@misc{BonhageMykhailovaHirschetal., author = {Bonhage, Alexander and Mykhailova, Larysa and Hirsch, Florian and Schneider, Anna and Raab, Thomas and Fischer, Thomas and Raab, Alexandra and Donovan, Sally and Ouimet, William}, title = {Effects of historical charcoal burning on soil landscapes in West Connecticut - Quantifying pyrogenic and organic soil carbon content of Technosols by FTIR analysis}, series = {European Geosciences Union, General Assembly 2019, Vienna, Austria, 7-12 April 2019}, journal = {European Geosciences Union, General Assembly 2019, Vienna, Austria, 7-12 April 2019}, address = {Katlenburg-Lindau}, language = {en} } @misc{BonhageRaabSchneideretal., author = {Bonhage, Alexander and Raab, Thomas and Schneider, Anna and Fischer, Thomas and Ramezany, Shaghayegh and Ouimet, William and Raab, Alexandra and Hirsch, Florian}, title = {Vertical SOC distribution and aromatic carbon in centuries old charcoal-rich Technosols}, series = {European Journal of Soil Science}, volume = {73}, journal = {European Journal of Soil Science}, number = {4}, doi = {10.1111/ejss.13293}, pages = {1 -- 16}, abstract = {Charcoal-rich Technosols on century-old relict charcoal hearths (RCHs) are the subject of ongoing research regarding potential legacy effects that result from historic charcoal production and subsequent charcoal amendments on forest soil properties and forest ecosystems today. RCHs consist mostly of Auh horizons that are substantially enriched in soil organic carbon (SOC), of which the largest part seems to be of pyrogenic origin (PyC). However, the reported range of SOC and PyC contents in RCH soil also suggests that they are enriched in nonpyrogenic SOC. RCH soils are discussed as potential benchmarks for the long-term influence of biochar amendment and the post-wildfire influences on soil properties. In this study, we utilised a large soil sample dataset (n = 1245) from 52 RCH sites in north-western Connecticut, USA, to quantify SOC contents by total element analysis. The contents of condensed highly aromatic carbon as a proxy for black carbon (BC) were predicted by using a modified benzene polycarboxylated acid (BPCA) marker method in combination with diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy-based partial least square regression (r2 = 0.89). A high vertical spatial sampling resolution allowed the identification of soil organic matter (SOM) enrichment and translocation processes. The results show an average 75\% and 1862\% increase in TOC and BPCA-derived carbon, respectively, for technogenic Auh horizons compared to reference soils. In addition to an increase in aromatic properties, increased carboxylic properties of the RCH SOC suggest self-humification effects of degrading charcoal and thereby the continuing formation of leachable aromatic carbon compounds, which could have effects on pedogenic processes in buried soils. Indeed, we show BPCA-derived carbon concentrations in intermediate technogenic Cu horizons and buried top/subsoils that suggest vertical translocation of highly aromatic carbon originating in RCH Auh horizons. Topmost Auh horizons showed a gradual decrease in total organic carbon (TOC) contents with increasing depth, suggesting accumulation of recent, non-pyrogenic SOM. Lower aliphatic absorptions in RCH soil spectra suggest different SOM turnover dynamics compared to reference soils. Furthermore, studied RCH soils featured additional TOC enrichment, which cannot be fully explained now.}, language = {en} } @misc{HirschSproeteFischeretal., author = {Hirsch, Florian and Spr{\"o}te, Roland and Fischer, Thomas and Forman, Steven L. and Raab, Thomas and Bens, Oliver and H{\"u}ttl, Reinhard F.}, title = {Late Quaternary aeloian dynamics, pedostratigraphy and soil formation in the North European Lowlands - new findings from the Baruther ice-marginal valley}, series = {Die Erde}, volume = {148}, journal = {Die Erde}, number = {1}, issn = {0013-9998}, doi = {10.12854/erde-148-30}, pages = {58 -- 73}, abstract = {The formation of dunes in central Europe reflects ample sediment supply during the last deglacial hemicycle. A Quaternary inland dune complex in southern Brandenburg, Germany, was studied to frame the duration of pedogenesis in two outcrops containing buried paleosols. An integrative approach, which combined geomorphological, sedimentological, pedological and chronological methods was used to identify aeolian deposition events, ensuing pedogenesis and anthropogenic remobilization. At the outcrops, which were situated approximately 2 km apart from each other, a total of twelve samples of the aeolian sands were dated using optically stimulated luminescence (OSL) and a further six samples using 14C dating. Although the dunes have similar morphological features, these forms have a different history of aeolian sand deposition and pedogenesis. At the older dune (Gl 1) the surface soil is a well developed Podzol, whereas soil development of the younger dune (Gl 2) is clearly in an initial state. The studied sites of the dune complex also differ in grain size distribution and in the presence of buried soils, thereby indicating a climatic impact on aeolian remobilization.}, language = {en} }