TY - GEN A1 - Bawohl, Melanie A1 - Nilges, Tom A1 - Schmidt, Peer T1 - Temperature Initiated P-Polymerization in Solid [Cd3Cu]CuP10 T2 - Inorganic chemistry N2 - [Cd3Cu]CuP10 is the first representative of a class of compounds featuring polyphosphidic adamantine-analogous [P10] units, which tend to be fragmented and polymerized to [P6] rings and tubular [P26] units in the solid state. A new polyphosphide with nominal composition Cd15Cu10P46 results, featuring isolated and polymerized polyanions. Thermoanalytic experiments and phase analytic measurements substantiated the consecutive loss of P4 and Cd of the starting material via different intermediate steps. After P4 loss, the new polyphosphide occurred followed by various binary copper phosphides to the final product Cu3P. KW - Thermal Analysis, Solid State Synthesis, Crystal Structure, Polyphosphide Y1 - 2014 UR - https://opus4.kobv.de/opus4-UBICO/frontdoor/index/index/docId/10388 UR - http://pubs.acs.org/doi/abs/10.1021/ic401508n SN - 1520-510X VL - 52 IS - 20 SP - 11895 EP - 11901 ER -