@inproceedings{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {Soil formation on Late Quaternary sediments in the Central Pyrenees (Spain)}, series = {Landscapes and soils through time, proceedings, Hohenheim, July 28th - August 01th, 2011}, booktitle = {Landscapes and soils through time, proceedings, Hohenheim, July 28th - August 01th, 2011}, editor = {Sauer, Daniela and Jahn, Reinhold and Stahr, Karl}, address = {Hohenheim}, pages = {4 -- 5}, language = {en} } @inproceedings{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {Distribution, formation and chronology of Late Quaternary sediments in the Central Spanish Pyrenees}, series = {8th International Conference (IAG) on Geomorphology, IAG, Paris, 27 - 31 August 2013, abstract volume}, booktitle = {8th International Conference (IAG) on Geomorphology, IAG, Paris, 27 - 31 August 2013, abstract volume}, publisher = {International Association of Geomorphologists}, address = {Paris}, pages = {S. 342}, language = {en} } @inproceedings{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {Micromorphology and macrofabrics of Late Quaternary sediments in the Aragonese Pyrenees, Spain}, series = {8th International Conference (IAG) on Geomorphology, IAG, Paris, 27 - 31 August 2013, abstract volume}, booktitle = {8th International Conference (IAG) on Geomorphology, IAG, Paris, 27 - 31 August 2013, abstract volume}, publisher = {International Association of Geomorphologists}, address = {Paris}, pages = {S. 1018}, abstract = {Within the scope of the research project Post-LGM pedogenesis and geomorphodynamics in the Aragonese Pyrenees we used a combination of field and laboratory methods to differentiate and classify Late Quaternary sediments. Our analyses indicate no post sedimentary erosion of the LGM lateral moraines in the Aragon and Gallego valley. Precipitation of calcium carbonate led to the fixation of the diamictons and thus stabilized the glacial landforms. Clasts in the glacial sediments are orientated parallel to the Pleistocene glacial flow direction and therefore underpin the stability of the glacial deposits during paraglacial times. Grain size analyses and OSL ages indicate the covering of glacial sediments by an eolian deposit before the onset of the Holocene.}, language = {en} } @inproceedings{HirschRaabSchneideretal., author = {Hirsch, Florian and Raab, Thomas and Schneider, Anna and Wechler, Klaus-Peter}, title = {Late Holocene eolian fossilization of Podzols in Northeastern Germany}, series = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {The North European lowland has been formed by glacial and periglacial processes in the Late Pleistocene. Multiple reshaping since the Late Glacial considerably changed the landscape up to and including especially historic times. Sediment sequences and (fossilized) soils can improve our understanding of Late Quaternary landscape development, but mapping of buried soils and surfaces is often limited to single outcrops. Ongoing archaeological rescue excavations in the pre-field of the open-cast mine Cottbus-Nord (northeastern Germany) with dense excavation trenches in an about 10 ha dune and drift sand area reveal multilayered sediment sequences with fossilized soils and sediments from the Late Pleistocene to the Late Holocene. Archaeological findings ranging from Mesolithic flint stones to an about 200 year old ceramics in eolian sediments covering plow horizons and wheel tracks suggest that eolian relocation of sandy material was intensive about 200 years ago. Still unpublished OSL dating underline the intense eolian activity. Recent studies showed that between the 15Th to the 19Th century an iron smelter 5 km to the west of our study site was supplied with charcoal, which was produced in a forest 5 km east to our study site. Our current findings about Late Holocene eolian activity raise the question if this eolian reshaping of the landscape is connected with the operation of the iron smelter either directly by transport or bog iron ore winning or indirectly by population pressure caused by the prospering iron smelter. Our ongoing research indicates, that already for historic land-use off-site effects causing further landscape changes have to be considered.}, language = {en} } @inproceedings{RaabHirschOuimetetal., author = {Raab, Thomas and Hirsch, Florian and Ouimet, William and Dethier, David}, title = {Soil stratigraphy of charcoal kiln remains (CKR) in the Litchfield Hills, CT, USA}, series = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Charcoal kiln relicts (CKRs) are small anthropogenic landforms that are often found in historic mining areas. CKRs have not been a big research topic yet but mainly were studied as by-products of archaeological excavations. In the last years newly available and very accurate Digital Elevation Models (DEMs) based on high-resolution Airborne Laser Scanning (ALS) data have been used to identify these archaeological remains. In addition, findings of several thousands CKRs in the North German Lowland have increased the awareness that historical charcoal production may significantly contribute to Late Holocene landscape change. Besides the archaeological aspect of CKRs, potential impacts of charcoal burning on the ecology of modern soil landscapes and ecosystem processes must be considered. A relatively high density of CKRs is found in the Litchfield Hills nearby the town of West Cornwall, Litchfield County, CT, USA. The CKRs are especially well preserved on slopes of the tributary valleys of the Housatonic River and form little, circular ramparts with diameters normally less than ten meters. First, rough field surveys in Litchfield County in spring 2015 have suggested differences between soils inside and outside the CKR. Soils on the CKR seem to have relatively deep humus-rich and charcoal containing topsoils whereas the topsoils outside the CKR appear typically thinner and less rich in humus. More thorough investigations have been started in autumn 2015 to prove the hypothesis that properties, distribution and development of soils are controlled by archaeological remains of historical charcoal burning. We present preliminary results from our field studies conducted in October 2015. The stratigraphy and the extent of the 26 CKRs were studied using a sedimentological-pedological approach by coring and trenching. Our results indicate that in Litchfield County the CKRs were used twice and in quick succession. Before the second reuse, the rim of the platform was stabilized with boulders. The black topsoils on the CKRs contain residual charcoal and the topsoils are thicker compared to the soil sequences outside of the CKRs.}, language = {en} } @inproceedings{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {Missing evidence for the LGM-asynchronity in the Central Spanish Pyrenees in geomorphological, sedimentological and pedological archives}, series = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2016, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {According to the state of knowledge, the glacial advances in the Eastern Pyrenees were synchronous with the global LGM during the Late Pleistocene (MIS 2), but the glacial advances in the Central Spanish Pyrenees at MIS 3 were asynchron with the global LGM. Whereas in the Eastern Pyrenees the glacial advances are dated in several well agreeing studies by surface exposure dating of boulders from lateral or terminal moraines, the asynchronity of the Central Spanish Pyrenees was postulated mainly by OSL dating on glacial and fluvial sediments and on radiocarbon dating of pollen from lacustrine deposits. The time difference of about 15 ka raises the question if this is a result of (local) climate factors or owed to failures caused by using several dating techniques on different archives. Anyway, if this time lag is correct, post-LGM formation of soils and sediments from the Late Pleistocene should be different between the Eastern Pyrenees and the Central Spanish Pyrenees. We therefore applied a combined approach of geomorphological, sedimentological and pedological investigations to reconstruct the Late Quaternary landscape development in the Aragon- and Gallego Valley of the Central Spanish Pyrenees. Our study reveals that in both valleys the Pre-Holocene geomorphodynamics on the lateglacial deposits show clear analogies with findings from Pleistocene periglacial landscapes in Central Europe. For MIS 4 and early MIS 3 periglacial processes are proven by loess deposition and formation of solifluction sediments. The glacial sediments, which were dated in earlier studies into mid MIS 3 and counted so far as prove for the asynchronous LGM of the Central Spanish Pyrenees, are covered by periglacial deposits of lateglacial age (14 ka to 11 ka). Surprisingly neither the glacial sediments have pedogenic features that indicate lateglacial soil development, nor do the periglacial deposits show indications for lateglacial soil erosion. Therefore we conclude that soil formation began after the sedimentation of the periglacial deposits, either implying a striking timeframe of more than 15 ka with a stable landscape without any pedogenesis, or the untenability of the MIS 3 age of the glacial sediments. Because we can clearly differentiate further phases of geomorphodynamics during the Holocene with truncated soil profiles and the correlate sediments of soil erosion next to undisturbed soils in periglacial sediments with a lateglacial age, we challenge the thesis of an asynchronous LGM in the Central Spanish Pyrenees and advocate a synchronous LGM in the Gallego- and Aragon valley analog to the Eastern Pyrenees.}, language = {en} } @misc{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {Chronology of Late Quaternary sediments in the Aragonese Pyrenees}, series = {Quaternary International}, volume = {279-280}, journal = {Quaternary International}, doi = {10.1016/j.quaint.2012.08.371}, pages = {S. 202}, abstract = {The Spanish Pyrenees are a type region for Quaternary glaciations. Although the history of glacial research dates back until the first fieldtrips of Charpentier in 1841 and Penck in 1883, the maximum extent of Pleistocene glaciers and the exact chronology is still discussed. Whereas some authors suggest a last glacial maximum (LGM) synchronous to the European Alps, there are also several authors preferring a much earlier Pyrenean LGM. The differing ages for the LGM research using absolute chronological methods reveal the need for a clear stratigraphical and sedimentological approach prior to chronological sampling on Quaternary sediments. Within the scope of the research project post-LGM pedogenesis and geomorphodynamics in the Aragonese Pyrenees (Spain) funded by the DFG (Az RA 931/3-1) Quaternary sediments are differentiated by a combination of multiple field and laboratory methods. This identification of the sediments, combined with the stratigraphic approach forms the basis for the dating of the sediment facies and therefore the prevailing climate conditions at the time of the sedimentation. The studies are mainly conducted in the Aragon- and Gallego Valley, which are both situated in the Aragonese Pyrenees (Spain). We use optically stimulated luminescence (OSL) to date the uppermost unit of the periglacial slope deposits which typically cover glacial sediments in most parts of the study area. There is clear evidence that the glacial and periglacial sediments are partly eroded due to human impact. First OSL and 14C dating reveal relatively young ages for this phase of soil erosion and redepostion on the slopes (approximately 300 a BP).}, language = {en} } @inproceedings{HirschNicolaySchneideretal., author = {Hirsch, Florian and Nicolay, Alexander and Schneider, Anna and Błaszkiewicz, Mirosław and Kordowski, Jarosław and Noryskiewicz, Agnieszka M. and Tyszkowski, Sebastian and Raab, Alexandra and Raab, Thomas}, title = {Late Quaternary soil genesis and geomorphodynamics in Northern Poland}, series = {2nd Annual ICLEA Workshop 2013, Dynamics of climate and landscape evolution of cultural landscapes in the Northern Central European Lowlands since the last ice age, Abstract volume \& Excursion guide}, booktitle = {2nd Annual ICLEA Workshop 2013, Dynamics of climate and landscape evolution of cultural landscapes in the Northern Central European Lowlands since the last ice age, Abstract volume \& Excursion guide}, publisher = {Deutsches GeoForschungsZentrum GFZ}, address = {Potsdam}, doi = {10.2312/GFZ.b103-13047}, pages = {S. 43}, language = {en} } @inproceedings{BłaszkiewiczBrademannBraueretal., author = {Błaszkiewicz, Mirosław and Brademann, Brian and Brauer, Achim and Brykała, Dariusz and Deg{\´o}rski, Marek and Froehlich, Wojciech and Gierszewski, Piotr and Hirsch, Florian and Kaczmarek, Halina and Kordowski, Jarosław and Kramkowski, Mateusz and Krzymińska, Jarmila and Lamparski, Piotr and Lutyńska, Monika and Mirosław-Grabowska, Joanna and Nicolay, Alexander and Noryśkiewicz, Agnieszka M. and Noryśkiewicz, Bożena and Obremska, Milena and Ott, Florian and Raab, Alexandra and Raab, Thomas and Schneider, Anna and Schwab, Markus}, title = {Introduction to ICLEA fieldtrips - Stara Kiszewa 2013}, series = {2nd Annual ICLEA Workshop 2013, Dynamics of climate and landscape evolution of cultural landscapes in the Northern Central European Lowlands since the last ice age, Abstract volume \& Excursion guide}, booktitle = {2nd Annual ICLEA Workshop 2013, Dynamics of climate and landscape evolution of cultural landscapes in the Northern Central European Lowlands since the last ice age, Abstract volume \& Excursion guide}, publisher = {Deutsches GeoForschungsZentrum GFZ}, address = {Potsdam}, doi = {10.2312/GFZ.b103-13047}, pages = {53 -- 67}, language = {en} } @inproceedings{HirschRaabSchuhart, author = {Hirsch, Florian and Raab, Thomas and Schuhart, Stefan}, title = {Quaternary deposits and soil formation in the Arag{\´o}n Pyrenees (Spain) - First results from sedimentological studies}, series = {EGU General Assembly 2010, held in Vienna, Austria, 02 - 07 May 2010}, booktitle = {EGU General Assembly 2010, held in Vienna, Austria, 02 - 07 May 2010}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @misc{LangeHirschMirskyetal., author = {Lange, Ulrich and Hirsch, Thomas and Mirsky, Vladimir M. and Wolfbeis, Otto S.}, title = {Hydrogen sensor based on graphene - palladium nanocomposite}, series = {Electrochimica Acta}, volume = {56}, journal = {Electrochimica Acta}, number = {10}, issn = {0013-4686}, doi = {10.1016/j.electacta.2010.10.078}, pages = {3707 -- 3712}, abstract = {A composite material was prepared from graphene and palladium nanoparticles (PdNP) by layer-by-layer deposition on gold electrodes. The material was characterized by absorption spectroscopy, scanning electron microscopy, Raman spectroscopy and surface plasmon resonance. Cyclic voltammetry demonstrated the presence of electrocatalytic centers in the palladium decorated graphene. This material can serve as a sensor material for hydrogen at levels from 0.5 to 1\% in synthetic air. Pure graphene is poorly sensitive to hydrogen, but incorporation of PdNPs increases its sensitivity by more than an order of magnitude. The effects of hydrogen, nitrogen dioxide and humidity were studied. Sensor regeneration is accelerated in humid air. The sensitivity of the nanocomposite depends on the number of bilayers of graphene-PdNPs.}, language = {en} } @misc{FassoldFalkAndersetal., author = {Fassold, Alexander and Falk, Werner and Anders, Sven and Hirsch, Thomas and Mirsky, Vladimir M. and Straub, Rainer H.}, title = {Soluble neuropilin-2, a nerve repellent receptor, is increased in rheumatoid arthritis synovium and aggravates sympathetic fiber repulsion and arthritis}, series = {Arthritis and Rheumatology}, volume = {60}, journal = {Arthritis and Rheumatology}, number = {10}, issn = {2326-5205}, doi = {10.1002/art.24860}, pages = {2892 -- 2901}, abstract = {In inflammatory lesions, sympathetic nerve fibers disappear soon after the start of inflammation. We identified sympathetic nerve repellents as possible causal agents in rheumatoid arthritis (RA). On nerve terminals, repellent factors bind to neuropilin-2 and its coreceptor. The aim of this study was to investigate the role of neuropilin-2 in the synovial tissue of patients with RA and patients with osteoarthritis (OA) and in experimental arthritis. The density of neuropilin-2-positive fibers and cells positive for semaphorin 3F (a sympathetic repellent) was investigated using immunofluorescence staining. Enzyme-linked immunosorbent assay was used to detect soluble neuropilin-2 in body fluids from patients with RA and patients with OA. An axon outgrowth assay and a neuropilin-2 Fc fusion construct (neuropilin-2Fc) were used to investigate semaphorin 3F-induced sympathetic nerve repulsion. In an animal model of type II collagen-induced arthritis, soluble neuropilin-2Fc was studied in vivo. The synovial density of neuropilin-2-positive sympathetic nerve fibers was lower in RA than in OA, but the density of cells positive for semaphorin 3F was similar. In synovial fluid, the level of soluble neuropilin-2 was markedly higher in RA compared with OA. Mouse sympathetic ganglia served as an excellent model with which to study semaphorin 3F-induced nerve fiber repulsion. Neuropilin-2 and its coreceptor were present on sympathetic neurons, and semaphorin 3F bound to neuropilin-2Fc (binding constant 96 nmoles/liter). Semaphorin 3F dose-dependently increased sympathetic nerve fiber repulsion (at a 50\% maximum response concentration of 160-210 nmoles/liter). In contrast to our expectations, soluble neuropilin-2Fc did not inhibit repulsion but increased the repellent effect of semaphorin 3F. In experimental arthritis, therapy with neuropilin-2Fc aggravated arthritis. Soluble neuropilin-2 has no antirepellent activity but aggravates sympathetic nerve fiber repulsion and arthritis. Increased shedding of neuropilin-2 is probably an unfavorable sign in RA.}, language = {en} } @misc{HirschShaporenkoMirskyetal., author = {Hirsch, Thomas and Shaporenko, Andrey and Mirsky, Vladimir M. and Zharnikov, Michael}, title = {Monomolecular films of phthalocyanines: formation, characterisation and expelling by alkanethiols}, series = {Langmuir}, volume = {23}, journal = {Langmuir}, number = {8}, issn = {0743-7463}, doi = {10.1021/la0634239}, pages = {4373 -- 4377}, abstract = {Adsorption of aluminum-2,3-naphthalocyanine (Al-PC) onto gold (111) substrate from the pure and mixed (with alkanethiols) solutions of the target molecules in ethanol was studied. The resulting films were characterized by X-ray photoelectron spectroscopy and near-edge X-ray absorption fine structure spectroscopy. The adsorption from the pure solution resulted in formation of an Al-PC monolayer composed of the strongly inclined molecules. However, a presence of only one molar percent of a thiolated compound (alkanethiol) in the primary solution led to the complete expelling of the Al-PC molecules from the substrate and formation of a one-component alkylthiolate monolayer. The results indicate that an equilibrium formation of mixed monolayers of rodlike thiolated molecules and relatively large planar-geometry molecules, whose interaction with the metal surface is mainly provided by the π-electron system, is difficult to achieve or is in most cases even impossible under equilibrium conditions and requires an introduction of additional anchor moieties (e.g., thiols) into these molecules, as has been demonstrated by successful coadsorption of hexadecanethiol and thiolated tetraphenylporphyrin.}, language = {en} } @inproceedings{RaabRaabSchneideretal., author = {Raab, Thomas and Raab, Alexandra and Schneider, Anna and Hirsch, Florian and Takla, Melanie and Nicolay, Alexander and Bonhage, Alexander and Bauriegel, Albrecht and R{\"o}sler, Horst}, title = {Landnutzungsgeschichte und historische Landschaftsentwicklung in der Niederlausitz - Neue Befunde und aktuelle Forschung}, series = {Jahrestagung Arbeitskreis Geoarch{\"a}ologie, T{\"u}bingen, 4. Mai bis 7. Mai 2016}, booktitle = {Jahrestagung Arbeitskreis Geoarch{\"a}ologie, T{\"u}bingen, 4. Mai bis 7. Mai 2016}, abstract = {Seit 2010 untersucht eine interdisziplin{\"a}re Forschergruppe der BTU, des BLDAM und des LBGR die Landnutzungsgeschichte sowie die nat{\"u}rliche und anthropogen induzierte Landschaftsentwicklung in der Niederlausitz, Brandenburg. Systematische arch{\"a}ologische Grabungen des BLDAM im Vorfeld der laufenden Tagebaue sind eine wichtige Grundlage f{\"u}r geopedologische Untersuchungen. Die Arbeiten hatten zun{\"a}chst ihren r{\"a}umlichen Schwerpunkt in den Braunkohletagebauen nord{\"o}stlich von Cottbus (Tgb. Cottbus Nord, Tgb. J{\"a}nschwalde) und wurden dann ausgedehnt auf weitere Forstfl{\"a}chen n{\"o}rdlich von Peitz. Wir geben einen {\"U}berblick {\"u}ber die wichtigsten Erkenntnisse der letzten Jahre, pr{\"a}sentieren aktuelle Ergebnisse und zeigen zuk{\"u}nftige Forschungsfelder auf. Im Tagebau J{\"a}nschwalde sind zwischenzeitlich mehr als 1000 Relikte von Holzkohlmeilern (HKM) als Zeugen einer intensiven historischen Holznutzung arch{\"a}ologisch dokumentiert. Mit Stand Januar 2016 liegen Dendroalter von 64 HKM vor. Die Alter schwanken zwischen dem ausgehenden 16. Jahrhundert und der Mitte des 19. Jahrhunderts, was in etwa dem Betriebszeitraum des H{\"u}ttenwerks in Peitz entspricht. Die Mehrzahl der Meiler datiert auf den Beginn des 18. Jahrhunderts. Weitere Hinterlassenschaften der historischen Landnutzung sind u.a. W{\"o}lb{\"a}cker und begrabene Ackerb{\"o}den. Fossile B{\"o}den und ehemalige Landoberfl{\"a}chen sind stellenweise mit {\"a}olischen Sedimenten {\"u}berdeckt. 14C- und OSL-Datierungen an diesen B{\"o}den und Sedimenten lassen auf eine Intensivierung der {\"a}olischen Aktivit{\"a}t zur slawischen Zeit und im Deutschen Mittelalter schließen. Einige Relikte von HKM sind mit Sand {\"u}berweht worden, und an einer Stelle konnte das Alter dieser {\"a}olischen Sedimentation mittels Dendrodatierung des begrabenen Meilers auf1850 oder j{\"u}nger bestimmt werden. Allerdings stellt dies die Ausnahme dar. Der weitaus gr{\"o}ßere Teil der HKM-Relikte liegt direkt an der Oberfl{\"a}che und ist nicht begraben, was auf eine sehr geringe Winderosion in der Neuzeit schließen l{\"a}sst. Seit 2015 konnte im Rahmen des DFG-Projekts „R{\"a}umliche und zeitliche Dimension der historischen K{\"o}hlerei im Tauerschen Forst (Niederlausitz, Brandenburg). Ein Beitrag zur Kulturlandschaftsentwicklung des Norddeutschen Tieflands" (Az RA 1129/3-1; RA 931/6-1) ein weiteres Gebiet mit hoher HKM-Dichte untersucht werden. Erste Auswertungen der LiDAR-Daten ergeben eine Anzahl von 4449 ehemaligen Meilerstandorten im Tauerschen Forst. 26 Meilerstellen sind beprobt, die Dendroalter hierzu sind in Bearbeitung. Ebenfalls in j{\"u}ngerer Zeit fanden Untersuchungen zur Verbreitung von HKM-Relikten f{\"u}r das gesamte Land Brandenburg statt. Mit Hilfe eines bin{\"a}ren Modells wurden Gebiete mit hoher Wahrscheinlichkeit von HKM-Standorten detektiert. Im Rahmen des im November 2016 beginnenden DFG-Projekts „Die historische K{\"o}hlerei in Brandenburg - Analyse der r{\"a}umlichen Dimension und der Effekte auf bodenhydraulische Eigenschaften" (SCHN 1349/1-1) sollen nun neben der Verbreitung der historischen K{\"o}hlerei auch bodenrelevante Auswirkungen beschrieben und bewertet werden.}, language = {de} } @incollection{SchneiderRaabRoesleretal., author = {Schneider, Anna and Raab, Alexandra and R{\"o}sler, Horst and Takla, Melanie and Hirsch, Florian and Ritschl, Bosse and Raab, Thomas}, title = {Geophysikalische Prospektion und Mikrodrohnenbefliegungen zur Dokumentation von Meilerpl{\"a}tzen in der J{\"a}nschwalder Heide}, series = {Ausgrabungen im Niederlausitzer Braunkohlerevier 2013/2014}, booktitle = {Ausgrabungen im Niederlausitzer Braunkohlerevier 2013/2014}, editor = {Schopper, Franz and B{\"o}nisch, Eberhard}, publisher = {Brandenburgisches LAndesamt f{\"u}r Denkmalpflege und Arch{\"a}ologisches Landesmuseum}, address = {Zossen OT W{\"u}nsdorf}, isbn = {978-3-910011-79-3}, pages = {145 -- 154}, language = {de} } @misc{HirschZharnikovShaporenkoetal., author = {Hirsch, Thomas and Zharnikov, Michael and Shaporenko, Andrey and Stahl, Joachim and Weiss, Dieter and Wolfbeis, Otto S. and Mirsky, Vladimir M.}, title = {Size-controlled electrochemical synthesis of metallic nanoparticles on molecular templates}, series = {Angewandte Chemie International Edition}, volume = {44}, journal = {Angewandte Chemie International Edition}, number = {41}, issn = {1521-3773}, doi = {10.1002/anie.200500912}, pages = {6775 -- 6778}, abstract = {Reduction on the spot: Planarly adsorbed thiolated porphyrin molecules (purple) incorporated in an insulating alkanethiol monolayer (blue) function as nanoelectrodes for the local reduction of metals (gray). This approach was applied for the in situ synthesis of nanoparticles of a predetermined size.}, language = {en} } @misc{ProdramidisHirschWolfbeisetal., author = {Prodramidis, Mamas I. and Hirsch, Thomas and Wolfbeis, Otto S. and Mirsky, Vladimir M.}, title = {Enantioselective chemosensors based on spreader-bar structures}, series = {Electroanalysis}, volume = {15}, journal = {Electroanalysis}, number = {22}, issn = {1521-4109}, doi = {10.1002/elan.200302756}, pages = {1795 -- 1798}, abstract = {Chiroselective binding sites have been created on thin gold films by application of the spreader-bar approach. Impedometric techniques and surface plasmon resonance were applied to detect binding. (R)-(+)-1,1 '-Binaphthyl-2,2 '-diol (R-BNOH) and (S)-(-)-1,1 '-binaphthyl-2,2'-diol (S-BNOH) were used as model analytes. The artificial receptors were prepared by co-adsorption of 16-mercaptohexadecane (matrix) with a thiol-modified chiral selector (template). The conjugates of d, l-thioctic acid and (R)-(+)- or (S)-(-)-1,1'-binaphthyl-2,2'-diamine were used as templates. Different concentration ratios of the matrix and template were tested. No chiral selectivity of surfaces formed by either the matrix or the template alone was observed. The use of alkylthiols shorter than 16-mercaptohexadecane led to the formation of surfaces with no chiral selectivity. The gold electrodes coated by the spreader-bar technique displayed an enantioselectivity of up to 4.76 or up to 2.55 as measured by the capacitive and SPR methods, espectively.}, language = {en} } @misc{MirskyWrobelRiepletal., author = {Mirsky, Vladimir M. and Wrobel, Nadia and Riepl, Michael and Hirsch, Thomas and Wolfbeis, Otto S.}, title = {Intelligente Nanostrukturen f{\"u}r Biosensoren und Sensor-Arrays}, series = {BioTec: Zeitschrift f{\"u}r Biotechnologie}, volume = {10}, journal = {BioTec: Zeitschrift f{\"u}r Biotechnologie}, issn = {0937-2725}, pages = {28 -- 32}, language = {de} } @misc{HirschKettenbergerWolfbeisetal., author = {Hirsch, Thomas and Kettenberger, Hubert and Wolfbeis, Otto S. and Mirsky, Vladimir M.}, title = {A simple strategy for preparation of sensor arrays: Nanostructured monolayers as recognition elements}, series = {Chemical Communications}, journal = {Chemical Communications}, number = {3}, issn = {1359-7345}, doi = {10.1039/b210554c}, pages = {432 -- 433}, abstract = {The spreader-bar approach is a simple method for producing a huge variety of receptors with different selectivities. A sensor-array consisting of five such receptors is presented. A pattern recognition provides selective detection of different purines and pyrimidines.}, language = {en} } @misc{MirskyHirschPanasyuketal., author = {Mirsky, Vladimir M. and Hirsch, Thomas and Panasyuk, Tatiana L. and Piletsky, Sergey A. and Wolfbeis, Otto S.}, title = {Two- and three-dimensional artificial chemoreceptors: molecular spreader-bar vs. molecular imprinting}, series = {Medical and Biological Engineering and Computing}, volume = {37}, journal = {Medical and Biological Engineering and Computing}, number = {suppl.2}, issn = {0140-0118}, pages = {344 -- 345}, language = {en} } @misc{MirskyHirschPiletskyetal., author = {Mirsky, Vladimir M. and Hirsch, Thomas and Piletsky, Sergey A. and Wolfbeis, Otto S.}, title = {A spreader-bar approach to molecular architecture: formation of stable artificial chemoreceptors}, series = {Angewandte Chemie International Edition}, volume = {38}, journal = {Angewandte Chemie International Edition}, number = {8}, issn = {1521-3773}, doi = {10.1002/(SICI)1521-3773(19990419)38:8<1108::AID-ANIE1108>3.0.CO;2-C}, pages = {1108 -- 1110}, abstract = {The destructive influence of lateral diffusion on nanostructured monolayers can be prevented by using the spreader-bar technique. This approach allows the formation of stable artificial receptors for barbituric acid by lateral structuring of a dodecanethiol monolayer with molecular spreader-bars from thiobarbituric acid without chemical polymerization (see schematic representation). The new technique may have applications in chemosensors, affinity chromatography, stereoselective catalysis, and molecular electronics.}, language = {en} } @inproceedings{RaabRaabTaklaetal., author = {Raab, Thomas and Raab, Alexandra and Takla, Melanie and Nicolay, Alexander and Hirsch, Florian and Schneider, Anna and R{\"o}sler, Horst}, title = {Integrative Application of Traditional and Cutting-Edge Techniques to Reconstruct Holocene Earth Surface Processes and Landscape Dynamics - A Case Study from the Northern German Lowland}, series = {AGU Joint Assembly, Montreal, 2015, abstracts listing}, booktitle = {AGU Joint Assembly, Montreal, 2015, abstracts listing}, pages = {135 -- 136}, abstract = {This study outlines the opportunities to reconstruct Holocene landscape dynamics in active opencast lignite mines in southern Brandenburg (Germany). Studies on extensive outcrops that address geomorphology, pedology and archaeology provide unique insights into human-induced environmental changes. Our approach uses a variety of traditional and cutting-edge techniques to characterize small-scale landforms (high-resolution DEMs by micro-drone and LiDAR), to analyze soils and substrate properties in the field (GPR, ERT, geomagnetics, Field Portable XRF and XRD) and to provide chronological information (OSL, 14C, tree-ring dating). This approach is combined with a GIS for data integration. We present the most recent results and review important findings from the last several years. Studies conducted in the opencast mines focus on soil development and Late Quaternary geomorphodynamics and as well as past land use and the legacy of agriculture and woodland use. Our results regarding the human-induced geomorphodynamics are similar to those in other regions in Central Europe, but we also observe regional differences caused by the local setting, e.g., intensification of soil erosion coinciding with the expansion of farming of cultivated lands in the Slavic Middle Ages. By analyzing LiDAR data the largest area of historical charcoal production in the Northern European Lowland (NEL) has been revealed. We are clearly only beginning to understand the massive dimensions of charcoal production in the region and the impact on late Holocene geomorphodynamics. The usage of new high-resolution imagery is essential to identify small-scale anthropogenic landforms hidden in the landscape. Future work will consist of developing and improving our integrative approach. However, comprehensive ground truth data provided by the archaeological prospections in the open-cast mines are an excellent basis for GIS-based analyses of high-resolution ALS data and geomorphological research.}, language = {en} } @inproceedings{SchneiderTaklaRaabetal., author = {Schneider, Anna and Takla, Melanie and Raab, Alexandra and Raab, Thomas and Hirsch, Florian and R{\"o}sler, Horst}, title = {Mapping historic charcoal production fields from excavation to landscape scale}, series = {AGU Joint Assembly, Montreal, 2015, abstracts listing}, booktitle = {AGU Joint Assembly, Montreal, 2015, abstracts listing}, pages = {168}, abstract = {In the forefield of the open-cast mine J{\"a}nschwalde (north of Cottbus, Germany), archaeological excavations have revealed one of the largest charcoal production fields described so far. As remains of the historic charcoal kilns, small mounds of sediment rich in charcoal fragments and ash cover the soil surface. We applied a combination of methods for mapping such kiln relicts across a range of scales, in order to analyze the spatial distribution of kiln sites and to improve the understanding of historic forest use systems. In archaeological excavations in the mine forefield, the geometry of kiln relicts could be studied in high detail. We used a microdrone to record high-resolution photographs of excavation sites for the documentation of kiln site ground plans and other traces of historic land use. Based on airborne laser scanning elevation models, kiln site mapping was extended to areas beyond the mine forefield. Manual digitization from shaded relief maps was used for mapping kiln sites in further woodland areas surrounding an historic ironwork north of Cottbus. An automated mapping approach based on template matching was developed to detect charcoal production fields on a larger scale, and was applied for an area of about 1000 km2up to now. In archaeological excavations, about 900 kiln sites have been documented on an approximately 17 km2 large area. Excavation documentations and aerial photographs show variations in the kiln site ground plans. By manual digitization from Shaded Relief Maps, more than 5000 kiln sites with diameters up to 29 m were detected in the 32 km2 area of the royal forest J{\"a}nschwalder Heide north of Cottbus. First results of mapping for larger areas indicate similar densities, but smaller diameters of kiln sites in other charcoal production fields; and show that charcoal production is a so far underestimated component of the land use history in many areas in the Northern European Lowlands.}, language = {en} } @inproceedings{HirschBauriegelBonhageetal., author = {Hirsch, Florian and Bauriegel, Albrecht and Bonhage, Alexander and Schneider, Anna and Raab, Thomas}, title = {Occurrence, micromorphology, and soil chemistry of Fuchserden (Rhodic Arenosols) on sandy deposits in northeastern Germany}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {In the sandy deposits from the Late Pleistocene in the Northern European lowlands, the local appearance of red subsoils emerges the question of their formation and palaeoenvironmental significance. According to the WRB this soil is classified as Rhodic Arenosols, but in the German Guidelines for Soil Mapping this soil is still unconsidered because the age and genesis is unclear. Due to the intense red subsoil, the working title of this soil is 'Fuchserde'. Whereas rubefication is a characteristic feature of soils in regions with warm and dry summers like in the Mediterranean, the occurrence of red subsoil horizons containing hematite in soils in northeastern Germany is not an indicator for tropic or Mediterranean climate conditions. Already the appearance of Fuchserden on sandy deposits from the last glaciation objects earlier theories that consider these soils as a relictic soil formation from the last interglacial or even the Palaeogene or Neogene. To characterize the genesis of the Fuchserden, we focused on four different study sites in northeastern Germany. We present our findings from soil micromorphology and the identification of the iron(hydr)oxides by FTIR. Our results give new insights on the development of the Fuchserden and the importance of lateral input of iron for their genesis.}, language = {en} } @inproceedings{HirschMaatenTheunissenMaatenetal., author = {Hirsch, Florian and Maaten-Theunissen, Marieke van der and Maaten, Ernst van der and Schneider, Anna and Raab, Alexandra and Raab, Thomas}, title = {Soil physics and chemistry at a medieval ridge and furrow site in northeastern Germany}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {The usage of non-reversible ploughs, mainly during the Middle Ages and until historic times, led to the formation of ridge and furrow systems. Due to improvements of agricultural techniques, these historic agricultural sites were often abandoned and are now marginal land. The parallel ridges and furrows are usually, if not destroyed by later conventional ploughing, preserved in present-day forests. In northeastern Germany ridge and furrow systems are normally several decameters long and up to ten meters wide. The height difference between ridge top and furrow bottom is up to 50 centimeters and is expected to cause significant contrasts of soil properties and vegetation. Furthermore, due to the abandonment of sites with ridges and furrows, soils on these sites are unique archives for studies on fertilization, soil carbon dynamics and soil development. Therefore, we are characterizing soil physics (bulk density, saturated soil hydraulic conductivity, texture) and soil chemistry (soil acidity, carbon and nitrogen content) on a type location of historic ridges and furrows about 100 km northwest of Berlin.}, language = {en} } @inproceedings{HirschRaabOuimetetal., author = {Hirsch, Florian and Raab, Thomas and Ouimet, William and Dethier, David and Schneider, Anna and Raab, Alexandra}, title = {Soils on historic charcoal hearths - chemical properties and terminology}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, url = {http://nbn-resolving.de/http://meetingorganizer.copernicus.org/EGU2017/EGU2017-4009-1.pdf}, abstract = {Charcoal hearths are a unique archive for the long term interaction between biochar, soil development and plant growth. Charcoal as raw material was crucial for the production of iron in iron works and hence numerous charcoal hearths can be found in the forests near historic iron works in Europe as well as the Eastern United States. Charcoal hearths are round to elliptical forms often around 10 m in diameter, and consisting of a several decimeter thick layer containing charcoal fragments, ash, and burnt soil. We studied the soil chemistry of 24 charcoal hearths and compared them to the surrounding 'natural' soils in Litchfield County, Connecticut. The thickness of the organic rich horizons on the charcoal hearths and their carbon content is remarkably higher than in the surrounding topsoils. The wide distribution of charcoal hearths, their usually high quantity, and their occurrence in different ecosystems underlines their importance for further pedological research.}, language = {en} } @inproceedings{RaabHirschVassermanetal., author = {Raab, Thomas and Hirsch, Florian and Vasserman, Oleksandr and Raab, Alexandra and Naeth, M. Anne}, title = {Influence of relief and vegetation on soil properties in a disturbed chernozem soil landscape}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {In central and southeastern Alberta, chernozems dominate the soil landscape and are divided into several groups that follow the climate gradient from Northwest to Southeast: Dark Grey Chernozems, Black Chernozems, Dark Brown Chernozems; Brown Chernozems. Principles controlling development and distribution of these chernozem subtypes along the ecotone transect are quite well known. However, intensive land use over the last century has affected soils that originally have formed under natural conditions during the Holocene in more than 10,000 years. There is a lack of knowledge regarding soil development in these landscapes on the decadal to centennial time scale. Within this time frame the most important factor of soil formation may be relief, although this has not been properly studied. This study aims to compare soil properties in a typical chernozem landscape where soils have been highly disturbed and parent materials have been re-arranged by surface coal mining.We hypothesize that within 50 years, soils develop with significant differences based on vegetation type and slope aspect. Our study site is the former Diplomat Mine near Forestburg, Alberta where spoils form a small scale ridge and graben topography. The south facing slopes of the piles are covered by grassland, whereas on the north exposition has trees and shrubs. Samples were taken from six sites with differences in topography and vegetation type. Diplomate T1 is at the top of the ridge with grassland, Diplomate S1 is on the southern slope with grassland, Diplomate N1 is on the northern slope with trees, and Diplomate N2 is on the northern slope with shrubs. For comparison we took samples from two sites without slope aspect. One site was an undisturbed grassland (Diplomate Z1) and the other sites were reclaimed piles (Diplomate R1). At each site, five soil profiles were examined and volumetrically sampled (250 cm3 steel ring) in steps of five centimeters to a depth of 30 centimeters. We present first results of basic physical and chemical soil parameters (bulk density, water content, pH, Cstock, N-stock).}, language = {en} } @inproceedings{SchneiderHirschRaabetal., author = {Schneider, Anna and Hirsch, Florian and Raab, Alexandra and Bonhage, Alexander and Raab, Thomas}, title = {Assessing the legacy effects of historic charcoal production in Brandenburg, Germany}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Charcoal produced in kilns or hearths was an important source of energy in many regions of Europe and Northern America until the 19th century, and charcoal production in hearths is still common in many other regions of the world. The remains of charcoal hearths are therefore a widespread legacy of historic land use in forest areas. Soils on charcoal hearth sites are characterized by a technogenic layer rich in charcoal and ash on top of the soil profile, and by a pyrogenic modification of substrates below the former hearth. The aims of our study are to examine how these alterations to the natural soil profiles affect the soil water regime and other soil physical properties, and to assess the relevance of these effects on the landscape scale. We present first results of a mapping of hearth site occurrence in forest areas in the state of Brandenburg, Germany, and of a characterization of the infiltration behaviour on hearth sites as compared with undisturbed forest soils. Results of mapping small-scale relief features from LIDAR-based digital elevation models show that charcoal hearths occur in a high density in many large forest areas throughout Brandenburg. In the areas studied so far, up to almost 3\% of the soil surface were found to be affected by the remains of historic hearths. First analyses of soil physical properties indicate differences in the infiltration characteristics of hearth site soils and undisturbed forest soils: Hood infiltrometer measurements show a very high spatial variability of hydraulic conductivity for hearth site soils, and water-drop-penetration-time tests reflect extremely high hydrophobicity of the technogenic layer on the sites. Results of dye tracer experiment show considerably strong preferential flow and therefore a higher spatial variability of soil wetness below the hearth remains. Overall, our first results therefore indicate that the legacy effects of historic charcoal production might significantly affect overall site conditions in forest areas with a high density of charcoal hearth remains.}, language = {en} } @inproceedings{RaabSchneiderBonhageetal., author = {Raab, Alexandra and Schneider, Anna and Bonhage, Alexander and Raab, Thomas and Hirsch, Florian}, title = {Extensive historical charcoal production in Brandenburg (Germany) - identification of potential areas by GIS analysis}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {We used a GIS analysis of environmental and historical data to identify potential areas of extensive charcoal production in Brandenburg. The analysis was based on three assumptions (i to iii). Large charcoal kiln fields can be found in areas that i) are close to historical industrial sites, ii) are close to bog iron ore deposits, and iii) have been continuously covered by forest during the last centuries. Information on theses parameters was gathered in an archive and literature study and from historical and recent maps. Areas with a high probability of kiln site occurrence were then determined using a simple binary additive model. In the last step, shaded-relief maps (SRMs) were visually checked for clearly visible kiln sites and soil properties were analysed in the determined areas. In total, eight areas with a high probability of kiln site occurrence are identified for the state of Brandenburg. By visual interpretation of SRMs, high kiln site densities in these areas are confirmed. The analysis of soil maps shows that kiln fields are predominantly located on sandy soils with a low yield potential. Although further parameters and study areas need to be considered in the model in order to explain the spatial distribution patterns of charcoal production, the results indicate correlations between the location of bog iron ore deposits, historic ironworks and charcoal kiln fields.}, language = {en} } @inproceedings{SchneiderHirschWechleretal., author = {Schneider, Anna and Hirsch, Florian and Wechler, Klaus-Peter and Raab, Alexandra and Raab, Thomas}, title = {Mapping a paleosurface and archaeological site location in an inland dune area in Brandenburg, Germany}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Mapping and visualizing the position of archaeological remains in the surface relief provides important basic information for archaeological survey design and interpretation. Geomorphological processes in (pre)history can have resulted in a modification of the local relief around archaeological sites, especially in areas that are prone to sediment erosion and relocation, so that models of past surfaces are necessary for a correct interpretation of archaeological survey results. In this study, we combined terrestrial survey and remote sensing methods to reconstruct the palaeorelief around two archaeological excavation sites in an inland dune area in southern Brandenburg, Germany. Remains from two Mesolithic hunter-gatherer camps were documented in archaeological excavations and found to be associated with a buried soil horizon. To gather information on the relief of the buried soil surface, we used a combination of sedimentological and pedological profile description of archaeological survey trenches and geophysical prospection with Ground-Penetrating Radar; supplemented by microdrone photography and photogrammetry, GPS surveys and analysis of LIDAR-based elevation models. A digital elevation model of the buried surface was created by combining point data from these sources. The buried surface morphology and the position of the archeological remains within the reconstructed landscape were analyzed in GIS. The comparison of the generated paleosurface model with the recent surface elevation model shows that sand remobilization resulted in a considerable reshaping of the relief. Analysis of the buried surface model further shows that the relief position of the two archaeological sites in the study area was considerably more prominent in relation to the corresponding buried soil surface than in relation to the recent surface morphology. Results affirm the importance of considering Holocene relief modifications in archaeological surveys.}, language = {en} } @inproceedings{HirschDietrichKnoopetal., author = {Hirsch, Florian and Dietrich, Nils and Knoop, Christine and Raab, Thomas}, title = {Micromorphology of pelletized soil conditioners}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Soil conditioners produced by anaerobic digestion and subsequent composting of organic household waste, bear the potential to improve unproductive farmland together with a reduced input risk of unwanted pollutants into the soils. Within the VeNGA project (http://www.biogas-network.de/venga), soil conditioners from anaerobically digested organic household waste are tested for their potential to increase plant growth in glasshouse and field experiments. Because the production techniques of these soil conditioners may influence their physical and chemical behaviour in the soil, two different techniques for pelletizing the soil conditioners where applied. We present findings from a pot experiment with cereal that has been sampled after two months for micromorphological analyses.We visualize the decomposition and the physical behaviour of the soil conditioners. Pellets produced in an agglomeration mixer result in dense balls, that are only slightly decomposed after the trial. But the soil conditioners created under pressure in a screw extruder are rich in voids and have the potential of retaining more soil water.}, language = {en} } @inproceedings{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {The Finow soil - a stratigraphic marker or just a pedologic horizon?}, series = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2017, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, abstract = {Palaeosoils indicate periods of landscape stability, and therefore warmer periods during the cold climate conditions of the Late Pleistocene, when pedogenic processes can shape the surface. Therefore, in Late Pleistocene glacial and periglacial deposits, palaeosoils are widely used as chronostratigraphic markers. However, in contrast to limnic archives the records in terrestrial sediments are often discontinuous or ambiguous. The so called Finow soil is commonly found as 5 to 15 cm thick and fossilized horizon, characterized by brunification and the illuviation of clay in the sandy deposits of Northern Central Europe. We present a micromorpological approach together with OSL ages, that contradicts the stratigraphic potential of the Finow soil and also questions the suitability of soil horizons formed by clay illuviation as stratigraphic markers.}, language = {en} } @inproceedings{RaabRaabHirschetal., author = {Raab, Thomas and Raab, Alexandra and Hirsch, Florian and Schneider, Anna and Bonhage, Alexander}, title = {Late Quaternary landscape development and legacies of human-induced land use changes in Lower Lusatia, South Brandenburg, Germany}, series = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, booktitle = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, editor = {Schwab, Markus and Błaszkiewicz, Mirek and Raab, Thomas and Wilmking, Martin and Brauer, Achim}, publisher = {GFZ German Research Centre for Geosciences}, address = {Potsdam}, doi = {10.2312/GFZ.b103-17037}, pages = {182 -- 198}, language = {en} } @inproceedings{HirschSchneiderRaabetal., author = {Hirsch, Florian and Schneider, Anna and Raab, Alexandra and Raab, Thomas and Ouimet, William and Dethier, David}, title = {Late Holocene biochar enrichment in soils - implications of an anthropogenic legacy for ecosystems}, series = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, booktitle = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, editor = {Schwab, Markus and Błaszkiewicz, Mirek and Raab, Thomas and Wilmking, Martin and Brauer, Achim}, publisher = {GFZ German Research Centre for Geosciences}, address = {Potsdam}, doi = {10.2312/GFZ.b103-17037}, pages = {79 -- 81}, language = {en} } @inproceedings{SchneiderHirschRaabetal., author = {Schneider, Anna and Hirsch, Florian and Raab, Alexandra and Raab, Thomas}, title = {Dye tracer visualization of infiltration patterns in soils on historic charcoal hearth sites}, series = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, booktitle = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, editor = {Schwab, Markus and Błaszkiewicz, Mirek and Raab, Thomas and Wilmking, Martin and Brauer, Achim}, publisher = {GFZ German Research Centre for Geosciences}, address = {Potsdam}, doi = {10.2312/GFZ.b103-17037}, pages = {150 -- 151}, language = {en} } @inproceedings{SchneiderHirschWechleretal., author = {Schneider, Anna and Hirsch, Florian and Wechler, Klaus-Peter and Raab, Alexandra and Raab, Thomas}, title = {Mapping a palaeosurface and archaeological site location in an anthropogenic drift sand area}, series = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, booktitle = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, editor = {Schwab, Markus and Błaszkiewicz, Mirek and Raab, Thomas and Wilmking, Martin and Brauer, Achim}, doi = {10.2312/GFZ.b103-17037}, pages = {152 -- 154}, language = {en} } @inproceedings{SchneiderRaabHirschetal., author = {Schneider, Anna and Raab, Alexandra and Hirsch, Florian and Bonhage, Alexander and Raab, Thomas}, title = {Assessing the legacies of historical charcoal production in Brandenburg}, series = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, booktitle = {ICLEA Final Symposium 2017, Human Impact and Landscape Evolution in the Southern Baltic Lowlands, Abstract Volume \& Excursion Guide}, editor = {Schwab, Markus and Błaszkiewicz, Mirek and Raab, Thomas and Wilmking, Martin and Brauer, Achim}, publisher = {GFZ German Research Centre for Geosciences}, address = {Potsdam}, doi = {10.2312/GFZ.b103-17037}, pages = {155 -- 156}, language = {en} } @misc{HirschRaabHelleretal., author = {Hirsch, Florian and Raab, Thomas and Heller, Sebastian and Bauriegel, Albrecht}, title = {Classification of pedogenic cementation in Podzols by pocket penetrometry}, series = {Journal of Plant Nutrition and Soil Science}, volume = {180}, journal = {Journal of Plant Nutrition and Soil Science}, number = {4}, issn = {1522-2624}, doi = {10.1002/jpln.201600395}, pages = {430 -- 435}, abstract = {According to the German Soil Taxonomy, the formation of cemented horizons in Podzols is restricted to the precipitation of iron oxides. However, in iron-poor sandy substrates, also illuviation of only organic compounds can form cemented horizons with penetration resistances of up to 14 kg cm-2. We present a reproducible field test for classifying pedogenic cementation in Podzols and suggest considering cemented horizons (Bmh and Bhm) in the upcoming edition of the Guidelines for Soil Mapping.}, language = {en} } @misc{HirschRaabOuimetetal., author = {Hirsch, Florian and Raab, Thomas and Ouimet, William and Dethier, David and Schneider, Anna and Raab, Alexandra}, title = {Soils on historic charcoal hearths - terminology and chemical properties}, series = {Soil Science Society of America Journal : SSSAJ}, volume = {81}, journal = {Soil Science Society of America Journal : SSSAJ}, number = {6}, issn = {1435-0661}, doi = {10.2136/sssaj2017.02.0067}, pages = {1427 -- 1435}, abstract = {Historic charcoal hearth remains provide a unique archive of the long term interaction between biochar, soil development and plant growth. Charcoal as raw material was crucial for production of iron in iron works and hence numerous charcoal hearths can be found in the forests near historic iron works in Europe as well as the Eastern United States. Charcoal hearths are round to elliptical forms often around 10 m in diameter, and consist of several decimeter thick layers that contain charcoal fragments, ash, and burnt soil. We studied the soil chemistry of 24 charcoal hearths and compared them to the surrounding 'natural' soils in the northern Appalachians of northwestern Connecticut. The thickness of the topsoils on the charcoal hearths and their carbon content are remarkably higher than in the surrounding topsoils. The presence of residual products from charcoal production classifies the soils as Anthropic Udorthents (US Soil Taxonomy) or Spolic Technosols (Humic) according to the World Reference Base for Soil Resources. The widespread occurrence of charcoal hearth remains and their high spatial density in different ecosystems underlines their importance for further pedological research.}, language = {en} } @inproceedings{RaabSchneiderRaabetal., author = {Raab, Thomas and Schneider, Anna and Raab, Alexandra and Hirsch, Florian and Bonhage, Alexander}, title = {The geomorphic legacy of historic charcoal production in Brandenburg, Germany}, series = {4th Central European Geomorphology Conference, Bayreuth, October 9th-13th 2017}, booktitle = {4th Central European Geomorphology Conference, Bayreuth, October 9th-13th 2017}, editor = {Holzheu, Stefan and Thies, Birgit}, address = {Bayreuth}, pages = {117 -- 118}, language = {en} } @inproceedings{HirschBauriegelBonhageetal., author = {Hirsch, Florian and Bauriegel, Albrecht and Bonhage, Alexander and Schneider, Anna and Raab, Thomas}, title = {Fuchserden in Brandenburg - Vorkommen, Mikromorphologie und Bodenchemie}, series = {Abstracts der Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, G{\"o}ttingen, 2017}, booktitle = {Abstracts der Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, G{\"o}ttingen, 2017}, publisher = {DBG}, address = {G{\"o}ttingen}, pages = {1}, language = {de} } @inproceedings{HirschRaab, author = {Hirsch, Florian and Raab, Thomas}, title = {Der Finowboden - ein lokaler Pal{\"a}oboden?}, series = {Abstracts der Jahrestagung de Deutschen Bodenkundlichen Gesellschaft, G{\"o}ttingen, 2017}, booktitle = {Abstracts der Jahrestagung de Deutschen Bodenkundlichen Gesellschaft, G{\"o}ttingen, 2017}, publisher = {DBG}, address = {G{\"o}ttingen}, pages = {1}, language = {de} } @inproceedings{SchneiderHirschRaabetal., author = {Schneider, Anna and Hirsch, Florian and Raab, Alexandra and Bonhage, Alexander and Raab, Thomas}, title = {Bodenver{\"a}nderungen durch die historische Holzkohleproduktion in Brandenburg}, series = {Abstracts der Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, G{\"o}ttingen, 2017}, booktitle = {Abstracts der Jahrestagung der Deutschen Bodenkundlichen Gesellschaft, G{\"o}ttingen, 2017}, publisher = {DBG}, address = {G{\"o}ttingen}, pages = {1}, language = {de} } @inproceedings{SchneiderRaabBonhageetal., author = {Schneider, Anna and Raab, Alexandra and Bonhage, Alexander and Hirsch, Florian and Raab, Thomas}, title = {Legacies of historic charcoal production in Brandenburg, Germany}, series = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{BonhageHirschSchneideretal., author = {Bonhage, Alexander and Hirsch, Florian and Schneider, Anna and Raab, Alexandra and Raab, Thomas}, title = {Multiproxy analysis of a relict charcoal hearth field in Brandenburg (Germany)}, series = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{HirschMaatenTheunissenMaatenetal., author = {Hirsch, Florian and Maaten-Theunissen, Marieke van der and Maaten, Ernst van der and Schneider, Marcus and Bauriegel, Albrecht and Raab, Alexandra and Raab, Thomas}, title = {Soil physics and chemistry at two medieval ridge and furrow sites in northeastern Germany}, series = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{HirschBonhageBauriegeletal., author = {Hirsch, Florian and Bonhage, Alexander and Bauriegel, Albrecht and Schneider, Anna and Raab, Alexandra and Raab, Thomas and Gypser, Stella}, title = {Occurrence, soil parameters and genesis of Rhodic Arenosols ('Fuchserden') in northeastern Germany}, series = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{HirschSchneiderBauriegeletal., author = {Hirsch, Florian and Schneider, Anna and Bauriegel, Albrecht and Raab, Alexandra and Raab, Thomas}, title = {Formation, classification and properties of soils at two relict charcoal hearth sites in Brandenburg, Germany}, series = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, booktitle = {European Geosciences Union, General Assembly 2018, Vienna, Austria}, publisher = {European Geophysical Society}, address = {Katlenburg-Lindau}, language = {en} } @inproceedings{HirschMaatenTheunissenMaatenetal., author = {Hirsch, Florian and Maaten-Theunissen, Marieke van der and Maaten, Ernst van der and Schneider, Marcus and Schneider, Anna and Raab, Alexandra and Raab, Thomas}, title = {Pedology and effects on vegetation at two medieval ridge and furrow sites in northeastern Germany}, series = {Jahrestagung des Arbeitskreises Geoarch{\"a}ologie, M{\"u}nchen, 2018}, booktitle = {Jahrestagung des Arbeitskreises Geoarch{\"a}ologie, M{\"u}nchen, 2018}, editor = {Berg, Stefanie and Eckmeier, Eileen and Linzen, Sven and Werther, Lukas and Zielhofer, Christoph}, publisher = {Friedrich-Schiller-Universit{\"a}t Jena [u.a.]}, address = {Jena [u.a.]}, doi = {10.22032/dbt.34521}, pages = {S. 18}, language = {en} } @inproceedings{BonhageHirschSchneideretal., author = {Bonhage, Alexander and Hirsch, Florian and Schneider, Anna and Raab, Alexandra and Raab, Thomas}, title = {Multiproxy analysis of a relict charcoal hearth field in Brandenburg (Germany)}, series = {Jahrestagung des Arbeitskreises Geoarch{\"a}ologie, M{\"u}nchen, 2018}, booktitle = {Jahrestagung des Arbeitskreises Geoarch{\"a}ologie, M{\"u}nchen, 2018}, editor = {Berg, Stefanie and Eckmeier, Eileen and Linzen, Sven and Werther, Lukas and Zielhofer, Christoph}, publisher = {Friedrich-Schiller-Universit{\"a}t Jena [u.a.]}, address = {Jena [u.a.]}, doi = {10.22032/dbt.34521}, pages = {S. 27}, language = {en} } @inproceedings{SchneiderRaabBonhageetal., author = {Schneider, Anna and Raab, Alexandra and Bonhage, Alexander and Hirsch, Florian and Raab, Thomas}, title = {Relikte der historischen K{\"o}hlerei in Brandenburg}, series = {Jahrestagung des Arbeitskreises Geoarch{\"a}ologie, M{\"u}nchen, 2018}, booktitle = {Jahrestagung des Arbeitskreises Geoarch{\"a}ologie, M{\"u}nchen, 2018}, editor = {Berg, Stefanie and Eckmeier, Eileen and Linzen, Sven and Werther, Lukas and Zielhofer, Christoph}, publisher = {Friedrich-Schiller-Universit{\"a}t Jena [u.a.]}, address = {Jena [u.a.]}, doi = {10.22032/dbt.34521}, pages = {S. 28}, language = {de} }