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The present study deals with the phenomenological observation of the corrosion of the positive electrode foil of lithium-ion batteries containing LiNi0.6Co0.2Mn0.2O2 (NMC) as cathode material. Due to the presence of moisture, localized water accumulation is formed on the NMC surface. The water absorbed by the electrolyte reacts with the NMC under Li+/H+ exchange and the resulting pH increase leads to dissolution of the carrier foil and characteristic salt-like blooms on the NMC surface. With the increase in the relative area occupied by the holes in the aluminum foil per time, a sufficiently suitable parameter was found with which to quantitatively determine the extent of corrosion. The degree of degradation depends on time and ambient humidity. It was shown that functional recycling with the water jet method is no longer applicable for degraded foils, since the mechanical stability of the foils decreases as corrosion progresses. Lithium, aluminum, sulfur and oxygen were detected in the blooms using SEM–EDX and Laser-Induced-Breakdown-Spectroscopy (LIBS). The underlying NMC layer was found to contain mainly aluminum and significantly lower lithium content than the non-degraded material. SEM and Raman microscopy analyses also showed that the active material is also locally degraded and therefore no longer suitable for functional recycling.
A classic approach for solving differential equations with neural networks builds upon neural forms, which employ the differential equation with a discretisation of the solution domain. Making use of neural forms for time-dependent differential equations, one can apply the recently developed method of domain segmentation. That is, the domain may be split into several subdomains, on which the optimisation problem is solved. In classic adaptive numerical methods, the mesh as well as the domain may be refined or decomposed, in order to improve the accuracy. Also, the degree of approximation accuracy may be adapted. Therefore, it is desirable to transfer such important and successful strategies to the field of neural-network-based solutions. In the presented work, we propose a novel adaptive neural approach to meet this aim for solving time-dependent problems. To this end, each subdomain is reduced in size until the optimisation is resolved up to a predefined training accuracy. In addition, while the neural networks employed are by default small, we propose a means to adjust also the number of neurons in an adaptive way. We introduce conditions to automatically confirm the solution reliability and optimise computational parameters whenever it is necessary. Results are provided for several initial-value problems that illustrate important computational properties of the method.
Additive technologies are now widely used for the production of complex precise parts and have high potential for the production of forming dies. In this work, hot-forming dies optimized for additive manufacturing were developed and produced with wire arc direct energy deposition (WA-DED) and laser powder bed fusion (L-PBF) technologies. The concept of lightweight hot-forming dies with a 2D-lattice structure was developed, which reduced the weight of each die by 56%, from 14.2 kg to 6.1 kg, in production using L-PBF. Maraging/precipitation-hardened steel 17-4PH was used as an alternative to traditional hot-working steels with slightly lower mechanical properties and a much higher processability in the additive manufacturing process. The workability of the manufactured dies was confirmed by forging tests on an industrial screw press.
Temperature variability may have direct and indirect impacts on the environments of the Accra and Kumasi Metropolises in Ghana. This study analysed temperature and trends in temperature in both cities using in-situ measurements from one meteorological station in both cities from 1986 to 2015. The temperature indices were computed using the RClimdex package from the Expert Team on Climate Change Detection Monitoring Indices (ETCCDMI). The temperature time series was pre-whitened before the Mann–Kendall trend and Sen’s slope estimator analysis were applied. Initial analysis revealed minimal variation in temperature in both cities. The results from the analysed temperature indices revealed an increase in warm days and a general rise in the minimum temperature compared to maximum temperatures. Mann Kendall and Sen’s slope revealed significant trends in the annual and seasonal (dry and wet seasons) in minimum temperature in both cities. These might lead to an increased rate of heat-stressed diseases and an overall rise in urban warming in both cities. The analysis of temperature, indices and trends provided comprehensive insights into the temperature of Accra and Kumasi. The results highlight the essence of evaluating temperature indices and trends in light of Climate Change concerns. It is recommended that urban green and blue spaces should be incorporated into land use plans as these policy directions can aid regulate the temperature in both cities.
The Accra Metropolis of Ghana has experienced rapid urban expansion over the past decades. Agricultural and forest-lands have been transformed into urban/built-up areas. This study analysed urban expansion and its relationship with the temperature of Accra from 1986 to 2022. Multi-source datasets such as remote sensing (RS) and other ancillary data were utilised. Land use land cover (LULC) maps were produced employing the random forests classifier. Land surface temperature (LST) and selected d(RS) Indices were extracted. Regression techniques assessed the interplay between LST and remote sensing indices. The LULC maps revealed increasing trends in the urban/built-up areas at the expense of the other LULC types. The analysis from the LST and the RS indices revealed a direct relationship between temperature and urban/built-up areas and an inverse relationship between temperature and vegetation. Thus, spatial urban expansion has modified the urban temperature of Accra. The integrated utilisation of RS and GIS demonstrated to be an efficient approach for analysing and monitoring urban expansion and its relationship with temperature.
Biomass and bioenergy perspectives of a coal region : status quo, potential and scenarios in Lusatia
(2023)
Coal has been one of the main fuels used in Europe. Its decreasing role due to the ongoing transformation of the energy system will create significant socio-economic challenges. The switch into renewable energy systems could be an alternative to maintain jobs and economic activities within the affected regions. Biomass use and bioenergy can play an important role in the energy transition. Instead of energy crops, forest and agricultural residues should be used as biogenic energy sources in the future to avoid impacts on land use and food security. The main objective of this article is to investigate the biomass potential of a coal region and to provide scenarios for the future development of bioenergy production. Due to the changing framework conditions and, as a result, the different biomass focuses, previous bioenergy potential estimates must be reviewed. The methods for determining the potential of biomass for energy production was used for Lusatia (in German: Lausitz), the second largest coal region in Germany. These methods can also be applied in other regions. As a first step, the regional status quo assessment of cultivated areas and yields had decisive relevance for calculating biomass potential ranges. In a second step, the current bioenergy facilities in the region were identified, with a focus on power and heat production. The third step was the estimation of future regional bioenergy use. Therefore, the regional potential was gathered with the generally supra-regional framework conditions. For this purpose, national scenario studies were used, which contain the relevant target values and framework conditions. Two scenarios were developed for future bioenergy estimations: a conservative path based on the current policies and a progressive path, derived from the goal of climate neutrality by 2045. The results show a qualitative comparison among both scenarios and the previously determined potential ranges. Bioenergy can probably contribute to achieving climate neutrality with an increase in wood-fired systems, while agricultural bioenergy potential is likely to decline. In the discussion section, however, the uncertainty of these results is pointed out, as future use of bioenergy will be heavily influenced by the regulatory framework, competition with material use and the influences of climate change.
Bored children begin to draw, do crafts, to fidget - or they do something bad. Others fall silent, withdraw, or become lethargic. Research on school-related boredom has focused primarily on the negative consequences of boredom, such as decreased cognitive performance, motivation or attentativeness, or disruptiveness. These negative aspects of boredom can be contrasted by the notion that boredom can promote creative performance. This paper reflects on boredom's creative and suppressive consequences as an interplay of personality traits and behavioral possibilities in school situations, on the one hand, and as an interplay of situational experiences with constituent developmental processes on the other. It is proposed that boredom is a gauge of the learner's resonance with school content, learning and/or developmental relationships. Boredom indicates a psychological need and its desideratum. Thus, both creative and suppressive potentials are inherent in boredom.
Comparing hybrid urbanisms in the global south : water delivery configurations in Peru and Ghana
(2023)
Urban development processes in the Global South (and North) are often described as characterized by formal and informal practices of different actors and their respective material realities. In critical urban studies, the disposition for this binary conception of formal and informal urbanisms has been discussed for many years. To a certain extent, these sometimes align rather problematically with contrasting notions of the “structural” versus the “everyday.” In this article, we explore an understanding of formal and informal urban practices (and respectively “structure” and “everyday”) as always interrelated, and we develop a methodology for a comparative examination of such hybrid urbanisms. In doing so, we address a missing link in the surging theoretical debate on comparative/southern urbanisms, which has rarely been substantiated by methodological explorations. The adapted concept of “delivery configurations” combines analyses of actor networks, material realities, rules and regulations, discourses, and heterogenous arrays of urban practices of negotiating these. However, bringing together local particularities and structural commonalities and exploring their interrelation only provides a basis for understanding case‐specific complexities. We argue that embedding the analysis in a multi‐scalar comparative framework can further its analytical rather than descriptive attributes and provide deeper insights into issues such as social inequality. To illustrate our methodological contribution, we provide first insights from a comparative research
project of water delivery in different neighbourhoods in the secondary cities of Sunyani (Ghana) and Arequipa (Peru). We highlight the practical challenges of comparing diverse urban contexts and examining the rather complex relationships between infrastructure delivery, urban development, and social inequality.
The permanent magnet synchronous motor (PMSM) can be a suitable candidate for electrified propulsion in aviation. Despite the very high efficiency, heat dissipation during operation leads to performance limitations. Elevated temperatures in the electrical insulations and the magnets pose a potential safety risk that must be reduced by selective cooling. A comprehensive review is conducted to capture current research interests in cooling methods in PMSM. Cooling methods are described according to their heat transfer mechanism, grouped, and assigned to the components within the motor. Key findings of the literature reviewed are described in the context of PMSM cooling. Information on cooling media and potential combinations of cooling methods in components is gathered. Assessment parameters such as safety, weight, effectiveness, integrability, complexity and cost are defined to enable a subsequent qualitative analysis for six selected cooling methods. A point-weighted evaluation approach, according to VDI 2225, was applied to identify the most promising cooling approach for successful implementation in aviation.
The very soft and flow-permeable plumage is among the special adaptations of the owl that the silent flight is attributed to. Using a specially designed apparatus that provides a low-speed volume flow of air through a small sample of porous materials, measurements of the air flow permeability were performed in accordance to ISO 9053 on a total of 39 prepared wing specimen from six different bird species, including three species of silently flying owls and three non-silently flying bird species. The resulting data set described in the present paper contains the static airflow resistance measured at different positions on the wing.