubility of Prussian Blue, both in acidic and slightly alkaline MGP soils, implies the need to introduce an additional cyanide fraction ("readily soluble fraction") to improve and specify cyanide leaching methods. Long-term extraction of cyanide-contaminated soil in neutral solution seems to be a promising approach to evaluate the potential hazard of groundwater pollution at the MGP sites.}, language = {en} } @inproceedings{SutLohmannBoldtBurischRaab, author = {Sut-Lohmann, Magdalena and Boldt-Burisch, Katja and Raab, Thomas}, title = {Effect of ryegrass (Lolium perenne L.) roots inoculation using different arbuscular mycorrhizal fungi (AMF) species on sorption of iron-cyanide (Fe-CN) complexes}, series = {European Geosciences Union, General Assembly 2016, Vienna, Austria, 17 April - 22 May 2016}, booktitle = {European Geosciences Union, General Assembly 2016, Vienna, Austria, 17 April - 22 May 2016}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Soils and groundwater on sites of the former Manufactured Gas Plants (MGPs) are contaminated with various complex iron-cyanides (Fe-CN). Phytoremediation is a promising tool in stabilization and remediation of Fe-CN affected soils, however, it can be a challenging task due to extreme adverse and toxic conditions. Phytoremediation may be enhanced via rhizosphere microbial activity, which can cooperate on the degradation, transformation and uptake of the contaminants. Recently, increasing number of scientist reports improved plants performance in the removal of toxic compounds with the support of arbuscular mycorrhizae fungi (AMF). Series of batch experiments using potassium hexacyanoferrate (II) solutions, in varying concentrations, were used to study the effect of ryegrass roots (Lolium perenne L.) inoculation with Rhizophagus irregularis and a mixture of Rhizophagus irregularis, Funneliformis mosseae, Rhizophagus aggregatus, and Claroideoglomus etunicatum on Fe-CN sorption. Results indicated significantly higher colonization of R. irregularis than for the mixture of AMF species on ryegrass roots. Sorption experiments revealed significantly higher reduction of total CN and free CN content in the mycorrhizal roots, indicating greater cyanide decrease in the treatment inoculated with R. irregularis. Our study indicates contribution of AM fungi in phytoremediation of Fe-CN contaminated soil.}, language = {en} } @misc{SutLohmannRepmannRaab, author = {Sut-Lohmann, Magdalena and Repmann, Frank and Raab, Thomas}, title = {Retardation of iron-cyanide complexes in the soil of a former manufactured gas plant site}, series = {Journal of Environmental Science and Health, Part A}, volume = {50}, journal = {Journal of Environmental Science and Health, Part A}, number = {3}, issn = {1532-4117}, doi = {10.1080/10934529.2015.981116}, pages = {282 -- 291}, abstract = {The soil in the vicinities of former Manufactured Gas Plant (MGP) sites is commonly contaminated with iron-cyanide complexes (ferric ferrocyanide). The phenomenon of cyanide mobility in soil, according to the literature, is mainly governed by the dissolution and precipitation of ferric ferrocyanide, which is only slightly soluble (<1 mg L!'1) under acidic conditions. In this paper, retention properties of the sandy loam soil and the potential vertical movement of the solid iron-cyanide complexes, co-existing with the dissolution, sorption and precipitation reactions were investigated. Preliminary research conducted on a former MGP site implied colloidal transport of ferric ferricyanide from the initial deposition in the wastes layer towards the sandy loam material (secondary accumulation), which possibly retarded the mobility of cyanide (CN). A series of batch and column experiments were applied in order to investigate the retardation of iron-cyanide complexes by the sandy loam soil. Batch experiments revealed that in circumneutral pH conditions sandy loam material decreases the potassium ferro- and ferricyanide concentration. In column experiments a minor reduction in CN concentration was observed prior to addition of iron sulfide (FeS) layer, which induced the formation of the Prussian blue colloids in circumneutral pH conditions. Precipitated solid iron-cyanide complexes were mechanically filtered by the coherent structure of the investigated soil. Additionally, the reduction of the CN concentration of the percolation solutions by the sandy loam soil was presumably induced due to the formation of potassium manganese iron-cyanide (K2Mn[Fe(CN)6]).}, language = {en} } @misc{SutLohmannBoldtBurischRaab, author = {Sut-Lohmann, Magdalena and Boldt-Burisch, Katja and Raab, Thomas}, title = {Possible evidence for contribution of arbuscular mycorrhizal fungi (AMF) in phytoremediation of iron-cyanide (Fe-CN) complexes}, series = {Ecotoxicology}, volume = {25}, journal = {Ecotoxicology}, number = {6}, issn = {1573-3017}, doi = {10.1007/s10646-016-1678-y}, pages = {1260 -- 1269}, abstract = {Arbuscular mycorrhizal fungi (AMF) are integral functioning parts of plant root systems and are widely recognized for enhancing contaminants uptake and metabolism on severely disturbed sites. However, the patterns of their influence on the phytoremediation of iron-cyanide (Fe-CN) complexes are unknown. Fe-CN complexes are of great common interest, as iron is one of the most abundant element in soil and water. Effect of ryegrass (Lolium perenne L.) roots inoculation, using mycorrhizal fungi (Rhizophagus irregularis and a mixture of R. irregularis, Funneliformis mosseae, Rhizophagus aggregatus, and Claroideoglomus etunicatum), on iron-cyanide sorption was studied. Results indicated significantly higher colonization of R. irregularis than the mixture of AMF species on ryegrass roots. Series of batch experiments using potassium hexacyanoferrate (II) solutions, in varying concentrations revealed significantly higher reduction of total CN and free CN content in the mycorrhizal roots, indicating greater cyanide decrease in the treatment inoculated with R. irregularis. Our study is a first indication of the possible positive contribution of AM fungi on the phytoremediation of iron-cyanide complexes.}, language = {en} } @inproceedings{SutLohmannBoldtBurischRaab, author = {Sut-Lohmann, Magdalena and Boldt-Burisch, Katja and Raab, Thomas}, title = {Influence of Arbuscular Mycorrhizal Fungus (AMF) on degradation of iron-cyanide complexes}, series = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, booktitle = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{SutLohmannRepmannRaab, author = {Sut-Lohmann, Magdalena and Repmann, Frank and Raab, Thomas}, title = {Vertical movement of iron-cyanide complexes in soils of a former Manufactured Gas Plant site}, series = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, booktitle = {European Geosciences Union, General Assembly 2015, Vienna, Austria, 13 April - 17 May 2015}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas}, title = {Long-Term Release of Iron-Cyanide Complexes from the Soil of a Manufactured Gas Plant Site}, series = {Journal of Environmental Protection}, volume = {4}, journal = {Journal of Environmental Protection}, number = {11B}, issn = {2152-2219}, doi = {10.4236/jep.2013.411A2002}, pages = {8 -- 19}, abstract = {Iron-cyanide (Fe-CN) complexes have been detected at Manufactured Gas Plant sites (MGP) worldwide. The risk of groundwater contamination depends mainly on the dissolution of ferric ferrocyanide. In order to design effective reme- diation strategies, it is relevant to understand the contaminant's fate and transport in soil, and to quantify and mathe- matically model a release rate. The release of iron-cyanide complexes from four contaminated soils, originating from the former MGP in Cottbus, has been studied by using a column experiment. Results indicated that long-term cyanide (CN) release is governed by two phases: one readily dissolved and one strongly fixed. Different isotherm and kinetic equations were used to investigate the driving mechanisms for the ferric ferrocyanide release. Applying the isotherm equations assumed an approach by which two phases were separate in time, whereas the multiple first order equation considered simultaneous occurrence of both cyanide pools. Results indicated varying CN release rates according to the phase and soil. According to isotherm and kinetic models, the long-term iron cyanide release from the MGP soils is a complex phenomenon driven by various mechanisms parallely involving desorption, diffusion and transport processes. Phase I (rapid release) is presumably mainly constrained by the transport process of readily dissolved iron-cyanide complexes combined with desorption of CN bound to reactive heterogeneous surfaces that are in direct contact with the aqueous phase (outer-sphere complexation). Phase II (limited rate) is presumably driven by the diffusion controlled processes involving dissolution of precipitated ferric ferrocyanide from the mineral or inner-sphere complexation of fer- ricyanides. CN release rates in phase I and II were mainly influenced by the pH, organic matter (OM) and the total CN content. The cyanide release rates increased with increasing pH, decreased with low initial CN concentration and were retarded by the increase in OM content.}, language = {en} } @inproceedings{SutLohmannRepmannRaab, author = {Sut-Lohmann, Magdalena and Repmann, Frank and Raab, Thomas}, title = {Release of iron-cyanide complexes form contaminated soils - Batch and column experiments on substrates from Manufactured Gas Plant (MGP) site}, series = {European Geosciences Union General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, booktitle = {European Geosciences Union General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Soils of former Manufactured Gas Plants (MGPs) are often contaminated with iron-cyanide (Fe-CN) complexes that originate from gas purification process. Cyanide is a potentially toxic substance and its presence in soil and groundwater may cause risk for human health as well as for the environment. MGPs were commonly built on the city suburban areas, which have spread ever since. Nowadays, these sites are typically located in inner cities, causing environmental thread, due to the leaching of pollutants. More recently, columns and batch experiments have been used to study fate and mobility of contaminants is soil. The release of iron-cyanide complexes under unsaturated flow conditions was evaluated with eight columns of 30 cm length and a diameter of 5,4 cm. Cyanide concentrations in the collected leachates were measured with Flow Injection Analysis (FIA). Additionally pH, electrical conductivity (EC) and various ion concentrations were determined. In order to compare the release of Fe-CN complexes in saturated conditions a batch experiment was conducted, where in defined time intervals, 1 ml of the extract water phase was analyzed for CN concentration. Study revealed an analogous trend of cyanide release in both experiments indicating primarily the release of formerly dissolved phase (hexacyanoferrates) followed by continual dissolution of ferric ferrocyanide. We conclude that batch experiments, conducted prior to column analysis, can serve as preliminary prediction of the water soluble cyanide fraction under unsaturated conditions.}, language = {en} } @inproceedings{SutLohmannFischerRepmannetal., author = {Sut-Lohmann, Magdalena and Fischer, Thomas and Repmann, Frank and Raab, Thomas}, title = {Feasibility of field portable near infrared (NIR) spectroscopy to determine cyanide concentrations in soil}, series = {European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, booktitle = {European Geosciences Union, General Assembly 2013, Vienna, Austria, 07 - 12 April 2013}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {In Germany, at more than 1000 sites, soil is polluted with an anthropogenic contaminant in form of iron-cyanide complexes. These contaminations are caused by former Manufactured Gas Plants (MGPs), where electricity for lighting was produced in the process of coal gasification. The production of manufactured gas was restrained in 1950, which caused cessation of MGPs. Our study describes the application of Polychromix Handheld Field Portable Near-Infrared (NIR) Analyzer to predict the cyanide concentrations in soil. In recent times, when the soil remediation is of major importance, there is a need to develop rapid and non-destructive methods for contaminant determination in the field. In situ analysis enables determination of 'hot spots', is cheap and time saving in comparison to laboratory methods. This paper presents a novel usage of NIR spectroscopy, where a calibration model was developed, using multivariate calibration algorithms, in order to determine NIR spectral response to the cyanide concentration in soil samples. As a control, the contaminant concentration was determined using conventional Flow Injection Analysis (FIA). The experiments revealed that portable near-infrared spectrometers could be a reliable device for identification of contamination 'hot spots', where cyanide concentration are higher than 2400 mg kg-1 in the field and >1750 mg kg-1 after sample preparation in the laboratory, but cannot replace traditional laboratory analyses due to high limits of detection.}, language = {en} } @misc{MatvejevaSutLohmannRaabetal., author = {Matvejeva, Agne and Sut-Lohmann, Magdalena and Raab, Thomas and Heinrich, Martina}, title = {Assessing the possibility to cultivate industrial hemp (Cannabis sativa L.) in sandy agricultural soils of Brandenburg under water scarcity and nutrient deficiency}, series = {International journal of environmental research}, volume = {20}, journal = {International journal of environmental research}, number = {1}, publisher = {Springer Science and Business Media LLC}, address = {Cham}, issn = {1735-6865}, doi = {10.1007/s41742-025-01038-5}, pages = {1 -- 13}, abstract = {Industrial fiber hemp (Cannabis sativa L.) is an annual crop that requires minimal agricultural inputs and has a high potential to improve soil organic matter (SOM) accumulation in sandy soils, including soil fertility and yields. Hemp cultivation, due to rapid growth and high biomass production, in addition to its deep-seated and entrenched roots, has vast potential in carbon (C) sequestration and nitrogen (N) accumulation. The research aims to analyse industrial hemp species Santhica 27 feasibility for fiber cultivation and biomass production in water-scarce and nutrient-deficient sandy soils of Brandenburg. The impact of high (142 plants·m- 2) and low (71 plants·m- 2) planting densities on hemp´s morphological development and productivity, expressed as yields, is also assessed. The results showed that the dry condition with a water deficit of 168.9 mm during the growing period was the main factor significantly impeding hemp`s morphological development and fiber yields. Control treatments with the precipitation sum of 242 mm planted in a lower planting density had on average, significantly taller plants of 122 cm with greater total biomass yield of 3.74 t·ha- 1 dry weight compared to simulated water-scarce dry treatments, with the lowest plant height and total biomass of 69 cm and 1.91 t·ha- 1, respectively, when planted in high density. Although the N content in the original sandy soil was below 1 g·kg- 1, the dry environmental conditions had prompted N accumulation up to 35 N g·kg- 1 in hemp biomass, 18 N g·kg- 1 in lateral roots, and 13 N g·kg- 1 in tap roots. High calcium (Ca) content was found in hemp biomass and lateral roots, whereas potassium (K) content was greater in tap roots. The results suggest that a lower hemp planting density for hemp cultivation should be considered in a water-scarce and nutrient-deficient environment. Moreover, the elemental analysis showed that hemp parts contain considerable amounts of macronutrients, which could be of great importance to the sandy soil´s total nutrient-pool enrichment.}, language = {en} }